利用官能化三配向三聯三吡啶配位基架構功能性籠狀超分子之研究

Ting-Wei Hsu; 許庭瑋

請用此 Handle URI 來引用此文件： http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/19745

完整後設資料紀錄

DC 欄位	值	語言
dc.contributor.advisor	詹益慈(Yi-Tsu Chan)
dc.contributor.author	Ting-Wei Hsu	en
dc.contributor.author	許庭瑋	zh_TW
dc.date.accessioned	2021-06-08T02:16:43Z	-
dc.date.copyright	2015-12-01
dc.date.issued	2015
dc.date.submitted	2015-10-19
dc.identifier.citation	1. Lehn, J.-M., Angew. Chem. Int. Ed. 1988, 27, 89-112. 2. Lehn, J., Science 1993, 260, 1762-1763. 3. Hofmeier, H.; El-ghayoury, A.; Schenning, A. P. H. J.; Schubert, U. S., Chem. Commun. 2004, 318-319. 4. Kraus, T.; Buděšínský, M.; Cvačka, J.; Sauvage, J.-P., Angew. Chem. Int. Ed. 2006, 45, 258-261. 5. Tominaga, M.; Suzuki, K.; Kawano, M.; Kusukawa, T.; Ozeki, T.; Sakamoto, S.; Yamaguchi, K.; Fujita, M., Angew. Chem. Int. Ed. 2004, 43, 5621-5625. 6. Morgan, G. T.; Burstall, F. H., J. Chem. Soc. 1932, 20-30. 7. Hofmeier, H.; Schubert, U. S., Chem. Soc. Rev. 2004, 33, 373-399. 8. Mahata, K.; Frischmann, P. D.; Würthner, F., J. Am. Chem. Soc. 2013, 135, 15656-15661. 9. Schalley, C. A.; Lützen, A.; Albrecht, M., Chem. Eur. J. 2004, 10, 1072-1080. 10. Riddell, I. A.; Smulders, M. M. J.; Clegg, J. K.; Nitschke, J. R., Chem. Commun. 2011, 47, 457-459. 11. Smulders, M. M. J.; Zarra, S.; Nitschke, J. R., J. Am. Chem. Soc. 2013, 135, 7039-7046. 12. Bolliger, J. L.; Belenguer, A. M.; Nitschke, J. R., Angew. Chem. Int. Ed. 2013, 52, 7958-7962. 13. S?rensen, A.; Castilla, A. M.; Ronson, T. K.; Pittelkow, M.; Nitschke, J. R., Angew. Chem. Int. Ed. 2013, 52, 11273-11277. 14. Takao, K.; Suzuki, K.; Ichijo, T.; Sato, S.; Asakura, H.; Teramura, K.; Kato, K.; Ohba, T.; Morita, T.; Fujita, M., Angew. Chem. Int. Ed. 2012, 51, 5893-5896. 15. Kikuchi, T.; Murase, T.; Sato, S.; Fujita, M., Supramol. Chem. 2008, 20, 81-94. 16. Suzuki, K.; Takao, K.; Sato, S.; Fujita, M., Angew. Chem. Int. Ed. 2011, 50, 4858-4861. 17. Chakrabarty, R.; Mukherjee, P. S.; Stang, P. J., Chem. Rev. 2011, 111, 6810-6918. 18. Schubert, U. S.; Hofmeier, H.; Newkome, G. R., Syntheses of Functionalized 2,2':6',2'-Terpyridines. In Modern Terpyridine Chemistry, Wiley-VCH Verlag GmbH & Co. KGaA: 2006; pp 7-35. 19. Xie, T.-Z.; Liao, S.-Y.; Guo, K.; Lu, X.; Dong, X.; Huang, M.; Moorefield, C. N.; Cheng, S. Z. D.; Liu, X.; Wesdemiotis, C.; Newkome, G. R., J. Am. Chem. Soc. 2014, 136, 8165-8168. 20. Suzuki, K.; Takao, K.; Sato, S.; Fujita, M., J. Am. Chem. Soc. 2010, 132, 2544-2545. 21. Breiner, B.; Nitschke, J. R., Nat. Chem. 2010, 2, 6-7. 22. Zhao, L.; Ghosh, K.; Zheng, Y.-R.; Stang, P. J., J. Org. Chem. 2009, 74, 8516-8521. 23. Suzuki, K.; Kawano, M.; Sato, S.; Fujita, M., J. Am. Chem. Soc. 2007, 129, 10652-10653. 24. Murase, T.; Sato, S.; Fujita, M., Angew. Chem. Int. Ed. 2007, 46, 1083-1085. 25. Sato, S.; Iida, J.; Suzuki, K.; Kawano, M.; Ozeki, T.; Fujita, M., Science 2006, 313, 1273-1276. 26. Tominaga, M.; Suzuki, K.; Murase, T.; Fujita, M., J. Am. Chem. Soc. 2005, 127, 11950-11951. 27. Yang, J.; Bhadbhade, M.; Donald, W. A.; Iranmanesh, H.; Moore, E. G.; Yan, H.; Beves, J. E., Chem. Commun. 2015, 51, 4465-4468. 28. Roberts, D. A.; Pilgrim, B. S.; Cooper, J. D.; Ronson, T. K.; Zarra, S.; Nitschke, J. R., J. Am. Chem. Soc. 2015, 32, 10068-10071. 29. Xu, L.; Chen, L.-J.; Yang, H.-B., Chem. Commun. 2014, 50, 5156-5170. 30. Lewis, J. E. M.; Elliott, A. B. S.; McAdam, C. J.; Gordon, K. C.; Crowley, J. D., Chem. Sci. 2014, 5, 1833-1843. 31. Qing-Fu, S.; Sota, S.; Makoto, F., Nat. Chem. 2012, 4, 330-333. 32. Chakrabarty, R.; Stang, P. J., J. Am. Chem. Soc. 2012, 134, 14738-14741. 33. Wang, M.; Lan, W.-J.; Zheng, Y.-R.; Cook, T. R.; White, H. S.; Stang, P. J., J. Am. Chem. Soc. 2011, 133, 10752-10755. 34. Ghosh, K.; Hu, J.; White, H. S.; Stang, P. J., J. Am. Chem. Soc. 2009, 131, 6695-6697. 35. Yang, H.-B.; Ghosh, K.; Zhao, Y.; Northrop, B. H.; Lyndon, M. M.; Muddiman, D. C.; White, H. S.; Stang, P. J., J. Am. Chem. Soc. 2008, 130, 839-841. 36. Yang, H.-B.; Ghosh, K.; Northrop, B. H.; Zheng, Y.-R.; Lyndon, M. M.; Muddiman, D. C.; Stang, P. J., J. Am. Chem. Soc. 2007, 129, 14187-14189. 37. Jude, H.; Disteldorf, H.; Fischer, S.; Wedge, T.; Hawkridge, A. M.; Arif, A. M.; Hawthorne, M. F.; Muddiman, D. C.; Stang, P. J., J. Am. Chem. Soc. 2005, 127, 12131-12139. 38. Das, N.; Stang, P. J.; Arif, A. M.; Campana, C. F., J. Org. Chem. 2005, 70, 10440-10446. 39. Schröder, T.; Brodbeck, R.; Letzel, M. C.; Mix, A.; Schnatwinkel, B.; Tonigold, M.; Volkmer, D.; Mattay, J., Tetrahedron Lett. 2008, 49, 5939-5942. 40. Jude, H.; Sinclair, D. J.; Das, N.; Sherburn, M. S.; Stang, P. J., J. Org. Chem. 2006, 71, 4155-4163. 41. Huang, F.; Yang, H.-B.; Das, N.; Maran, U.; Arif, A. M.; Gibson, H. W.; Stang, P. J., J. Org. Chem. 2006, 71, 6623-6625. 42. Merlau, M. L.; del Pilar Mejia, M.; Nguyen, S. T.; Hupp, J. T., Angew. Chem. Int. Ed. 2001, 113, 4369-4372. 43. Fujita, N.; Biradha, K.; Fujita, M.; Sakamoto, S.; Yamaguchi, K., Angew. Chem. Int. Ed. 2001, 40, 1718-1721. 44. Fan, J.; Whiteford, J. A.; Olenyuk, B.; Levin, M. D.; Stang, P. J.; Fleischer, E. B., J. Am. Chem. Soc. 1999, 121, 2741-2752. 45. Stang, P. J.; Cao, D. H.; Chen, K.; Gray, G. M.; Muddiman, D. C.; Smith, R. D., J. Am. Chem. Soc. 1997, 119, 5163-5168. 46. Stang, P. J.; Olenyuk, B.; Fan, J.; Arif, A. M., Organometallics 1996, 15, 904-908. 47. Drain, C. M.; Lehn, J.-M., J. Chem. Soc., Chem. Commun. 1994, 2313-2315. 48. Northrop, B. H.; Yang, H.-B.; Stang, P. J., Chem. Commun. 2008, 5896-5908. 49. Chi, K.-W.; Addicott, C.; Stang, P. J., J. Org. Chem. 2004, 69, 2910-2912. 50. Halls, J. J. M.; Pichler, K.; Friend, R. H.; Moratti, S. C.; Holmes, A. B., Appl. Phys. Lett. 1996, 68, 3120-3122. 51. Haugeneder, A.; Neges, M.; Kallinger, C.; Spirkl, W.; Lemmer, U.; Feldmann, J.; Scherf, U.; Harth, E.; Gügel, A.; Müllen, K., Phys. Rev. B: Condens. Matter 1999, 59, 15346-15351. 52. Theander, M.; Yartsev, A.; Zigmantas, D.; Sundström, V.; Mammo, W.; Andersson, M. R.; Inganäs, O., Phys. Rev. B: Condens. Matter 2000, 61, 12957-12963. 53. Stübinger, T.; Brütting, W., J. Appl. Phys. 2001, 90, 3632-3641. 54. Markov, D. E.; Amsterdam, E.; Blom, P. W. M.; Sieval, A. B.; Hummelen, J. C., J. Phys. Chem. A 2005, 109, 5266-5274. 55. Cheng, Y.-J.; Yang, S.-H.; Hsu, C.-S., Chem. Rev. 2009, 109, 5868-5923. 56. Kim, Y.; Cook, S.; Tuladhar, S. M.; Choulis, S. A.; Nelson, J.; Durrant, J. R.; Bradley, D. D. C.; Giles, M.; McCulloch, I.; Ha, C.-S.; Ree, M., Nat. Mater. 2006, 5, 197-203. 57. Koppe, M.; Brabec, C. J.; Heiml, S.; Schausberger, A.; Duffy, W.; Heeney, M.; McCulloch, I., Macromolecules 2009, 42, 4661-4666. 58. Hiorns, R. C.; de Bettignies, R.; Leroy, J.; Bailly, S.; Firon, M.; Sentein, C.; Khoukh, A.; Preud'homme, H.; Dagron-Lartigau, C., Adv. Funct. Mater. 2006, 16, 2263-2273. 59. Hoppe, H.; Glatzel, T.; Niggemann, M.; Hinsch, A.; Lux-Steiner, M. C.; Sariciftci, N. S., Nano Lett. 2005, 5, 269-274. 60. Li, G.; Shrotriya, V.; Huang, J.; Yao, Y.; Moriarty, T.; Emery, K.; Yang, Y., Nat. Mater. 2005, 4, 864-868. 61. Reyes-Reyes, M.; Kim, K.; Dewald, J.; López-Sandoval, R.; Avadhanula, A.; Curran, S.; Carroll, D. L., Org. Lett. 2005, 7, 5749-5752. 62. Li, G.; Yao, Y.; Yang, H.; Shrotriya, V.; Yang, G.; Yang, Y., Adv. Funct. Mater. 2007, 17, 1636-1644. 63. Nguyen, L. H.; Hoppe, H.; Erb, T.; Günes, S.; Gobsch, G.; Sariciftci, N. S., Adv. Funct. Mater. 2007, 17, 1071-1078. 64. Ayzner, A. L.; Wanger, D. D.; Tassone, C. J.; Tolbert, S. H.; Schwartz, B. J., J. Phys. Chem. C 2008, 112, 18711-18716. 65. Swinnen, A.; Haeldermans, I.; vande Ven, M.; D'Haen, J.; Vanhoyland, G.; Aresu, S.; D'Olieslaeger, M.; Manca, J., Adv. Funct. Mater. 2006, 16, 760-765. 66. Yang, X.; van Duren, J. K. J.; Rispens, M. T.; Hummelen, J. C.; Janssen, R. A. J.; Michels, M. A. J.; Loos, J., Adv. Mater. 2004, 16, 802-806. 67. Yang, X.; van Duren, J. K. J.; Janssen, R. A. J.; Michels, M. A. J.; Loos, J., Macromolecules 2004, 37, 2151-2158. 68. Cheng, Y.-J.; Hsieh, C.-H.; Li, P.-J.; Hsu, C.-S., Adv. Funct. Mater. 2011, 21, 1723-1732. 69. Zhang, Y.; Yip, H.-L.; Acton, O.; Hau, S. K.; Huang, F.; Jen, A. K. Y., Chem. Mater. 2009, 21, 2598-2600. 70. Liao, H.-C.; Tsao, C.-S.; Lin, T.-H.; Jao, M.-H.; Chuang, C.-M.; Chang, S.-Y.; Huang, Y.-C.; Shao, Y.-T.; Chen, C.-Y.; Su, C.-J.; Jeng, U. S.; Chen, Y.-F.; Su, W.-F., ACS Nano 2012, 6, 1657-1666. 71. Bunck, D. N.; Dichtel, W. R., Angew. Chem. Int. Ed. 2012, 51, 1885-1889. 72. Wang, J.-L.; Li, X.; Lu, X.; Hsieh, I. F.; Cao, Y.; Moorefield, C. N.; Wesdemiotis, C.; Cheng, S. Z. D.; Newkome, G. R., J. Am. Chem. Soc. 2011, 133, 11450-11453. 73. Wang, C.; Hao, X.-Q.; Wang, M.; Guo, C.; Xu, B.; Tan, E. N.; Zhang, Y.-Y.; Yu, Y.; Li, Z.-Y.; Yang, H.-B.; Song, M.-P.; Li, X., Chem. Sci. 2014, 5, 1221-1226. 74. Li, X.; Chan, Y.-T.; Casiano-Maldonado, M.; Yu, J.; Carri, G. A.; Newkome, G. R.; Wesdemiotis, C., Anal. Chem. 2011, 83, 6667-6674. 75. Chan, Y.-T.; Li, X.; Soler, M.; Wang, J.-L.; Wesdemiotis, C.; Newkome, G. R., J. Am. Chem. Soc. 2009, 131, 16395-16397. 76. Mesleh, M. F.; Hunter, J. M.; Shvartsburg, A. A.; Schatz, G. C.; Jarrold, M. F., J. Phys. Chem. 1996, 100, 16082-16086. 77. Shvartsburg, A. A.; Jarrold, M. F., Chem. Phys. Lett. 1996, 261, 86-91. 78. Sleno, L.; Volmer, D. A., J. Mass Spectrom. 2004, 39, 1091-1112. 79. Felder, D.; Nierengarten, H.; Gisselbrecht, J.-P.; Boudon, C.; Leize, E.; Nicoud, J.-F.; Gross, M.; Van Dorsselaer, A.; Nierengarten, J.-F., New J. Chem. 2000, 24, 687-695. 80. Li, G.; Chu, C.-W.; Shrotriya, V.; Huang, J.; Yang, Y., Appl. Phys. Lett. 2006, 88, 253503. 81. Krebs, F. C.; Norrman, K., Prog. Photovoltaics Res. Appl. 2007, 15, 697-712. 82. Hau, S. K.; Yip, H.-L.; Baek, N. S.; Zou, J.; O’Malley, K.; Jen, A. K.-Y., Appl. Phys. Lett. 2008, 92, 253301. 83. Hau, S. K.; Yip, H.-L.; Acton, O.; Baek, N. S.; Ma, H.; Jen, A. K. Y., J. Mater. Chem. 2008, 18, 5113-5119. 84. Hau, S. K.; Cheng, Y.-J.; Yip, H.-L.; Zhang, Y.; Ma, H.; Jen, A. K. Y., ACS Appl. Mater. Interfaces 2010, 2, 1892-1902. 85. Hsieh, C.-H.; Cheng, Y.-J.; Li, P.-J.; Chen, C.-H.; Dubosc, M.; Liang, R.-M.; Hsu, C.-S., J. Am. Chem. Soc. 2010, 132, 4887-4893. 86. Chang, C.-Y.; Wu, C.-E.; Chen, S.-Y.; Cui, C.; Cheng, Y.-J.; Hsu, C.-S.; Wang, Y.-L.; Li, Y., Angew. Chem. Int. Ed. 2011, 50, 9386-9390. 87. He, Z.; Zhong, C.; Su, S.; Xu, M.; Wu, H.; Cao, Y., Nat. Photonics 2012, 6, 591-595. 88. Liao, S.-H.; Jhuo, H.-J.; Cheng, Y.-S.; Chen, S.-A., Adv. Mater. 2013, 25, 4766-4771. 89. Liang, W.-W.; Chang, C.-Y.; Lai, Y.-Y.; Cheng, S.-W.; Chang, H.-H.; Lai, Y.-Y.; Cheng, Y.-J.; Wang, C.-L.; Hsu, C.-S., Macromolecules 2013, 46, 4781-4789. 90. Cheng, Y.-J.; Hsieh, C.-H.; He, Y.; Hsu, C.-S.; Li, Y., J. Am. Chem. Soc. 2010, 132, 17381-17383. 91. Tsao, C.-S.; Li, M.; Zhang, Y.; Leao, J. B.; Chiang, W.-S.; Chung, T.-Y.; Tzeng, Y.-R.; Yu, M.-S.; Chen, S.-H., J. Phys. Chem. C 2010, 114, 19895-19900. 92. Tsao, C.-S.; Yu, M.-S.; Chung, T.-Y.; Wu, H.-C.; Wang, C.-Y.; Chang, K.-S.; Chen, H.-L., J. Am. Chem. Soc. 2007, 129, 15997-16004. 93. Tsao, C. S.; Chen, C. Y.; Jeng, U. S.; Kuo, T. Y., Acta Mater. 2006, 54, 4621-4631. 94. Li, Y.-C.; Chen, K.-B.; Chen, H.-L.; Hsu, C.-S.; Tsao, C.-S.; Chen, J.-H.; Chen, S.-A., Langmuir 2006, 22, 11009-11015. 95. Lin, T. L.; Jeng, U.; Tsao, C. S.; Liu, W. J.; Canteenwala, T.; Chiang, L. Y., J. Phys. Chem. B 2004, 108, 14884-14888. 96. Liao, H.-C.; Tsao, C.-S.; Lin, T.-H.; Chuang, C.-M.; Chen, C.-Y.; Jeng, U. S.; Su, C.-H.; Chen, Y.-F.; Su, W.-F., J. Am. Chem. Soc. 2011, 133, 13064-13073. 97. Shelimov, K. B.; Clemmer, D. E.; Hudgins, R. R.; Jarrold, M. F., J. Am. Chem. Soc. 1997, 119, 2240-2248. 98. Valentine, S. J.; Anderson, J. G.; Ellington, A. D.; Clemmer, D. E., J. Phys. Chem. B 1997, 101, 3891-3900. 99. Bush, M. F.; Campuzano, I. D. G.; Robinson, C. V., Anal. Chem. 2012, 84, 7124-7130. 100. Campuzano, I.; Bush, M. F.; Robinson, C. V.; Beaumont, C.; Richardson, K.; Kim, H.; Kim, H. I., Anal. Chem. 2012, 84, 1026-1033. 101. Salbo, R.; Bush, M. F.; Naver, H.; Campuzano, I.; Robinson, C. V.; Pettersson, I.; J?rgensen, T. J. D.; Haselmann, K. F., Rapid Commun. Mass Spectrom. 2012, 26, 1181-1193. 102. Chan, Y.-T.; Li, X.; Yu, J.; Carri, G. A.; Moorefield, C. N.; Newkome, G. R.; Wesdemiotis, C., J. Am. Chem. Soc. 2011, 133, 11967-11976. 103. Gallina, M. E.; Baytekin, B.; Schalley, C.; Ceroni, P., Chem. Eur. J. 2012, 18, 1528-1535. 104. He, Q.; Dai, H.; Tan, X.; Cheng, X.; Liu, F.; Tschierske, C., J. Mater. Chem. C 2013, 1, 7148-7154.
dc.identifier.uri	http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/19745	-
dc.description.abstract	在超分子領域中，許多團隊致力於架構立體的籠狀超分子；現今已有各式各樣的三維高對稱結構被創造及報導。本實驗中，我們成功展示籠狀超分子外修飾的可能性；透過合成一系列帶有不同官能基團的三配向三聯三吡啶配位基並與金屬離子錯合形成立方體的超分子；含有不同基團的立方超分子表現出相異的性質，例如溶解度；透過氫核磁共振、電灑式質譜及電子顯微鏡等技術來鑑定及觀察其自組裝後的結果和行為。除此，我們亦利用連接不同位點的聯三吡啶，形成向內彎曲的三聯三吡啶配位基結構並與金屬離子錯合形成較小的籠狀超分子；藉由連接位點的改變微調配基幾何結構，更多的三維超分子可以簡單地被建構。現今以噻吩及碳球衍生物為主動層之有機太陽能電池具有穩定性不佳的問題，其中有部分原因為小分子的碳球衍生物隨時間產生大規模聚集進而造成主動層間嚴重的巨觀相分離；因此，我們將富勒烯引入至三配向三聯三吡啶配位基上，透過自組裝形成帶有八個富勒烯的立方超分子，並作為交聯劑降低碳球衍生物在主動層的聚集速度，成功改善有機太陽能電池的穩定性。	zh_TW
dc.description.abstract	In supramolecular chemistry, constructing a well-defined three-dimensional cage has attracted more and more attention. Herein, we explore the possibility of exterior functionalization for the self-assembled cages. A series of tritopic terpyridine-based ligands with various exterior functionalities was used to construct metallo-supramolecular cages. To investigate the self-assembly behavior of the predesigned tritopic ligand system, ligands with simple hydroxyl and alkyl substituents were synthesized and complexed with Cd(II) and Zn(II) ions to give supramolecular cubic cages that were well characterized by 1H-NMR, ESI-MS, and electron microscopes. Besides, changing connected positions between the terpyridine moieties and the central core to generate a bent version of the tritopic ligand was successfully used for constructing a smaller supramolecular structure, demonstrating a simple method to build variant metallo-supramolecular structures. To date, the polymer solar cells (PSCs) with P3HT and PCBM as an active layer suffer from a severe lifetime problem, which is partly caused by the macrophase separation from the aggregation of PCBM with time. Based on our new findings, the tritopic terpyridine-based ligand decorated with pendant fullerene groups was successfully synthesized and self-assembled into a functional metallocage via coordination. In addition, the fullerene-functionalized cage was used as a supramolecular crosslinker to alleviate the macrophase aggregation caused by the migration of the C60 acceptor, which significantly improved the stability of organic photovoltaics.	en
dc.description.provenance	Made available in DSpace on 2021-06-08T02:16:43Z (GMT). No. of bitstreams: 1 ntu-104-R02223175-1.pdf: 9730235 bytes, checksum: d047d78aaafe353e6a8cc7df142bd1b4 (MD5) Previous issue date: 2015	en
dc.description.tableofcontents	Chapter 1. Introduction 1 1-1 Supramolecules 1 1-1-1 Pyridine-Based Metal Coordination 2 1-1-2 2,2':6',2'-Terpyridine 4 1-2 Metallosupramolecular Cages 5 1-3 Functionalization of metallosupramolecules 6 1-3-1 Edge- and corner-functionalization 7 1-3-2 Endo-functionalization 7 1-3-3 Exo-functionalization 9 1-4 Polymer solar cells 10 1-5 Motivation and Goals 15 Chapter 2. Metallo-supramolecular cages 17 2-1 Design and synthesis of ligands 17 2-2 Construction of metallo-supramolecular cages 19 2-2-1 L1 and [M12L18] 19 2-2-2 L2 and [M12L28] 21 2-2-3 L3 and [M12L38] 30 2-2-4 L4 and [M3L42] 33 2-3 Summary 40 Chapter 3. Fullerene-functionalized metallo-supramolecular cages 42 3-1 Synthesis and characterization of L5 and CPX5 42 3-2 ZnO modification with L5 47 3-3 Stability improvement by using CPX5 as a supramolecular crosslinker 50 3-4 Characterization of the P3HT:PC61BM:CPX5 blends 52 Chapter 4. Conclusions 59 Chapter 5. Experimental section 61 References 106
dc.language.iso	en
dc.title	利用官能化三配向三聯三吡啶配位基架構功能性籠狀超分子之研究	zh_TW
dc.title	Self-Assembly of Functional Metallo-Supramolecular Cages Using Tritopic Terpyridine-Based Ligands	en
dc.type	Thesis
dc.date.schoolyear	104-1
dc.description.degree	碩士
dc.contributor.oralexamcommittee	周必泰(Pi-Tai Chou),童世煌(Shih-Huang Tung)
dc.subject.keyword	聯三?啶,籠狀超分子,富勒烯,有機太陽能電池,	zh_TW
dc.subject.keyword	terpyridine,metallo-supramolecular cage,exo-funtionalization,fullerene,solar cell,	en
dc.relation.page	113
dc.rights.note	未授權
dc.date.accepted	2015-10-20
dc.contributor.author-college	理學院	zh_TW
dc.contributor.author-dept	化學研究所	zh_TW
顯示於系所單位：	化學系

文件中的檔案：

檔案	大小	格式
ntu-104-1.pdf 未授權公開取用	9.5 MB	Adobe PDF

顯示文件簡單紀錄

系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。