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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱靜雯(Ching-Wen Chiu) | |
| dc.contributor.author | Chen-Hao Wang | en |
| dc.contributor.author | 王晨皓 | zh_TW |
| dc.date.accessioned | 2021-06-08T01:22:02Z | - |
| dc.date.copyright | 2014-09-04 | |
| dc.date.issued | 2014 | |
| dc.date.submitted | 2014-08-06 | |
| dc.identifier.citation | 1. Jutzi, P.; Burford, N. Chem. Rev. 1999, 99, 969-990.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/18726 | - |
| dc.description.abstract | 十三族錯合物具有路易士酸性的特性，為了提升其酸性，加上額外的正電荷可以有效地提升其路易士酸性。這類的錯合物缺電子且配位數低，必須用立障大且可提供電子的配位基來穩定。五甲基環戊二烯基以及氮異環碳烯都是優秀的配位基，因為其立障大且可提供電子穩定缺電子的金屬中心。在此論文中，我們嘗試結合此兩種不同性質的配位基來合成十三族二價陽離子。其中，成功合成鋁二價錯合物離子對，並用單晶繞射確定其結構。我們也研究一系列十三族化合物的反應性。 | zh_TW |
| dc.description.abstract | To increase the Lewis acidity of group 13 derivatives, introduction of positive charge is one of the effective methods. In order to stabilize the electron-deficient and low-coordinate species, bulky and electron-donating ligands are indispensable. Pentamethylcyclopentadienyl (Cp*) is a good candidate due to its flexible conformation and electron-rich nature, and has been utilized in stabilizing low-coordinate main group elements. In addition, strong s-donating N-heterocyclic carbene ligand is also applied to provide further kinetic and thermodynamic stability to the cationic group 13 derivatives. As an extension to our recent success in the isolation of low-coordinate boron dication, aluminum contact ion pairs are synthesized and structurally characterized. Several pentamethylcyclopetadienyl group 13 complexes are also synthesized. Reactivity studies these group 13 complexes will also be discussed. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-08T01:22:02Z (GMT). No. of bitstreams: 1 ntu-103-R01223148-1.pdf: 11367178 bytes, checksum: 22f0d4e2b08a39f4f7274e9e303bbede (MD5) Previous issue date: 2014 | en |
| dc.description.tableofcontents | 口試委員會審定書 #
中文摘要 i ABSTRACT ii CONTENTS iii LIST OF FIGURES iv LIST OF SCHEMES vi LIST OF TABLES vii Chapter 1 Introduction 1 1.1 General Introduction 1 1.2 Diborocenium Dication 2 1.3 Aluminum Dication 7 1.4 Gallium Dication 18 1.5 Brief Summary 22 Chapter 2 Results and Duscussion 23 2.1 Diborocenium Dication 23 2.2 Aluminum Dication 28 2.3 Gallium Dication 42 Chapter 3 Conclusion 46 Chapter 4 Experimental Section 48 Chapter 5 References 54 Chapter 6 Appendix 59 | |
| dc.language.iso | en | |
| dc.title | 五甲基環戊二烯基之十三族錯合物之合成 | zh_TW |
| dc.title | Syntheses of Group 13 Pentamethylcyclopentadienyl Complexes | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 102-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 林英智(Ying-Chih Lin),彭旭明(Shie-Ming Peng),林天送(Tien-Sung Tom Lin),楊振宜(Chen-I Yang) | |
| dc.subject.keyword | 十三族錯合物,硼,鋁,鎵,錯合物離子對, | zh_TW |
| dc.subject.keyword | Group 13 complexes,Boron,Aluminum,Gallium,Contact ion pairs, | en |
| dc.relation.page | 183 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2014-08-06 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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