請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/20827
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 陳賢燁(Hsien-Yeh Chen) | |
dc.contributor.author | Hsing-Ying Tung | en |
dc.contributor.author | 童星穎 | zh_TW |
dc.date.accessioned | 2021-06-08T03:05:34Z | - |
dc.date.copyright | 2017-08-04 | |
dc.date.issued | 2017 | |
dc.date.submitted | 2017-07-05 | |
dc.identifier.citation | 1. Szwarc, M., New monomers of the quinoid type and their polymers. Journal of Polymer Science, 1951. 6(3): p. 319-329.
2. Szwarc, M., Some remarks on the CH 2 [graphic omitted] CH 2 molecule. Discussions of the Faraday Society, 1947. 2: p. 46-49. 3. Szwarc, M., The C–H bond energy in toluene and xylenes. The Journal of Chemical Physics, 1948. 16(2): p. 128-136. 4. Gorham, W.F., A New, General Synthetic Method for the Preparation of Linear Poly‐p‐xylylenes. Journal of Polymer Science Part A‐1: Polymer Chemistry, 1966. 4(12): p. 3027-3039. 5. Loeb, G., et al., Histological reaction to various conductive and dielectric films chronically implanted in the subdural space. Journal of Biomedical Materials Research Part A, 1977. 11(2): p. 195-210. 6. Grzybowski, B., et al., Generation of micrometer-sized patterns for microanalytical applications using a laser direct-write method and microcontact printing. Analytical Chemistry, 1998. 70(22): p. 4645-4652. 7. Duffy, D.C., et al., Rapid prototyping of microfluidic systems in poly (dimethylsiloxane). Analytical chemistry, 1998. 70(23): p. 4974-4984. 8. Ionescu, M.A., et al., Parylene-N a Better Candidate for Medical Substrate Coating than Parylene-C. Revista De Chimie, 2015. 66(12): p. 1925-1928. 9. Lahann, J. and R. Langer, Novel poly (p-xylylenes): thin films with tailored chemical and optical properties. Macromolecules, 2002. 35(11): p. 4380-4386. 10. Lahann, J., et al., Reactive polymer coatings: a first step toward surface engineering of microfluidic devices. Analytical chemistry, 2003. 75(9): p. 2117-2122. 11. Lahann, J., et al., A new method toward microengineered surfaces based on reactive coating. Angewandte Chemie International Edition, 2001. 40(17): p. 3166-3169. 12. Lahann, J., H. Höcker, and R. Langer, Synthesis of Amino [2.2] paracyclophanes—beneficial monomers for bioactive coating of medical implant materials. Angewandte Chemie International Edition, 2001. 40(4): p. 726-728. 13. Lahann, J., D. Klee, and H. Höcker, Chemical vapour deposition polymerization of substituted [2.2] paracyclophanes. Macromolecular Rapid Communications, 1998. 19(9): p. 441-444. 14. Nandivada, H., H.Y. Chen, and J. Lahann, Vapor‐Based Synthesis of Poly [(4‐formyl‐p‐xylylene)‐co‐(p‐xylylene)] and Its Use for Biomimetic Surface Modifications. Macromolecular rapid communications, 2005. 26(22): p. 1794-1799. 15. Nandivada, H., et al., Reactive polymer coatings that “click”. Angewandte Chemie International Edition, 2006. 45(20): p. 3360-3363. 16. Chen, H.-Y. and J. Lahann, Designable biointerfaces using vapor-based reactive polymers. Langmuir, 2010. 27(1): p. 34-48. 17. Jiang, X., et al., Vapor‐Based Initiator Coatings for Atom Transfer Radical Polymerization. Advanced Functional Materials, 2008. 18(1): p. 27-35. 18. Qu, Z., et al., A biologically active surface enzyme assembly that attenuates thrombus formation. Advanced functional materials, 2011. 21(24): p. 4736-4743. 19. Tenhaeff, W.E. and K.K. Gleason, Initiated and oxidative chemical vapor deposition of polymeric thin films: iCVD and oCVD. Advanced Functional Materials, 2008. 18(7): p. 979-992. 20. Chen, H.-Y. and J. Lahann, Fabrication of discontinuous surface patterns within microfluidic channels using photodefinable vapor-based polymer coatings. Analytical chemistry, 2005. 77(21): p. 6909-6914. 21. Author, A., Novel porous materials for emerging applications. 2006, Royal Society of Chemistry. 22. Davis, M.E., Ordered porous materials for emerging applications. Nature, 2002. 417(6891): p. 813-821. 23. He, X. and D. Antonelli, Synthesen und Anwendungen von übergangsmetallhaltigen mesoporösen Molekularsieben. Angewandte Chemie, 2002. 114(2): p. 222-238. 24. Seo, J.S., et al., A homochiral metal-organic porous material for enantioselective separation and catalysis. Nature, 2000. 404(6781): p. 982-986. 25. Jing, Z. and J. Zhan, Fabrication and gas-sensing properties of porous ZnO nanoplates. Adv. Mater., 2008. 20(23): p. 4547-4551. 26. Guo, Y.-G., J.-S. Hu, and L.-J. Wan, Nanostructured materials for electrochemical energy conversion and storage devices. Adv. Mater., 2008. 20(15): p. 2878-2887. 27. Perez-Ramirez, J., et al., Hierarchical zeolites: enhanced utilisation of microporous crystals in catalysis by advances in materials design. Chem. Soc. Rev., 2008. 37(11): p. 2530-2542. 28. Braun, P.V. and P. Wiltzius, Microporous materials: Electrochemically grown photonic crystals. Nature, 1999. 402(6762): p. 603-604. 29. Horcajada, P., et al., Porous metal-organic-framework nanoscale carriers as a potential platform for drug delivery and imaging. Nat. Mater., 2010. 9(2): p. 172-178. 30. Hollister, S.J., Porous scaffold design for tissue engineering. Nat. Mater., 2005. 4(7): p. 518-524. 31. Yabu, H. and M. Shimomura, Single-step fabrication of transparent superhydrophobic porous polymer films. Chemistry of materials, 2005. 17(21): p. 5231-5234. 32. Chai, G.S., et al., Ordered porous carbons with tunable pore sizes as catalyst supports in direct methanol fuel cell. The Journal of Physical Chemistry B, 2004. 108(22): p. 7074-7079. 33. Martín, J., et al., Ordered three-dimensional interconnected nanoarchitectures in anodic porous alumina. Nat. Commun., 2014. 5: p. 5130. 34. Bryant, S.J., et al., Photo-patterning of porous hydrogels for tissue engineering. Biomaterials, 2007. 28(19): p. 2978-2986. 35. Unterlass, M.M., Creating geomimetic polymers. Mater. Today, 2015. 18(5): p. 242-243. 36. Tumbleston, J.R., et al., Continuous liquid interface production of 3D objects. Science, 2015. 347(6228): p. 1349-1352. 37. Gauvin, R., et al., Microfabrication of complex porous tissue engineering scaffolds using 3D projection stereolithography. Biomaterials, 2012. 33(15): p. 3824-3834. 38. Subbiah, T., et al., Electrospinning of nanofibers. J. Appl. Polym. Sci., 2005. 96(2): p. 557-569. 39. Moutos, F.T., L.E. Freed, and F. Guilak, A biomimetic three-dimensional woven composite scaffold for functional tissue engineering of cartilage. Nat. Mater., 2007. 6(2): p. 162-167. 40. Gratson, G.M., M. Xu, and J.A. Lewis, Microperiodic structures: Direct writing of three-dimensional webs. Nature, 2004. 428(6981): p. 386-386. 41. Alf, M.E., et al., Chemical vapor deposition of conformal, functional, and responsive polymer films. Adv. Mater., 2010. 22(18): p. 1993-2027. 42. Chen, Y.-C., et al., Sustained immobilization of growth factor proteins based on functionalized parylenes. ACS Appl. Mater. Interfaces, 2014. 6(24): p. 21906-21910. 43. Wu, J.T., et al., Reactive Polymer Coatings: A General Route to Thiol‐ene and Thiol‐yne Click Reactions. Macromolecular rapid communications, 2012. 33(10): p. 922-927. 44. Tsai, M.-Y., et al., Vapor-based synthesis of maleimide-functionalized coating for biointerface engineering. Chemical Communications, 2012. 48(89): p. 10969-10971. 45. Gorham, W.F., A new, general synthetic method for the preparation of linear poly-p-xylylenes. J. Polymer Sci. 1A, 1966. 4(12): p. 3027-3039. 46. Fortin, J.B. and T.M. Lu, A model for the chemical vapor deposition of poly(para-xylylene) (parylene) thin films. Chem. Mater., 2002. 14(5): p. 1945-1949. 47. Vaeth, K.M. and K.F. Jensen, Transition metals for selective chemical vapor deposition of parylene-based polymers. Chem. Mater., 2000. 12(5): p. 1305-1313. 48. Wu, C.-Y., et al., Electrically charged selectivity of poly-para-xylylene deposition. Chem. Commun., 2016. 52(14): p. 3022-3025. 49. Chen, H.-Y., et al., Substrate-independent dip-pen nanolithography based on reactive coatings. J. Am. Chem. Soc., 2010. 132(51): p. 18023-18025. 50. Wu, J.-T., et al., Customizable optical and biofunctional properties of a medical lens based on chemical vapor deposition encapsulation of liquids. Chem. Mater., 2015. 27(20): p. 7028-7033. 51. Charlson, E.M., E.J. Charlson, and R. Sabeti, Temperature selective deposition of parylene-C. IEEE T. Biomed. Eng., 1992. 39(2): p. 202-206. 52. Reina, A., et al., Large area, few-layer graphene films on arbitrary substrates by chemical vapor deposition. Nano Lett., 2009. 9(1): p. 30-35. 53. Asatekin, A., et al., Designing polymer surfaces via vapor deposition. Materials Today, 2010. 13(5): p. 26-33. 54. Franks, F., Freeze-drying of bioproducts: putting principles into practice. European Journal of Pharmaceutics and Biopharmaceutics, 1998. 45(3): p. 221-229. 55. Oh, S.H., T.H. Kim, and J.H. Lee, Creating growth factor gradients in three dimensional porous matrix by centrifugation and surface immobilization. Biomaterials, 2011. 32(32): p. 8254-8260. 56. Tang, X. and M.J. Pikal, Design of freeze-drying processes for pharmaceuticals: practical advice. Pharm. Res., 2004. 21(2): p. 191-200. 57. Chang, T.Y., et al., Cell and protein compatibility of parylene-C surfaces. Langmuir, 2007. 23(23): p. 11718-11725. 58. Barton, T.J., et al., Tailored porous materials. Chemistry of Materials, 1999. 11(10): p. 2633-2656. 59. Keskin, S., T.M. van Heest, and D.S. Sholl, Can Metal–Organic Framework Materials Play a Useful Role in Large‐Scale Carbon Dioxide Separations? ChemSusChem, 2010. 3(8): p. 879-891. 60. Li, J.-R., R.J. Kuppler, and H.-C. Zhou, Selective gas adsorption and separation in metal–organic frameworks. Chemical Society Reviews, 2009. 38(5): p. 1477-1504. 61. Choi, S., J.H. Drese, and C.W. Jones, Adsorbent materials for carbon dioxide capture from large anthropogenic point sources. ChemSusChem, 2009. 2(9): p. 796-854. 62. Ratner, B.D., et al., Biomaterials science: an introduction to materials in medicine. 2004: Academic press. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/20827 | - |
dc.description.abstract | 本研究利用化學氣相沉積在昇華的固體模板建構三維多孔結構。氣相沉積主要發生在動態蒸氣-固體界面處,巨觀來說,沉積的構造透過犧牲的模板的昇華過程來引導,並以昇華模板的表面/界面在模板完全消失之前提供臨時支撐;此外,這樣的依賴性也並行於氣相沉積的保形機制,需要氣相前驅物吸附於昇華表面。在微觀上,孔洞在沉積和建構過程中形成,主要經由佔據空隙體積的昇華氣體以及在除了空隙之外的體積空間的沉積,這兩個動態和連續相互作用的過程,讓孔洞結構在三維中隨機分佈。
多功能聚對二甲苯(PPXs)氣相沉積於昇華模板時,由於氣體佔據和昇華多出的空間,構造過程中會形成多孔結構,因此透過控制模板的昇華速率和/或熱力學性質能夠調控孔隙率。我們利用調控載台溫度至-15 °C、4 °C、 25 °C去控制昇華速率,分別做出孔隙度61 % 、69.1 %、74.3 %的聚對二甲苯的孔洞材料。而昇華性質的不同,我們利用己烷的高昇華熱,使其與水混合結冰後作為昇華模板,接著在4 °C沉積,得到57.5%的孔隙率。我們也利用含有梯度組成的酒精混合物模板去製造梯度孔洞結構,此模板提供了蒸氣壓的梯度變化以及相對應不同的昇華速度,沉積後就會形成梯度孔洞結構。最後一個部分,我們使用含溶質的系統的冷凍模板,將含有功能性分子冷凍以形成昇華模板,隨後沉積聚對二甲苯,結果其材料在整個孔洞結構展現功能性分子的全方位性和均勻分佈性。溶質模板的使用,提供了一種裝載/定位功能性分子進入孔洞材料的獨特方法。 本文介紹技術提供了一個製造3D多孔材料的新穎方法,並且推翻了氣相沉積必然在基板上形成緻密薄膜的觀點。 | zh_TW |
dc.description.abstract | Three-dimensional porous structures are constructed via vapor deposition onto a sublimating solid template. Construction upon deposition of vapor-phase material occurs at a dynamic vapor-solid interface and is directed by the solid surface vanishing by sublimation. A proof-of concept demonstration showed vapor depositions of poly-para-xylylenes (PPXs) on sublimating templates, including ice and mixtures with ethanol and hexane. The material construction macroscopically produces a replica architecture of the parent template. Characteristics of the pore structures are formed during the construction process as a result of the gas vapor and the space that is vacated by sublimation, thus enabling control of the porosity through regulation of the sublimation speed and/or the thermodynamic properties of the templates. The technology introduced herein provides a novel approach for 3D porous material manufacturing and overturns the notion that vapor deposition necessarily forms dense thin films on substrates. | en |
dc.description.provenance | Made available in DSpace on 2021-06-08T03:05:34Z (GMT). No. of bitstreams: 1 ntu-106-R04524020-1.pdf: 4051992 bytes, checksum: d3e55ed3cbfff11344b0a71edb7706f1 (MD5) Previous issue date: 2017 | en |
dc.description.tableofcontents | 摘要 I
Abstract II Content III List of Figures V List of tables VII Chapter 1 Introduction 1 1.1 Functionalized poly-para-xylene 1 1.2 Porous materials 3 1.3 Motivation 5 Chapter 2 Experimental Section 9 2.1 Analysis Instruments 9 2.2 Surface Characterization 10 2.2.1 Fourier transform infrared spectroscopy (IRRAS) 10 2.2.2 Cryo-scanning electron microscopy (CSEM) 10 2.2.3 Confocal laser scanning microscopy (CLSM) 11 2.2.4 Nuclear magnetic resonance spectroscopy (NMR) 11 2.2.5 Scanning electron microscopy (SEM) 11 2.2.6 Micro Computed Tomography (Micro-CT) 12 2.3 Ice template fabrication 13 2.4 Deposition of PPXs 15 2.4.1 Synthesis of functionalized [2,2] paracyclophane 15 2.4.2 CVD polymerization 15 Chapter 3 Results and Discussion 19 3.1 Fabrication method principle 19 3.2 Characterization 24 3.3 Porosity control by varying of sublimation rate 29 3.3.1 Temperature control 29 3.3.2 Distinct sublimation properties with mixture 32 3.3.3 Gradient composition of mixture 33 3.4 Solute-containing system 35 Chapter 4 Conclusion 37 4.1 Conclusion 37 4.2 Future Work 39 Reference 41 | |
dc.language.iso | en | |
dc.title | 利用化學氣相沉積技術製備三維孔洞結構 | zh_TW |
dc.title | Fabrication of 3D Porous Structures Based on Chemical Vapor Deposition | en |
dc.type | Thesis | |
dc.date.schoolyear | 105-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 游佳欣(Jia-shing Yu),趙玲(Ling Chao),戴子安(Chi-An Dai) | |
dc.subject.keyword | 材料製造,氣相沉積,多孔結構,昇華,三維, | zh_TW |
dc.subject.keyword | Material fabrication,Vapor deposition,Sublimation,Porous structure,3D, | en |
dc.relation.page | 49 | |
dc.identifier.doi | 10.6342/NTU201701296 | |
dc.rights.note | 未授權 | |
dc.date.accepted | 2017-07-06 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-106-1.pdf 目前未授權公開取用 | 3.96 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。