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請用此 Handle URI 來引用此文件: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/23356
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dc.contributor.advisor謝國煌
dc.contributor.authorTung-Lin Linen
dc.contributor.author林東霖zh_TW
dc.date.accessioned2021-06-08T04:59:42Z-
dc.date.copyright2010-08-20
dc.date.issued2010
dc.date.submitted2010-08-17
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dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/23356-
dc.description.abstract本研究的目的為利用鈴木偶合法(Suzuki coupling)合成出一系列新穎的含有卡唑(carbarzole)、苯並噻二唑(Benzothiadiazole)以及噻吩(thiophene)的施體-予體(donor-acceptor)結構的低能隙小分子(CZTHnBTester)。為了延長共軛長度,夾在carbazole和Benzothiadiazole中間的thiophene的個數從一個增加到三個(n=1~3)。從熱重損失分析可以發現三組小分子都有良好的熱穩定性,可以承受元件製程的溫度。這三組小分子在吸收光譜上皆有兩個吸收峰,且成膜後會有明顯的紅移;thiophene的個數增多,吸收光譜也會有相當的紅移發生,有著更廣的吸收。計算出的能隙值則是為1.80到1.98 eV。把PCBM當成予體,CZTH1BTester當做施體去製成的混摻異質接面(bulk heterojunction)太陽能電池元件,最好的效率值為0.24 % ,其中開路電壓(Voc)為0.49 V,短路電流(Jsc)為1.63 mA/cm2,填充因子(FF)為30 %。zh_TW
dc.description.abstractIn this study, a series of novel electron donor-acceptor low-bandgap moleculars (CZTHnBTester) which composed of carbazole, benzothiadiazole, thiophene units were synthesized by Suzuki coupling. To extend its conjugated length, the number of thiophene between carbazole and benzothiadiazole was increased from 1 to 3. In thermogravimetry analysis, the three moleculars were found with good thermal stability. All these moleculars displayed two absorption bands in absorption spectra and exhibit a noticeable red shift when they were in film. Increasing the number of thiophene also caused a evident shift and had broader absorptive ranges. The  optical band gap showed to 1.8 to 1.98 eV by absorption onset. Bulk heterojunction solar cells (PSCs) fabricated with these oligomers as the donor materials and PCBM as the acceptor material exhibited best power conversion efficiencies up to 0.24 % with the open circuit voltages of 0.49 V, short circuit currents of 1.63 mA/cm2 and fill factor of 30 %.en
dc.description.provenanceMade available in DSpace on 2021-06-08T04:59:42Z (GMT). No. of bitstreams: 1
ntu-99-R97549020-1.pdf: 1808591 bytes, checksum: 801c34551f9c73093ed443be5edb9ddb (MD5)
Previous issue date: 2010
en
dc.description.tableofcontents摘要 I
Absract II
目錄 III
表目錄 V
圖目錄 VI
第一章 緒論 1
1-1 前言 1
1-2 研究動機 1
第二章 文獻回顧 3
2-1 有機太陽能電池的歷史 3
2-2 有機太陽能電池的原理 4
2-2-1 光子的吸收 4
2-2-2 激子的擴散及分離 5
2-2-3 電荷的傳導 5
2-3 有機太陽能電池的特性曲線 5
2-3-1 短路電流(short-circuit current, Jsc) 6
2-3-2 開路電壓(Open-circuit voltage,Voc) 7
2-3-3 填充因子(Fill factor, FF) 7
2-4 有機太陽能電池的種類 8
2-4-1 以材料分類 8
2-4-2 以結構分類 9
2-4-2-1 單層結構 9
2-4-2-2 雙層異質接面結構 10
2-4-2-3 混摻異質接面結構 10
2-5 小分子太陽能電池材料 11
2-5-1 樹狀體(dendrimer)結構之小分子 11
2-5-2 寡聚物結構之小分子 12
2-5-3 含有施體-予體結構之小分子 13
第三章 實驗部份 18
3-1 實驗藥品 18
3-2 實驗儀器 22
3-3 實驗步驟 24
3-3-1 合成步驟 24
3-3-2 各化合物之合成 27
第四章 結果與討論 42
4-1 合成步驟之討論 42
4-2 熱性質分析 42
4-2-1 微差掃描熱卡計分析(DSC) 42
4-2-2 熱重損失分析(TGA) 44
4-3 光學性質分析 45
4-4電化學性質分析 49
4-5 太陽能電池元件性質分析 51
第五章 結論 54
參考文獻 55
附錄:化合物之1H-NMR圖譜 58
dc.language.isozh-TW
dc.title含卡唑及苯並噻二唑小分子之合成、特性及其於有機太陽能電池應用上之研究zh_TW
dc.titleSynthesis and Properties of Moleculars Containing Carbazole and Benzothiadiazole for Organic Solar Cellsen
dc.typeThesis
dc.date.schoolyear98-2
dc.description.degree碩士
dc.contributor.oralexamcommittee王怡仁,韓錦鈴,郭昭輝,黃智楷
dc.subject.keyword鈴木偶合法,施體-予體,低能隙,混摻異質接面,太陽能電池,zh_TW
dc.subject.keywordSuzuki coupling,donor-acceptor,low band gap,bulk heterojunction,solar cell,en
dc.relation.page72
dc.rights.note未授權
dc.date.accepted2010-08-18
dc.contributor.author-college工學院zh_TW
dc.contributor.author-dept高分子科學與工程學研究所zh_TW
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