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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
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dc.contributor.advisor | 張煥宗(Huan-Tsung Chang) | |
dc.contributor.author | Chun-Ting Wu | en |
dc.contributor.author | 吳郡庭 | zh_TW |
dc.date.accessioned | 2021-06-08T03:02:26Z | - |
dc.date.copyright | 2020-08-21 | |
dc.date.issued | 2020 | |
dc.date.submitted | 2020-08-19 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/20765 | - |
dc.description.abstract | 碳奈米點 (碳點) 是一種新興的螢光奈米材料,除了製備簡單外,優越的光學性質和良好的生物相容性皆使其成為螢光探針的理想材料,本研究中,我們選用麩胺酸和乙二胺作為前驅物,利用新穎的電化學合成法來製備碳點,此方法不需要外加高溫,並且能隨時間量測碳點形成過程中的變化。麩胺酸因同時具有羧基和胺基,容易於電化學合成過程中進行縮合反應,而乙二胺可作為氮源,除了能提高碳點量子產率外,同時也扮演表面鈍化和功能化的角色,賦予其表面大量胺基和醯胺基,有利於與金離子 (Au3+) 螯合。最後我們將所合成之碳點應用於金離子檢測,其線性範圍為0.5–5 μM (R2 = 0.98),偵測極限為0.28 μM,並成功利用此方法檢測溶於王水溶液中之廢棄電子元件的金離子含量。 | zh_TW |
dc.description.abstract | Carbon nanodots (C-dots), as emerging fluorescent nanomaterials, possess many advantages such as low cost and simple production process, unique optical properties, and good biocompatibility. These make it an ideal candidate for the fluorescent sensors. In this study, a novel one-step electrochemical method was used for the preparation of C-dots. The method is energy-saving, and could be monitoring the synthesis process of C-dots. L-glutamic acid and ethylenediamine were chosen as precursors. L-glutamic acid is an amino acid with carboxyl and amine groups which can form C-dots easily. Ethylenediamine can improve the quantum yield of C-dots by enhancing the doping of nitrogen atoms, and can act as passivation and functionalization agents in the meantime. The as-prepared C-dots are rich in amino and amide functional groups on the surface, resulting in high sensitivity and selectivity toward Au3+ ions. The detection linear range is from 0.5–5 μM (R2 = 0.98) with detection limit of 0.28 μM. This assay was successfully applied to quantitation of Au3+ in electronic waste with pretreatment in aqua regia. | en |
dc.description.provenance | Made available in DSpace on 2021-06-08T03:02:26Z (GMT). No. of bitstreams: 1 U0001-1908202014045400.pdf: 2963816 bytes, checksum: aeb2f29d2f9ff02a45923cd09b7b7c74 (MD5) Previous issue date: 2020 | en |
dc.description.tableofcontents | 口試委員審定書 I 致謝 II 中文摘要 IV Abstract V 目錄 VI 表目錄 VIII 圖目錄 IX 第一章、緒論 1 1.1碳點介紹 1 1.1.1碳點的基本性質 1 1.1.2碳點合成方法 3 1.1.3 Au3+的檢測 5 1.2研究動機 9 1.3本章圖表 10 第二章、實驗材料與方法 12 2.1實驗藥品 12 2.2碳點的製備 12 2.3螢光量子產率計算 13 2.4材料鑑定 14 2.5碳點檢測Au3+ 14 2.6螢光生命週期測量 15 2.7真實樣品檢測 15 第三章、結果與討論 16 2.1碳點之合成與優化 16 2.2碳點的光學性質 17 2.3碳點的型態和大小 17 2.4碳點的表徵鑑定 18 2.5推測碳點之合成過程 19 2.6碳點檢測Au3+的選擇性研究 20 2.7碳點檢測Au3+的靈敏度 21 2.8碳點檢測Au3+的干擾性研究 22 2.9螢光淬滅機制探討 22 2.10真實樣品的檢測 23 第四章、結論 24 表格與圖片 25 參考文獻 43 | |
dc.language.iso | zh-TW | |
dc.title | 電化學法製備碳點並應用於金離子檢測 | zh_TW |
dc.title | Electrochemical synthesis of carbon dots for sensing of Au3+ ions | en |
dc.type | Thesis | |
dc.date.schoolyear | 108-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 胡焯淳(Cho-Chun Hu),黃志清(Chih-Ching Huang),黃郁棻(Yu-Fen Huang) | |
dc.subject.keyword | 碳點,電化學合成,麩胺酸,乙二胺,金離子檢測, | zh_TW |
dc.subject.keyword | carbon nanodots,electrochemical synthesis,L-glutamic acid,ethylenediamine,Au3+ detection, | en |
dc.relation.page | 51 | |
dc.identifier.doi | 10.6342/NTU202004081 | |
dc.rights.note | 未授權 | |
dc.date.accepted | 2020-08-20 | |
dc.contributor.author-college | 理學院 | zh_TW |
dc.contributor.author-dept | 化學研究所 | zh_TW |
顯示於系所單位: | 化學系 |
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