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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱勝賢 | |
| dc.contributor.author | Wei-Fan Chen | en |
| dc.contributor.author | 陳韋帆 | zh_TW |
| dc.date.accessioned | 2021-06-08T04:20:45Z | - |
| dc.date.copyright | 2010-07-21 | |
| dc.date.issued | 2010 | |
| dc.date.submitted | 2010-07-16 | |
| dc.identifier.citation | 1. Muller-Dethlefs, K.; Hobza, P. Chem. Rev. 2000, 100, 143.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/22557 | - |
| dc.description.abstract | 我們試圖以resorcinarene為基礎，結合冠醚系統來建構出一個具有三維內部空腔的分子容器；並希望藉由resorcinarene與多種客體的鍵結，使此一分子容器得以展現出較本實驗室已發表之以CTV為基底的主體分子更為多樣化的客體鍵結特性。 | zh_TW |
| dc.description.abstract | A new molecular container composed by resorcinarenes and crown ethers is proposed. Because resorcinarenes are capable of binding different guests, we expect that this new molecular container will be a great host for guest complexation. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-08T04:20:45Z (GMT). No. of bitstreams: 1 ntu-99-R97223143-1.pdf: 9166574 bytes, checksum: 7c5481021f6e301499d8672d2fc8eca0 (MD5) Previous issue date: 2010 | en |
| dc.description.tableofcontents | 謝誌 .............................................................. I
摘要 ............................................................. II 總目錄 .......................................................... IV 圖目錄 .......................................................... VI 式目錄 .......................................................... IX 表目錄 ........................................................... X 第零章 前言 ..................................................... 1 超分子化學簡介 ................................................ 2 第一章 以Resorcinarene為基礎的分子容器合成研究 .................. 4 壹、文獻回顧 .................................................... 5 1.1.1 冠醚、芳杯與分子監獄之主體系統 ............................ 5 1.1.1.1 冠醚系統之發展 ........................................ 5 1.1.1.2 芳杯系統簡介 .......................................... 10 1.1.1.3 分子監獄簡介 .......................................... 11 1.1.2 Resorcinarene相關研究之發展 ................................ 13 1.1.2.1 Resorcinarene 之起源 .................................... 13 1.1.2.2 Resorcinarene 之錯合研究 ................................ 14 1.1.2.3 Resorcinarene 的自組裝現象 .............................. 17 1.1.2.4 以 Resorcinarene 為基底之穴狀物與分子監獄 ............... 20 貳、結果與討論 .................................................. 22 1.2.1 研究動機 ................................................. 22 1.2.2 逆合成解析 ............................................... 23 1.2.3 分子容器之合成 ........................................... 26 參、結論 ........................................................ 31 第二章 掌性雙環胍鹽分子的合成與研究 ............................ 32 壹、文獻回顧 ................................................... 33 2.1.1 內鎖型分子簡介 ......................................... 33 2.1.2 環連體之合成方法 ......................................... 34 2.1.3胍鹽於分子辨識之相關研究 ................................. 36 2.1.3.1 具胍鹽基之分子辨識系統 ................................ 36 2.1.3.2 雙環胍鹽系統之發展 .................................... 40 貳、結果與討論 .................................................. 45 2.2.1 研究動機 ................................................. 45 2.2.2 逆合成解析 ............................................... 47 2.2.3 掌性雙環胍鹽分子之合成 ................................... 49 2.2.4 鍵結測試 ................................................. 53 參、結論 ........................................................ 56 附錄一、實驗細節 ................................................. 57 附錄二、參考文獻 ................................................. 68 | |
| dc.language.iso | zh-TW | |
| dc.subject | 超分子 | zh_TW |
| dc.subject | supramolecular | en |
| dc.title | 新型分子容器與分子辨識系統之發展與研究 | zh_TW |
| dc.title | Toward a New Molecular Container and a Molecular Recognition System | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 98-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 徐秀福,賴建成 | |
| dc.subject.keyword | 超分子, | zh_TW |
| dc.subject.keyword | supramolecular, | en |
| dc.relation.page | 75 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2010-07-16 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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