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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 林俊彬 | |
dc.contributor.author | Ting-Hsuan Chen | en |
dc.contributor.author | 陳庭萱 | zh_TW |
dc.date.accessioned | 2021-06-08T04:42:34Z | - |
dc.date.copyright | 2009-08-12 | |
dc.date.issued | 2009 | |
dc.date.submitted | 2009-08-06 | |
dc.identifier.citation | (1) Gratzel, Michael, Photoelectrochemical cells. Nature 414 (6861), 338 (2001).
(2) D. M. Chapin, C. S. Fuller, G. L. Pearson, J. Appl. Phys. 25, 676 (1954) (3) Markvart, T., Solar Electricity, 2nd ed. (John Wiley & Sons, 2000). (4) Green, Martin A., Photovoltaic principles. Physica E: Low-dimensional Systems and Nanostructures 14 (1-2), 11 (2002). (5) S.Nakamura,KRI Report No. 8 of phase XVI,KRI,nc.,Japan(2005) (6) R.H.Bube,Photovoltaic Material,Imperia College Press,London(1998) (7) A. J. Bard, “Photoelectrochemistry,” Science, 207, 139-144 (1980). (8) N. S. Lewis, “Artificial photosynthesis,” Am. Sci., 83, 534-541 (1995). (9) 黃建昇﹐”結晶矽太陽電池發展近況”﹐工業材料雜誌203期﹐150 (2003) (10) 第6屆全國工業發展會議記錄﹐”加速推動太陽光電產業發展策略”﹐經濟部能源局 (2007) (11) D. M. Chapin, C. S. Fuller, G. L. Pearson, A new silicon p-n junction photocell for converting solar radiation into electrical power. Journal of Applied Physics 25, 676 (1954). (12) Reynolds, D. C., Leies, G., Antes, L. L., and Marburger, R. E., Photovoltaic Effect in Cadmium Sulfide. Physical Review 96 (2), 533 (1954). (13) Jenny, D. A., Loferski, J. J., and Rappaport, P., Photovoltaic Effect in GaAs p-n Junctions and Solar Energy Conversion. Physical Review 101 (3), 1208 (1956). (14) Stoger, M. et al., Investigation of defect formation and electronic transport in microcrystalline silicon deposited by hot-wire CVD. Physica B: Condensed Matter 273-274, 540 (1999). (15) Fujishima, Akira and Honda, Kenichi, Electrochemical Photolysis of Water at a Semiconductor Electrode. Nature 238 (5358), 37 (1972). (16) Amadelli, R., Argazzi, R., Bignozzi, C. A., and Scandola, F., Design of antenna-sensitizer polynuclear complexes. Sensitization of titanium dioxide with [Ru(bpy)2(CN)2]2. Journal of the American Chemical Society 112 (20), 7099 (1990). (17) C. W. Tang, “Two-Layer Organic Photovoltaic Cell,” Applied physics Letters, 48, 183 (1986). (18) O'Regan, Brian and Gratzel, Michael, A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature 353 (6346), 737 (1991). (19) Spanggaard, Holger and Krebs, Frederik C., A brief history of the development of organic and polymeric photovoltaics. Solar Energy Materials and Solar Cells 83 (2-3), 125 (2004). (20) J. Xue, B. Rand S. Uchida S. Forrest, A Hybrid Planar-Mixed Molecular Heterojunction Photovoltaic Cell. Advanced Materials 17 (1), 66 (2005). (21) Nazeeruddin, M. K., Efficient panchromatic sensitization of nanocrystalline TiO2 films by a black dye based on a trithiocyanato Ruthenium complex. Chemical Communications (18), 1705 (1997). (22) Fang, Jinghuai et al., The photovoltaic study of co-sensitized microporous TiO2 electrode with porphyrin and phthalocyanine molecules. Applied Surface Science 119 (3-4), 237 (1997). (23) Clifford, J. N. et al., Multistep Electron Transfer Processes on Dye Co-sensitized Nanocrystalline TiO2 Films. J. Am. Chem. Soc. 126 (18), 5670 (2004). (24) Masaru Yanagisawa, Ferenc Korodi, Jianjun He, Licheng Sun, Villy Sundström and Björn Åkermark, Ruthenium phthalocyanines with axial carboxylate ligands.Synthesis and function in solar cells based on nanocrystalline TiO2. J. Porphyrins Phthalocyanines .6: 217-224(2002) (25) Nazeeruddin,Md K. et al.,Acid-Base Equilibria of (2,2'-Bipyridyl-4,4'-dicarboxylic acid)ruthenium(II) Complexes and the Effect of Protonation on Charge-Transfer Sensitization of Nanocrystalline Titania. Inorg. Chem. 38 (26), 6298 (1999). (26) A. Fujishima, K. Honda, Nature 238, 37-38 (1972) (27) A. L. Linsebigler, G. Lu, J. T. Yates, Chem. Rev. 95, 735 (1995) (28) K. M. Reddy, S. V. Manorama, A. R. Reddy, Mater. Chem. and Phy.78, 239-245 (2002) (29) Rawling, Tristan and McDonagh, Andrew, Ruthenium phthalocyanine and naphthalocyanine complexes: Synthesis, properties and applications. Coordination Chemistry Reviews 251 (9-10), 1128 (2007). (30) Xiao, H., 半導體程技術概論, 2nd ed. (學銘圖書有限公司, 2002). (31) Madhusudan Reddy, K., Manorama, Sunkara V., and Ramachandra Reddy, A., Bandgap studies on anatase titanium dioxide nanoparticles. Materials Chemistry and Physics 78 (1), 239 (2003); Nagaveni, K. et al (32) Polo, Andr Sarto, Itokazu, Melina Kayoko, and Murakami Iha, Neyde Yukie, Metal complex sensitizers in dye-sensitized solar cells. Coordination Chemistry Reviews 248 (13-14), 1343 (2004). (33) Bignozzi, C. A., Molecular and supramolecular sensitization of nanocrystalline wide band-gap semiconductors with mononuclear and polynuclear metal complexes. Chemical Society Reviews 29 (2), 87 (2000). (34) P. Wang, S. zakeeruddin J. Moser R. Humphry-Baker P. Comte V. Aranyos A. Hagfeldt M. Nazeeruddin M. Gratzel, Stable New Sensitizer with Improved Light Harvesting for Nanocrystalline Dye-Sensitized Solar Cells. Advanced Materials 16 (20), 1806 (2004). (35) D. Cahen, G. Hodes, M. Gratzel, J. F. Guillemoles, I. Riess, J. Phys. Chem. B 104, 2053 (2000). (36) Neil, Robertson, Optimizing Dyes for Dye-Sensitized Solar Cells. Angewandte Chemie International Edition 45 (15), 2338 (2006). (37) Bauer, C., Interfacial Electron-Transfer Dynamics in Ru (tcterpy)(NCS)~ 3-Sensitized TiO2 Nanocrystalline Solar Cells. Journal of Physical Chemistry, The 106 (49), 12693 (2002). (38) Nazeeruddin, Md K., Humphry-Baker, R., Liska, P., and Gratzel, M., Investigation of Sensitizer Adsorption and the Influence of Protons on Current and Voltage of a Dye-Sensitized Nanocrystalline TiO2 Solar Cell. The Journal of Physical Chemistry B 107 (34), 8981 (2003). (39) G. Redmond, D. Fitzmaurice, J. phys. Chem. 97, 1426 (1993). (40) 化學通報 68, (2005). (41) 姚慶意, 化學技術 7, (1999). (42) U. Bach, Nature 395, 583 (1998). (43) V. P. S. P. K. Tennakone, I. R. M. Kottegoda and Grra Kumara Journal of Physics D: Applied Physics 32, 374 (1999). (44) F. Cao, G. Oskam, P. C. Searson, J. phys. Chem. 99, 17071 (1995). (45) A. F. Nogueira, M.-A. De Paoli, Solar Energy Materials and Solar Cells 61, 135 (2000). (46) Y. Saito et al., Electrochemistry Communications 6, 71 (2004). (47) T. Kitamura, M. Maitani, M. Matsuda, Y. Wada, S. Yanagida, Chemistry Letters 30, 1054 (2001). (48) T. Stergiopoulos, I. M. Arabatzis, G. Katsaros, P. Falaras, Nano Lett. 2, 1259 (2002). (49) W. Kubo, T. Kitamura, K. Hanabusa, Y. Wada, S. Yanagida, Chemical Communications, 374 (2002). (50) J. R. D. M. A. D. P. A. F. Nogueira, Advanced Materials 13, 826 (2001). (51) K. Seoung Hoon, J. James, L. Jiwon, K. Kang-Jin, Journal of The Electrochemical Society 152, A1378 (2005). (52) M. Biancardo, K. West, F. C. Krebs, Solar Energy Materials and Solar Cells 2575 (2006). (53) E. Stathatos, P. Lianos, C. Krontiras, J. Phys. Chem. B 105, 3486 (2001). (54) Zakeeruddin, S. M. et al., Design, Synthesis, and Application of Amphiphilic Ruthenium Polypyridyl Photosensitizers in Solar Cells Based on Nanocrystalline TiO2 Films. Langmuir 18 (3), 952 (2002); Wang, Peng et al., (55) Kay, Andreas and Gratzel, Michael, Low cost photovoltaic modules based on dye sensitized nanocrystalline titanium dioxide and carbon powder. Solar Energy Materials and Solar Cells 44 (1), 99 (1996). (56) Mclntyre, B. George and P., Analytical Chemistry by Open Learning. (John Wiley and Sons,). (57) The Praying MantisTM User’s Manual. (HARRIC Scientific Corporation, 2002). (58) Hsu, Y. C., National Taiwan University, 2005. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/23113 | - |
dc.description.abstract | 本研究的主要目的是探討染料共敏化現象在染料敏化太陽能電池中的影響。
以DSSC而言,光電轉換效率取決於染料可吸收的光波長範圍以及電子轉移速率。一般DSSC使用的染料主要光吸收範圍約在400nm-600nm,在紅光區的吸收表現已呈疲態。因此本研究欲利用混摻染料以達到延伸吸收光波長範圍,進而提昇DSSC的效率。 實驗上合成主要吸收波段為紅光區的酞花青染料bis(4-carboxypyridine)- (phthalocyanainato) ruthenium(II)以及選用了常見的聯吡啶釕錯合物染料N719(cis-di(thiocyanato)-bis(2,2'-bipyridyl -4,4'-dicarboxylic acid)-ruthenium(II))以及,混摻製作共敏化DSSC。 以合成的酞花青染料(bis(4-carboxypyridine)-(phthalocyanainato) ruthenium(II) 與市售之N719作混摻後,發現成功提升了約為原來混摻前效率的10%, | zh_TW |
dc.description.abstract | The main purpose of this research is to study co-sensitization in the dye-sensitized solar cell (DSSC) .
For DSSC, photon-to-electron conversion efficiency is depending on the dye absorption spectrum and the shifting rate of electron from dye to electrode. The absorption UV-vis spectrum of dyes in DSSC is generally in 400nm-600nm region ,but it is weak beyond 600nm.Therefore ,in this study we blend dyes in order to extend the range of light absorption and improve the efficiency of DSSC further. The common phthalcyano ruthenium complex, bis(4-carboxypyridine) -(phthalocyanainato) ruthenium(II) in near IR region are chosen to fabricate co-sensitized DSSC .ruthenuim complex, N719 (cis-di(thiocyanato)-bis(2,2'-bipyridyl -4,4'-dicarboxylic acid)-ruthenium(II)) in blue light region, and We want to extend light absorption and improve efficientcy by this process. The results reveal that the energy band of N719 and bis(4-carboxypyridine) -(phthalocyanainato) ruthenium(II) can macth well.So the efficiency of DSSCs is enhancing near 10%. | en |
dc.description.provenance | Made available in DSpace on 2021-06-08T04:42:34Z (GMT). No. of bitstreams: 1 ntu-98-R96549019-1.pdf: 8475115 bytes, checksum: 441e5584dda6a1d23ba1a8a113b159c3 (MD5) Previous issue date: 2009 | en |
dc.description.tableofcontents | 摘要 I
Abstract II 目錄 III 圖目錄 VI 表目錄 VIII 第1章 緒論 1 1-1 前言 1 1-2 太陽能電池的種類 2 1-2-1 矽晶太陽能電池(9)(10) 5 1-2-2 光化學太陽能電池 9 1-2-3 染料敏化太陽能電池 10 1-2-4 有機太陽能電池 14 1-3 光電轉換效率簡介 16 1-4 研究動機與目的 19 第2章 實驗原理與文獻回顧 22 2-1 半導體簡介 22 2-1-1 能帶結構與費米能階 25 2-1-2 染料敏化太陽能電池原理 28 2-1-3 電子-電洞對的分離與傳輸 31 2-2 二氧化鈦 34 2-3 光敏化染料 35 2-3-1 染料工作原理 36 2-3-2 釕錯合物 38 2-4 電解質(40) 43 2-4-1 非水溶液電解液 44 2-4-2 固態電解液 45 2-4-3 擬固態電解液 45 2-5 反電極 46 第3章 實驗設備與方法 47 3-1 實驗藥品與材料 47 3-2 實驗設備 48 3-3 實驗流程 49 3-3-1 實驗物品的預處理 49 3-3-2 酞花青釕錯合物染料 Bis(4-carboxypyridine)-phthalocyaninatoruthenium(II)之製備 50 3-3-2-1 PcRu之合成 50 3-3-2-2 Bis(4-carboxypyridine)-phthalocyaninatoruthenium(II)之合成 52 3-3-3 白金反電極之製備 54 3-3-4 二氧化鈦/染料薄膜電極製備 54 3-3-4-1 二氧化鈦薄膜之製備 54 3-3-4-2 二氧化鈦/N719染料薄膜電極製備 54 3-3-4-3 二氧化鈦/ Bis(4-carboxypyridine)-phthalocyaninatoruthenium(II)染料薄膜電極製備 55 3-3-4-4 二氧化鈦/N719/ Bis(4-carboxypyridine)-PcRu(II)染料薄膜電極製備 55 3-3-5 電解液之製備 56 3-3-6 染料敏化太陽能電池組裝 56 3-4 染料性質分析與測試 58 3-4-1 Bruker Avance-500 MHz 液態超導核磁共振儀 58 3-4-2 紫外光/可見光吸收光譜儀 (UV/Vis Spectrometer) 61 3-4-3 循環伏安儀 (Cyclic Voltammetry) 62 3-5 二氧化鈦薄膜性質分析與測試 62 3-5-1 高溫爐 62 3-5-2 傅立葉轉紅外線光譜儀 (FT-IR) 62 3-6 染料敏化太陽能電池效率測試 64 3-6-1 光電轉換效率量測系統 64 第4章 實驗結果與討論 66 4-1 染料性質討論 66 4-1-1 Bis(4-carboxypyridine)-phthalocyaninatoruthenium(II) 氫核磁共振光譜圖 66 4-1-2 染料吸收光譜(UV-vis spectrum) 67 4-1-3 循環伏安圖(Cyclic Voltammogram) 68 4-1-4 葉轉換紅外光吸收光譜圖(FT-IR) 70 4-2 二氧化鈦薄膜性質討論 73 4-2-1 吸收光譜(UV-vis spectrum) 73 4-2-2 循環伏安圖(Cyclic Voltammogram) 75 4-2-3 傅立葉轉換紅外光吸收光譜圖(FT-IR) 77 4-3 染料敏化太陽能電池效率 81 第5章 結論與建議 84 5-1 結論 84 5-2 建議 86 參考文獻 87 | |
dc.language.iso | zh-TW | |
dc.title | 酞花青染料之於染料敏化太陽能電池的應用與探討 | zh_TW |
dc.title | Study and Application of Phthalocyanato Ruthenium Dye for Dye-Sensitized Solar Cells | en |
dc.type | Thesis | |
dc.date.schoolyear | 97-2 | |
dc.description.degree | 碩士 | |
dc.contributor.coadvisor | 陳兆勛 | |
dc.contributor.oralexamcommittee | 謝國煌 | |
dc.subject.keyword | 染料敏化太陽能電池,共敏化,染料混摻,釕錯合物, | zh_TW |
dc.subject.keyword | dye-sensitized solar cell,co-sensitized,blending dye,phthalcyano ruthenium complex, | en |
dc.relation.page | 92 | |
dc.rights.note | 未授權 | |
dc.date.accepted | 2009-08-07 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
顯示於系所單位: | 高分子科學與工程學研究所 |
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