請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/24657完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 周楚洋(Chu-Yang Chou) | |
| dc.contributor.author | Mei-Hwei Wu | en |
| dc.contributor.author | 吳美慧 | zh_TW |
| dc.date.accessioned | 2021-06-08T05:35:20Z | - |
| dc.date.copyright | 2005-02-17 | |
| dc.date.issued | 2004 | |
| dc.date.submitted | 2005-01-27 | |
| dc.identifier.citation | 參考文獻
王明智。2003。以氧化還原電位控制活性污泥程序數學模式之推導。碩士論文。台北：國立台灣大學農業機械工程學研究所。 杜方裕。1988。二相式厭氧污泥床法處理纖維素之研究。碩士論文。台南：國立成功大學環境工程學研究所。 吳崇彥。1986。反應槽深度對厭氧污泥床法之影響。碩士論文。台南：國立成功大學環境工程學研究所。 莊明賢。1991。固定化細胞處理廢水中含酚類有毒物質之研究。碩士論文。台中：國立中興大學環境工程學研究所。 徐依聖。2001。固定式濾料 (EMMC) 處理堆肥舍臭味之研究。碩士論文。台北：國立台灣大學環境工程學研究所。 許斐凱。1991。二相式厭氧濾床處理抗生素藥廠廢水之研究。碩士論文。台北：國立台灣大學環境工程學研究所。 許梅娟。1987。固定化酵母菌應用於酒精醱酵之動力學模式及質傳效應。碩士論文。台北：國立台灣大學化學工程學研究所。 陳國誠。1991。廢水生物處理學。台北：茂昌。 陳國誠。1989。微生物酵素工程學。台北：藝軒。 陳國誠。1985。生化工程學。台北：國立編譯館。 陳俊廷。2001。利用流體化床反應器進行固定化菌體的染料脫色之研究。碩士論文。新竹：國立清華大學化學工程學研究所。 劉玉琦。1992。擋板式厭氧醱酵槽處理澱粉廢水數學模式之建立。碩士論文。台北：國立台灣大學農業機械工程學研究所。 劉安琪。1996。應用固定化細胞技術處理豬糞尿廢水。碩士論文。台北：國立台灣大學農業機械工程學研究所。 Bailey, J. E. and M. T. C. Chow. 1974.Immobilized enzyme catalysis with reaction-generated pH change, Biotechnol.Bioeng.,16:1345-1348. Bailey, J. E. and Ollis D. F. 1986.Biochemical engineering fundamentals。 Beck, R.E J. S and Schultz. J. S. 1972. Biochim.Biophys. Acta. 255,273. Boon, F .1994 .Influence of pH, High Volatile Fatty Acid Concentrations and Partial Hydrogen Pressure on Hydrolysis. MS thesis ,Wageningen, The Netherlands. Chen, K. C., K. I. Suga and H. Taguchi. 1980. Effects of pore and film diffusion resistances and deactivation of enzyme on the overall reaction rate of immobilized enzyme. Journal of Fermentation Technology, 58, 439-448. Chou, C. Y. 1989. Computer control of and anaerobic reactor utilizing a nonlinear self-turning regulator. Ph. D. Dissertation. The graduate school of the University of Florida. Dold, P.L. and G. V. R. Marais. 1986. Evaluation of the general activated sludge model proposed by the IAWPRC task group. Wat. Sci. Tech. 18:63-89. Levin, Y. and E. Katchalski. 1964. A water-insoluble poly-anionic derivative of trypsin. П. Effect of the polyelectrolyte carrier on the kinetic behavior of boundary typsin .Biochemistry.3.1913-1919. Liang, B.S., X.M. Li. and H.Y. Wang. 1986. Biotechnol.,Pro 2,187. Harvey, W. Blach ., S.Clark. Douglas. 1997.Biochemical Engineering。 McCarty, P. L. 1964. Anaerobic waste treatment fundamentals. Public Works. 95(9): 107-112. Merchant, F. J., A. A. Margaritis and J. B. Wallace. 1987.A novel technique for measuring solute diffusivities in entrapment matrices used in immobilization. Biotechnol. Bioeng. 30, 936-945. Roels, J. A. and N. W. F. Kossen. 1978. On the modeling of microbial metabolism. Prog. Ind. Microbiol.14:45-58. Scott, C. D . 1987. Immobilized cells：a review of recent literature. Enzyme and microbial technology 9(2)：66-73. Siegrist, H. , D. Renggli and W. Gujer. 2002.Mathematical modeling of anaerobic mesophilic sewage sludge treatment.Wat .Sci. Tech. 27, 25-36. Yang, P. Y. and M. L. Wang. 1990.Packed-Entrapped-Mixed Microbial Cells for Small Wastewater Treatment.Wat. Sci. Tech. Vol. 22, No. 3/4, pp. 343-350, 1990. Yang, P. Y., S. Nitisoravut and T.S. See. 1993.Entrapment of Mixed Microbial Cells for water and wastewater treatment. Wat.Sci.Tech Vol.28.No. 7. pp.165-170. Yang, P. Y., S. Nitisoravut and T.S. See. 1994. Applying entrapped mixed microbial cells techniques for biological wastewater treatment.Wat. Sci.Tech Vol.29.No. 10-11. pp. 487-495. Yang, P. Y., Z.Q. Zhang and B.G. Jeong . 1997. Simulataneous removal of carbon and nitrogen using an entrapped-mixed-microbial-cell process,Wat. Res Vol. 31, No. 10, pp. 2617-2625. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/24657 | - |
| dc.description.abstract | 摘 要
劉(1996)以纖維醋酸三酯(Cellulose triacetate)為固定化材質，包覆厭氣污泥製成固定化細胞 (Immobilized cells)，作為處理豬糞尿水填充床(Packed bed)的介質，同時評估氮、磷去除效果及固定化細胞大小對處理效率之影響。 其研究結果顯示，厭氧槽BOD去除率最高達84%，COD為82%。可見在廢水處理上，其為可行的處理法。本研究的目的為，推導以固定化細胞技術處理豬糞尿水之數學模式；並進行電腦模擬並找出最適切的操作條件。 由模擬結果得知運用本研究所推導的數學模式，於系統的生化反應模擬確實可行。本研究除找到描述此系統的生化反應數學模式外，透過敏感度分析了解系統內部相關參數、有效因子、系統物理及顆粒物理條件，對系統生化反應的影響；且透過數學模擬，便可預估反應槽處理效能，以供系統最佳化反應條件的設計參考。 | zh_TW |
| dc.description.abstract | Abstract
Liu(1996) used immobilized cells that was manufactured by entrapping the anaerobic sludge with cellulose triacetate as the media of packed-bed reactors. The objectives of the study are : to investigate the feasibility of using these immobilized cells for swine wastewater treatment, to evaluate its performance in removal of nitrogen and phosphorus, and the effect of the cell size on treatment efficiencies. It was observed that 84% of BOD and 82% of COD removal efficiencies for the anaerobic system. It is a feasible method in wastewater treatment. The purpose of this study is to develop a mathematical model of this system, use the model to predict the variation of the reaction performance and find the optimal operation criteria. It is certainly feasible to use the mathematical model of this study to simulation biochemical reaction in this system. Except finding a feasible mathematical model for this system, by sensitive analysis also show influence of the inner relational parameters, efficiency factor, the physics condition of this system and immobilized cells；We can predict treatment efficiencies by the simulation of mathematical model, and it can offer the reference to find the optimal operation criteria. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-08T05:35:20Z (GMT). No. of bitstreams: 1 ntu-93-R91631028-1.pdf: 2008607 bytes, checksum: 887861bf8113e3889069c424bdbc25a1 (MD5) Previous issue date: 2004 | en |
| dc.description.tableofcontents | 目 錄
標題頁···················································································································Ⅰ 誌謝·····················································································································Ⅱ 摘要·····················································································································Ⅲ 目錄·····················································································································Ⅴ 表目錄·················································································································Ⅵ 圖目錄·················································································································Ⅶ 符號說明··············································································································V 第一章 前言·····································································································1 第二章 文獻探討·····························································································3 2.1 厭氧消化程序·····················································································3 2.2 固定化微生物技術 ···········································································5 2.2.1 固定化方法 ··············································································5 2.2.2 固定化技術之應用 ··································································7 2.2.3 固定化技術製作········································································7 2.2.4 固定化微生物特性 ··································································9 2.3 數學模式 ·························································································17 2.3.1 固定化顆粒擴散質傳······························································17 2.3.2 微生物生長··············································································23 2.3.3 基質消耗轉換··········································································24 2.3.4 槽體垂直擴散效應··································································25 第三章 研究方法···························································································28 3.1 系統描述···························································································28 3.2 研究流程···························································································30 3.3 數學模式···························································································31 3.3.1 基本假設··················································································31 3.3.2 模式推導··················································································32 3.3.3 起始與邊界條件······································································38 3.4 參數確認···························································································39 3.4.1 參數選擇··················································································39 3.4.2 參數選擇演算法······································································40 3.5 數值方法···························································································42 第四章 結果與討論·······················································································45 4.1 模擬結果···························································································45 4.1.1 模式參數 ·······················································································45 4.1.2 各批次模擬結果 ···········································································46 4.2 模式驗證···························································································55 4.3 敏感度分析·······················································································57 4.4 系統實驗模擬···················································································70 4.4.1 固定顆粒表面積······································································70 4.4.2 反應槽淨容積··········································································74 4.4.3 水力停留時間··········································································75 4.4.4 進流基質濃度··········································································79 4.5 固定化顆粒有效因子分析·······························································92 4.4.1 有效因子分析··········································································92 4.4.2 整體有效因子敏感度分析·····················································95 4.6 槽內垂直擴散效應···········································································99 4.6.1 固定顆粒表面積······································································99 4.6.2 反應槽淨容積········································································107 第五章 結論與建議·····················································································111 5.1 結論·································································································111 5.2 建議·································································································113 第六章 參考文獻·························································································114 附錄A : 參數確認程式·················································································118 附錄B : 系統模擬程式·················································································124 附錄C : 固定化顆粒有效因子分析程式·····················································127 附錄D : 槽內垂直擴散效應程式·································································129 表目錄 表2-1 固定化方法表較·················································································6 表2-2 不同材質對細胞內酵素活性之影響···············································13 表2-3 不同材質其分子與材質擴散係數比較···········································14 表3-1 系統模式架構···················································································37 表3-2 前人研究之參數值範圍···································································42 表3-3 本研究選取之參數值範圍·······························································43 表4-1 各批次最佳參數解···········································································45 表4-2 以第一批次參數模擬各批次的相關殘差平方和···························55 表4-3 以第二批次參數模擬各批次的相關殘差平方和···························56 表4-4 以第三批次參數模擬各批次的相關殘差平方和···························56 表4-5 以第五批次參數模擬各批次的相關殘差平方和···························56 表4-6 以第六批次參數模擬各批次的相關殘差平方和···························56 表4-7 以第七批次參數模擬各批次的相關殘差平方和···························57 表4-8 以第各批次參數模擬各批次的相關殘差平方和···························57 表4-9 各參數改變對TSS誤差變化情形···················································69 表4-10 各參數改變對TCOD誤差變化情形···············································69 表4-11 各參數改變對MPR誤差變化情形··················································70 表4-12 各條件改變對MPR誤差變化情形·················································90 表4-13 各條件改變對TCOD誤差變化情形···············································91 表4-14 各條件改變對TSS誤差變化情形···················································91 表4-15 系統顆粒相關係數的數學式···························································94 表4-16 各參數改變對 變化情形·····························································99 表4-17 設計條件改變對TCOD隨槽體高度變化情形·····························110 圖目錄 圖2-1 有機物之厭氧分解流程·····································································4 圖2-2 水解階段後有機物質轉化為甲烷之途徑及佔全體COD之比例·········································································································5 圖2-3 固定化細胞製作流程圖·····································································8 圖2-4 固定化細胞之橫切面圖···································································10 圖2-5 固定化細胞內部槽狀結構·······························································11 圖2-6 非固定與固定或不同濃度對pH值活性曲線·································12 圖2-7 不同pH值對酵素活性之影響·························································12 圖2-8 基質濃度對酵素反應速率圖···························································15 圖2-9 內部顆粒粒徑對反應速度影響圖···················································16 圖2-10 感測器表面基質濃度降分布圖·······················································16 圖2-11 反應器中微生物生長、基質消耗及產物形成示意·························17 圖2-12 基質在顆粒內外部質傳情形···························································18 圖2-13 穩態狀態下顆粒質傳分析圖···························································19 圖2-14 液、固相固定化生物反應器之模式圖···········································26 圖3-1 固定化顆粒實體圖···········································································28 圖3-2 厭氧反應槽系統配置圖···································································29 圖3-3 研究流程圖·······················································································30 圖3-4 修改之Parameter Estimator流程圖················································44 圖4-1 第一批次TSS模擬···········································································46 圖4-2 第一批次TCOD模擬·······································································47 圖4-3 第一批次MPR模擬··········································································47 圖4-4 第二批次TSS模擬···········································································48 圖4-5 第二批次TCOD模擬·······································································48 圖4-6 第二批次MPR模擬·········································································49 圖4-7 第三批次TSS模擬···········································································49 圖4-8 第三批次TCOD模擬·······································································50 圖4-9 第三批次MPR模擬·········································································50 圖4-10 第五批次TSS模擬··········································································51 圖4-11 第五批次TCOD模擬·······································································51 圖4-12 第五批次MPR模擬·········································································52 圖4-13 第六批次TSS模擬··········································································52 圖4-14 第六批次TCOD模擬·······································································53 圖4-15 第六批次MPR模擬·········································································53 圖4-16 第七批次TSS模擬··········································································54 圖4-17 第七批次TCOD模擬·······································································54 圖4-18 第七批次MPR模擬·········································································55 圖4-19 對MPR敏感分度析圖·······························································59 圖4-20 對TSS去除率敏感分度析圖····················································60 圖4-21 對TCOD去除率敏感分度析圖················································60 圖4-22 對MPR敏感分度析圖·································································61 圖4-23 對TSS去除率敏感分度析圖······················································61 圖4-24 對TCOD去除率敏感分度析圖··················································62 圖4-25 對MPR敏感分度析圖·································································62 圖4-26 對TSS去除率敏感分度析圖······················································63 圖4-27 對TCOD去除率敏感分度析圖··················································63 圖4-28 對MPR敏感分度析圖································································64 圖4-29 對TSS去除率敏感分度析圖·····················································64 圖4-30 對TCOD去除率敏感分度析圖·················································65 圖4-31 對MPR敏感分度析·································································65 圖4-32 對TSS去除率敏感分度析圖···················································66 圖4-33 對TCOD去除率敏感分度析圖··············································66 圖4-34 Jb對MPR敏感分度析圖·································································67 圖4-35 Jb對TSS去除率敏感分度析圖·······················································67 圖4-36 Jb對TCOD去除率敏感分度析圖···················································68 圖4-37 不同顆粒總表面積模擬MPR情形(基面積為15000 cm2)·············71 圖4-38 不同顆粒總表面積模擬TSS去除率情形(基面積為15000cm2)····72 圖4-39 不同顆粒總表面積模擬TCOD去除率情形(基面積為15000cm2)72 圖4-40 不同顆粒總表面積模擬MPR情形(基面積為50000 cm2)············73 圖4-41 不同顆粒總表面積模擬TSS去除率情形(基面積為50000cm2)····73 圖4-42 不同顆粒總表面積模擬TCOD去除率情形(基面積為50000cm2)74 圖4-43 不同淨容積對MPR模擬情形(固定HRT)·····································75 圖4-44 不同淨容積對TSS去除率模擬情形(固定HRT)···························76 圖4-45 不同淨容積對TCOD去除率模擬情形(固定HRT) ······················76 圖4-46 不同淨容積對MPR模擬情形(固定進流量)·································77 圖4-47 不同淨容積對TSS去除率模擬情形(固定進流量) ·····················77 圖4-48 不同淨容積對TCOD去除率模擬 (固定進流量) ························78 圖4-49 不同HRT對MPR的模擬情形(固定淨容積) ································79 圖4-50 不同HRT對TSS去除率模擬情形(固定淨容積) ··························80 圖4-51 不同HRT對TCOD去除率模擬 (固定淨容積) ·····························80 圖4-52 不同HRT對MPR的模擬情形(固定進流量) ·································81 圖4-53 不同HRT對TSS去除率模擬情形(固定進流量) ···························81 圖4-54 不同HRT對TCOD去除率模擬 (固定進流量) ···························· 82 圖4-55 不同進流濃度TSS模擬情形(HRT=5)············································82 圖4-56 不同進流濃度TCOD模擬情形(HRT=5)········································83 圖4-57 不同進流濃度對MPR的模擬情形(HRT=5)···································83 圖4-58 不同進流濃度對TSS去除率模擬情形(HRT=5)····························84 圖4-59 不同進流濃度對TCOD去除率模擬 (HRT=5) ····························84 圖4-60 不同進流濃度TSS模擬情形(HRT=10)··········································85 圖4-61 不同進流濃度TCOD模擬情形(HRT=10)······································85 圖4-62 不同進流濃度對MPR的模擬情形(HRT=10)································86 圖4-63 不同進流濃度對TSS去除率模擬情形(HRT=10)·························86 圖4-64 不同進流濃度對TCOD去除率模擬 (HRT=10)····························87 圖4-65 不同進流濃度TSS模擬情形(HRT=15)··········································87 圖4-66 不同進流濃度TCOD模擬情形(HRT=15)······································88 圖4-67 不同進流濃度對MPR的模擬情形(HRT=15)·································88 圖4-68 不同進流濃度對TSS去除率模擬情形(HRT=15)··························89 圖4-69 不同進流濃度對TCOD去除率模擬 (HRT=15) ··························89 圖4-70 有效係數隨顆粒半徑改變的關係圖(固定基質濃)························93 圖4-71 有效係數隨顆粒半徑改變的關係圖(固定顆粒半徑) ···················93 圖4-72 有效係數隨薄膜阻力改變的關係圖···············································95 圖4-73 有效係數隨 改變的關係圖·······················································96 圖4-74 有效係數隨 改變的關係圖·························································97 圖4-75 有效係數隨 改變的關係圖··························································98 圖4-76 有效係數隨 改變的關係圖··························································98 圖4-77 第一批次操作10天後TCOD濃度對槽體高度關係模擬············101 圖4-78 第一批次系統內COD濃度對時間關係模擬································101 圖4-79 第二批次操作10天後TCOD濃度對槽體高度關係模擬············102 圖4-80 第二批次系統內COD濃度對時間關係模擬································102 圖4-81 第三批次操作10天後TCOD濃度對槽體高度關係模擬············103 圖4-82 第三批次系統內COD濃度對時間關係模擬································103 圖4-83 第五批次操作10天後TCOD濃度對槽體高度關係模擬············104 圖4-84 第五批次系統內COD濃度對時間關係模擬·······························104 圖4-85 第六批次操作10天後TCOD濃度對槽體高度關係模擬··········105 圖4-86 第六批次系統內COD濃度對時間關係模擬································105 圖4-87 第七批次操作10天後TCOD濃度對槽體高度關係模擬············106 圖4-88 第七批次系統內COD濃度對時間關係模擬································106 圖4-89 總表面積對TCOD隨槽體高度變化(基準面積為30000 cm2) ··· 108 圖4-90 不同HRT對TCOD隨槽體高度變化情形(固定淨容積) ············108 圖4-91 不同HRT對TCOD隨槽體高度變化模擬情形(固進流量)··········109 圖4-92 不同淨容積對TCOD隨槽體高度變化模擬(固定HRT) ) ···········109 圖4-93 不同淨容積對TCOD隨槽體高度變化模擬情形(固定進流量) ··110 | |
| dc.language.iso | zh-TW | |
| dc.title | 固定化細胞處理豬糞尿水之數學模式 | zh_TW |
| dc.title | The Mathematical Model of Swine Wastewater Treatmeat
by Using the Immobilized-Cell | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 93-1 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 李允中(Yeun-Chung Lee),林達德(Ta-Te Lin) | |
| dc.subject.keyword | 數學模式,固定化細胞, | zh_TW |
| dc.subject.keyword | mathematical model,immobilized cell, | en |
| dc.relation.page | 130 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2005-01-28 | |
| dc.contributor.author-college | 生物資源暨農學院 | zh_TW |
| dc.contributor.author-dept | 生物產業機電工程學研究所 | zh_TW |
| 顯示於系所單位： | 生物機電工程學系 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-93-1.pdf 目前未授權公開取用 | 1.96 MB | Adobe PDF |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。