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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 謝國煌 | |
| dc.contributor.author | Chung-In Lee | en |
| dc.contributor.author | 李忠穎 | zh_TW |
| dc.date.accessioned | 2021-06-08T05:26:18Z | - |
| dc.date.copyright | 2005-07-22 | |
| dc.date.issued | 2005 | |
| dc.date.submitted | 2005-07-20 | |
| dc.identifier.citation | 1. Kohan, M. I., Ed. Nylon Plastics; Wiley: New York, 1973.
2. Hajduk, F. Nylon Fibers. Chemical Economics Handbook; SRI International: Menlo Park, CA, Mar 1-2, 2002. 3. Davenport, R. E.; Riepl, J.; Sasano, T. Nylon Resins. Chemical Economics Handbook; SRI International: Menlo Park, CA, Jul 1-4, 2001. 4. 張超群等，”1999年中華民國高分子工業年度報告”，工業技術研究院化學工程研究所，第3，4 章，民88。 5. 馬振基編著，”高分子複合材料 上冊”，國立編譯館，第1，2，5，12，13，20，21章，民84。 6. Robinson, M. J.; Charette, R. O.; Leonard, B. G. SAMPE Q. 1991, 26-37. 7. Bergmann, H. W. SAMPE Q. 1990, 51-67. 8. Maison, S.; Thibout, C.; Garrigues, C.; Garcin, J.; Payen, H.; Sibois, H.; Coiffer-Colas, C.; Vautey, P.; Boulnois, P. SAMPE J. 1998, 34 (5), 33-39. 9. Stonier, R. A. Int. Encycl. Compos. 1991, 6, 404-430. 10. Kirk, R. E.; Othmer, D. F. Encyclopedia of Chemical Technology; Interscience: New York, 1955; p 10. 11. Leblanc, J.-P, Jois, Y. H. R.; Gibson, H. W. Macromolecules. 1992, 25, 6752-6755. 12. Angelo, R. J.; Miura, H.; Gardner, K. H.; Chase, D. B.; English, A. D. Macromolecules 1989, 22, 117-121. 13. Ueda, M.; Sugiyama, H. Macromolecules 1994, 27, 240-244. 14. Chapman, T. M.; Benrashid, R.; Marra, K. G.; Keener, J. P. Macromolecules 1995, 28, 331-335. 15. Edson Cocchieri Botelho. Macromolecules 2001, 34 , 3367 -3375,. 16. 陳原振,”高溫尼龍”,晉倫公司簡報 17. Rodriguez, F. Principles of Polymer Systems; Washington, DC, 1996. 18. 吳信玠,” Prepartion of microparticles of thermoplastic polymers and their toughening properties”, 台大材料碩士論文 19. Reza Arshady and M. H. George, Polymer. Eng. Sci., Vol.33, No.14,p.856 (1993) 20. E.L. Wittbecker and P. W. Morgan, J.Polymer. Sci., Vol.40, p.289 (1959) 21. P. W. Morgan and S.L. Kwolek, J.Polymer. Sci., Vol.40, p.299 (1959) 22. A. Conix, Ind. Eng. Chem., Vol.51, p.147 (1959) 23. H. Schnell, Ind. Eng. Chem., Vol.51, p.157 (1959) 24. F. Millich and C.E. Carraher, “Interfacial Synthesis-polymer application and technology”, Vol.2(1977) 25. Dietmar Mぴader, Martine Collaud Coen , Jぴorg Kressler , Rolf Mぴulhaupt, Martin Weber, Journal of Applied Polymer Science, v 65, n 3, Jul 18, 1997, p 567-579 26. Roh, I.J. Journal of Membrane Science, v 198, n 1, Mar 31, 2002, p 63-74 27. S. Konagaya *, O. Watanabe, Journal of Applied Polymer Science, v 76, n 2, 2000, p 201-207 28. Abu-Sharkh, B.F. Yahaya, G.O.; Ali, S.A.; Kazi, I.W.,Journal of Applied Polymer Science, v 82, n 2, Oct 10, 2001, p 467-476 29. N. Sarkar, L. D. Kershner, Journal of Applied Polymer Science, v 62, n 2, Oct 10, 1996, p 393-408 30. Rebouillat, S.; Peng, J.C.M.; Donnet, J.-B.Polymer, v 40, n 26, Sep, 1999, p 7341-7350 31. Song, Yujun; Liu, Fuan; Sun, Benhui , Journal of Applied Polymer Science, v 95, n 5, Mar 5, 2005, p 1251-1261 32. Eccleston, M.E.; Slater, N.K.H.; Tighe, B.J. Reactive and Functional Polymers, v 42, n 2, Nov, 1999, p 147-161 33. Ueda, Mitsuru; Sato, Akira; Imai, Yoshio,Journal of Polymer Science, Polymer Chemistry Edition, v 16, n 2, Feb, 1978, p 475-482 34. MacDonald, Robert N.; Sharkey, W. H,Journal of Polymer Science, Polymer Chemistry Edition, v 11, n 10, Oct, 1973, p 2519-2536 35. Mulhaupt, Rolf; Rosch, Joachim ,Polymers for Advanced Technologies, v 5, n 5, May, 1994, p 282-286 36. Diaz, F. R.; Gargallo, L.; Lizana, C.; Gilbert, S., Journal of Polymer Science, Polymer Chemistry Edition, v 17, n 7, Jul, 1979, p 2181-2191 37. Ueda, Mitsuru; Hara, Osamu; Sato, Akira; Imai, Yoshio ,Journal of Polymer Science, Polymer Chemistry Edition, v 17, n 3, Mar, 1979, p 769-775 38. Ueda, Mitsuru; Sato, Akira; Imai, Yoshio, Journal of Polymer Science, Polymer Chemistry Edition, v 16, n 2, Feb, 1978, p 475-482 39. Morgan, Paul W,.Journal of Macromolecular Science - Chemistry, v A15, n 5, Apr, 1980, p 683-399 40. Ogata, Naoya ; Sanui, Kohei; Onozaki, Takao; Imanishi, Shoehei , Journal of Macromolecular Science - Chemistry, v A15, n 5, Apr, 1980, p 1059-1063 41. Hinderer, H. E.; Smith, R. W.; Preston, J, Applied Polymer Symposia, n 2, 1973, p 1-9 | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/24446 | - |
| dc.description.abstract | 本研究中所採行Nylon 6t聚合是以雙醯氯及雙胺之界面聚合的方式，利用醯氯的活性大於酸類的特點並於兩相的溶劑系統之下反應藉以得到Nylon6t的聚合產物。並藉由界面聚合反應，研究醯氯及胺類合成Nylon的反應性。
本研究將以幾種不同的比例，籍改變其反應條件，試著得到最佳的比例配方及反應條件： 1．將不同的胺類依照不同的濃度進行界面聚合反應，觀察聚合產物的分子量，耐熱性之變化。 2．利用改變不同的反應溶劑所合成的Nylon並觀察界面聚合反應產物的分子量、耐熱性之變化情形。 3．改變不同的反應溫度合成Nylon並觀察界面聚合反應後的產物之分子量、耐熱性之變化情形。 將界面聚合反應後之聚合物作分子量、DSC、TGA、等性質測試，並評估本計畫可否用於量產。 | zh_TW |
| dc.description.abstract | This study on nylon6T is from diacid chloride and diamine interfacial polymerization. Producing nylon 6t is even easier if you use a diamine and a diacid chloride instead of a diacid. This is because acid chlorides are much higher reactive than the acids with amine . In order to get the optimized reaction condition of the nylon materials, we will carry out the studies of interfacial polymerization between diacid chloride and diamine.
It seems a good method to tune different kinds of reaction conditions to achieve our final goals: 1. Produce nylon by using diacid chlorides and diamines for Nylon6t polymerization. Measure the properties of the polymerized products. 2. Synthesis nylons with different kinds of biphase solvent systems. Test the mechanical properties and heat-resistance changes. 3．Produce nylon by changing the temperature of the interfacial polymerized reaction. Test the mechanical properties and heat-resistance changes.Compare the results of DSC, TGA, And then estimate this project for the practical application in the industry. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-08T05:26:18Z (GMT). No. of bitstreams: 1 ntu-94-R92549025-1.pdf: 1605639 bytes, checksum: 93032ffe121ec97152b984b2d3ebf7f4 (MD5) Previous issue date: 2005 | en |
| dc.description.tableofcontents | 中文摘要………………………………………………………………1
英文摘要………………………………………………………………2 目錄……………………………………………………………………3 圖索引…………………………………………………………………6 表索引…………………………………………………………………9 第一章 緒論………………………………………………………….11 第二章 文獻回顧…………………………………………………….12 2-1 Nylon6t簡介…………………………………………………...12 2-2 Nylon6t聚合方法………………………………………………19 2-3實驗目的………………………………………………………..21 第三章實驗方法………………………………………………………22 3-1實驗藥品與儀器………………………………………………22 3-1-1 實驗藥品………………………………………………...22 3-1-2 實驗儀器………………………………………………...26 3-2 實驗合成與製備流程………………………………………...28 3-2-1實驗合成…………………………………………………29 (1) Nylon66/6t 共聚合物合成…………………………………29 (2)加入NaOH中和對Nylon6t合成的影響…………………..31 (3)改變醯氯相溶劑對Nylon6t合成的影響…………………..33 (4)改變反應溫度對Nylon6t合成的影響……………………..35 (5)改變反應攪拌速度對合成的影響………………………….37 (6)改變反應方法對Nylon6t合成的影響……………………..39 (7)改變HDA水溶液濃度對合成的影響……………………...43 (8)改變二相溶液濃度對合成的影響………………………….45 (9)HCl酸化對產物的影響……………………………………..47 第四章 結果與討論…………………………………………………..49 4-1 Nylon66/6t 共聚合物合成…………………………………..49 4-2加入NaOH中和對Nylon6t合成的影響…………………..52 4-3改變醯氯相溶劑對Nylon6t合成的影響…………………...55 4-4改變反應溫度對Nylon6t合成的影響……………………...58 4-5改變反應攪拌速度對合成的影響…………………………..61 4-6改變反應方法對Nylon6t合成的影響……………………...63 4-7改變HDA水溶液濃度對合成的影響………………………67 4-8改變二相溶液濃度對合成的影響…………………………..70 4-9 HCl酸化對產物的影響……………………………………...73 第五章 結論………………………………………………………….75 參考文獻……………………………………………………………...78 附錄圖形代號說明……………………………………………………83 | |
| dc.language.iso | zh-TW | |
| dc.subject | 界面聚合 | zh_TW |
| dc.subject | interfacial polymerzation | en |
| dc.title | 界面聚合合成Nylon6t之性質與研究 | zh_TW |
| dc.title | Studies on interfacial polymerization of Nylon 6t | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 93-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 邱文英,韓錦鈴,廖文彬 | |
| dc.subject.keyword | 界面聚合, | zh_TW |
| dc.subject.keyword | interfacial polymerzation, | en |
| dc.relation.page | 105 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2005-07-20 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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