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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 陳國慶(Kuo-Ching Chen) | |
dc.contributor.author | Meng-Ting Chang | en |
dc.contributor.author | 張孟婷 | zh_TW |
dc.date.accessioned | 2021-06-08T01:20:48Z | - |
dc.date.copyright | 2014-08-12 | |
dc.date.issued | 2014 | |
dc.date.submitted | 2014-08-08 | |
dc.identifier.citation | 第一章
[1] 劉孔祥, 鋰離子電池充放電過程之離子遷移模型與模擬, 國立台灣大學電 機工程學研究所碩士論文 (2011) [2] Y. Zhang and C.Y. Wang, Cycle-Life Characterization of Automotive Lithium-Ion Batteries with LiNiO2 Cathode, J. Power Sources, 156, 527 (2009) [3] M. Dubarry, and B. Liaw, Development of a universal modeling tool for rechargeable lithium batteries, J. Power Sources, 174, 856 (2007) 第二章 [1] K. Mizushima, P.C. Jones, P.J. Wiseman and J.B. Goodenough, LixCoO2 (0<x≦l): A New Cathode Material for Batteries of High Energy Density, Mat. Res. Bull., 15, 783 (1980) [2] 劉孔祥, 鋰離子電池充放電過程之離子遷移模型與模擬, 國立台灣大學電 機工程學研究所碩士論文 (2011) [3] A.J. Bard, and L.R. Faulkner, Electrochemical Methods-Fundamentals and Applications, Second Edition, Wiley-Interscience (1980) [4] S. Rodrigues, N. Munichandraiah, A.K. Shukla, A review of state-of-charge indication of batteries by means of a.c. impedance measurements, J. Power Sources, 87, 12 (2000) [5] E. Barsoukov, and J. Ross Macdonald, Fundamental of Impedance Spectroscopy, Second Edition, Wiley-Interscience (2005) [6] J.E.B. Randles, Kinetics of Rapid Electrode Reactions, Discuss. Faraday Soc., 11 (1947) [7] X. Yuan, H.Wang, J. C. Sun, J. Zhang, AC impedance technique in PEM fuel cell diagnosis—A review, Int. J. Hydrogen Energy, 32, 4365 (2007) [8] M. Umeda, K. Dokko, Y. Fujita, M. Mohamed, I. Uchida, and J.R. Selman Electrochemical impedance study of Li-ion insertion into mesocarbon microbead single particle electrode Part I. Graphitized carbon, Electrochimica Acta, 47, 885 (2001) [9] Y. Zhang and C.Y. Wang, Cycle-Life Characterization of Automotive Lithium-Ion Batteries with LiNiO2 Cathode, J. Power Sources, 156, 527 (2009) 第三章 [1] E. Barsoukov, and J. Ross Macdonald, Fundamental of Impedance Spectroscopy, Second Edition, Wiley-Interscience (2005) [2] 沈育仁, 複合高分子電解質結構與電性之研究,國立中央大學化學研究所碩士論文 (2003) [3] A.J. Bard, and L.R. Faulkner, Electrochemical Methods-Fundamentals and Applications, Second Edition, Wiley-Interscience (1980) [4] 吳浩青、李永舫,電化學動力學, 科技圖書股份有限公司 (2001) [5] Y. Zhang and C.Y. Wang, Cycle-Life Characterization of Automotive Lithium-Ion Batteries with LiNiO2 Cathode, J. Power Sources, 156, 527 (2009) [6] J.-M. Tarascon and M. Armand, Issues and challenges facing rechargeable lithium batteries, Nature, 141, 359 (2001) [7] X.H. Huang, J.P. Tu, X.H. Xia, X.L. Wang, and J.Y. Xiang, Nickel foam-supported porous NiO/polyaniline film as anode for lithium ion batteries, Electrochemistry Communications, 10, 1288 (2008) [8] B.Y. Liawa, G. Nagasubramanian, R.G. Jungst, and D.H. Doughty, Modeling of lithium ion cells—A simple equivalent-circuit model approach, Solid State Ionics, 175, 835 (2004) [9] M.B. Pinson and M.Z. Bazant, Theory of SEI Formation in Rechargeable Batteries: Capacity Fade, Accelerated Aging and Lifetime Prediction, J. Electrochemical Society, 160, A243 (2013) [10] S.S. Zhang, K. Xu, and T.R. Jow, Electrochemical impedance study on the low temperature of Li-ion batteries, Electrochimica Acta, 49, 1057 (2004) [11] C. Ho, I.D. Raistrick, and R.A. Huggins, Application of A-C Techniques to the Study of Lithium Diffusion in Tungsten Trioxide Thin Films, J. Electrochemical Society, 127, 343 (1980) [12] F. Gao and Z. Tang, Kinetic behavior of LiFePO4/C cathode material for lithium-ion batteries, Electrochimica Acta, 53, 5071 (2008) 第四章 [1] Y. Zhang and C.Y. Wang, Cycle-Life Characterization of Automotive Lithium-Ion Batteries with LiNiO2 Cathode, J. Power Sources, 156, 527 (2009) [2] J. Vetter, P. Novak, M.R. Wagner, C. Veit, K.-C. Mȍller, J.O. Besenhard, M. Winter, M. Wohlfahrt-Mehrens, C. Vogler, and A. Hammouche, Ageing mechanisms in lithium-ion batteries, J. Power Sources, 147, 269 (2005) [3] G. Nagasubramanian, Two- and three-electrode impedance studies on 18650 Li-ion cells, J. Power Sources, 87, 226 (2000) 第五章 [1] J.-P. Diard, B. Le Gorrec, and C. Montella, Handbook of Electrochemical Impedance Spectroscopy, Bio-Logic (2011) [2] Y. Zhang and C.Y. Wang, Cycle-Life Characterization of Automotive Lithium-Ion Batteries with LiNiO2 Cathode, J. Power Sources, 156, 527 (2009) 第六章 [1] S.S. Zhang, K.Xu, and T.R. Jow, Electrochemical impedance study on the low temperature of Li-ion batteries, Electrochimica Acta, 49, 1057, (2004) [2] M.B. Pinsona, and M.Z. Bazant, Theory of SEI Formation in Rechargeable Batteries: Capacity Fade, Accelerated Aging and Lifetime Prediction, J. Power Sources, 160, 243 (2013) [3] 劉孔祥, 鋰離子電池充放電過程之離子遷移模型與模擬, 國立台灣大學電機工程學研究所碩士論文 (2011) [4] Y. Zhang and C.Y. Wang, Cycle-Life Characterization of Automotive Lithium-Ion Batteries with LiNiO2 Cathode, J. Power Sources, 156, 527 (2009) [5] M. Doyle, J. Newman, Antoni S. Gozdz, Caroline N. Schmutz, and Jean-Marie Tarascon, Comparison of Modeling Predictions with Experimental Data from Plastic Lithium Ion Cells, J. Electrochem. Soa., 143, 1890 (1996) [6] G. Nagasubramanian, Two- and three-electrode impedance studies on 18650 Li-ion cells, J. Power Sources, 87, 226 (2000) [7] V.S. Bagotsky, Fundamentals of Electrochemistry, 2nd Edition, Wiley-Interscience (2005) [8] F. Gao, Z. and Tang, Kinetic behavior of LiFePO4/C cathode material for lithium-ion batteries, Electrochimica Acta, 53, 5071 (2008) [9] P. Gao, Y. Li, H. Liu, J. Pinto, X. Jiang, and G. Yang, Improved High Rate Capacity and Lithium Diffusion Ability of LiNi1/3Co1/3Mn1/3O2 with Ordered Crystal Structure, J. Electrochemical Society, 159, 506 (2012) [10] G. B. Less, J. H. Seo, S. Han, A. M. Sastry, J. Zausch, , A. Latz, S. Schmidt, C. Wieser, D. Kehrwald, and S. Felle, Micro-Scale Modeling of Li-Ion Batteries: Parameterization and Validation, J. Electrochemical Society, 159, 697 (2012) [11] P.W. Atkins, and L.L. Jones; Chemical Principle –The Quest for Insight, 4th Edition, W.H. Freeman and Company (2008) [12] J.P. Fellner, G.J. Loeber, and S.S. Sandhu, Testing of lithium-ion 18650 cells and characterizing/predicting cell performance, J. Power Sources, 81-82, 867 (1999) [13] N. Ogihar, S. Kawauchi, C. Okuda, Y. Itou, Y. Takeuchi, and Y. Ukyo, Theoretical and Experimental Analysis of Porous Electrodes for Lithium-Ion Batteries by Electrochemical Impedance Spectroscopy Using a Symmetric Cell, J. Electrochemical Society, 159, 1034 (2012) [14] J.P. Fellner, G.J. Loeber, and S.S. Sandhu, Testing of lithium-ion 18650 cells and characterizing/predicting cell performance, J. Power Sources, 81-82, 867 (1999) 第七章 [1] B.Y. Liaw, G. Nagasubramanian, R.G. Jungst, and D.H. Doughty, Modeling of lithium ion cells—A simple equivalent-circuit model approach, Solid State Ionics, 175, 835 (2004) [2] M.W. Verbrugge and R.S. Conell, Electrochemical and Thermal Characterization of Battery Modules Commensurate with Electric Vehicle Integration, J. Electrochemical Society, 149, 45 (2002) [3] 劉孔翔,鋰離子電池充放電過程之離子遷移模型與模擬,國立臺灣大學電機資訊學院電機工程學研究所碩士論文 (2011) [4] T.S. Dao, C. P. Vyasarayani, and J. McPhee, Simplification and orderreduction of lithium-ion battery model based on porous-electrode theory, J. Power Sources, 198, 329 (2012) [5] M. Dubarry, and B. Liaw, Development of a universal modeling tool for rechargeable lithium batteries, J. Power Sources, 174, 856 (2007) [6] 孫建中、周裕福、鄭明旺、沈聖詠。2013。電池特性追蹤方法及電路。中華民國發明專利第394971號。 [7] J. Vetter, P. Nov’ak, M.R. Wagner, C. Veit, K.-C. M‥oller, J.O. Besenhard, M. Winter, M. Wohlfahrt-Mehrens, C. Vogler, and A. Hammouche, Ageing mechanisms in lithium-ion batteries, J. Power Sources, 147, 269 (2005) | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/18707 | - |
dc.description.abstract | 鋰離子電池之廣泛使用,促使相關研究也隨之展開。低成本、高性能、大功率、壽命長、安全性是鋰離子電池主要的研究方向。其中,使用相關電池檢測方法,以瞭解電池的內部情況為各研究中相當重要的一部分。而電化學阻抗頻譜法(EIS)即是常見的電池檢測方法之一,其主要優點為檢測時間短,且為一種非破壞性檢測法。
在本論文中,主要利用電化學交流阻抗法(EIS)來量測鋰離子電池阻抗頻譜,並藉由電池等效電路來模擬鋰離子電池阻抗頻譜。為了準確模擬阻抗頻譜,我們建構了一套兼具電化學理論與數學模擬的擬合方法。我們也根據模擬結果中,等效電路各參數的分析與探討,進而了解不同實驗條件對鋰離子電池內部阻抗的影響。再者,我們利用電池等效電路模型中的參數來取得電池電化學模型建立過程中重的要電化學參數,即電極表面鋰離子擴散係數,以利電化學模型之建構。此外,鋰離子電池等效電路可進一步用於模擬電池的放電行為。在模擬的過程中,我們也提出了一個電池開路電壓估算法,可成功減少電池開路電壓量測所需時間 。 | zh_TW |
dc.description.abstract | Many studies of lithium-ion battery (LIB) has been carried out because of the wide use of it. Cost reduction, performance improvement, increase of power, excellent cycle life along with high safety are the main targets of those studies. During the process of LIBs research, it is important to inspect the inner condition of LIBs by making battery examinations. Electrochemical Impedance Spectroscopy (EIS) is one of the commonly used examinations, which is a nondestructive testing and famous for its rapidity.
In this thesis, the EIS measurement was performed to obtain the spectra of LIBs. In addition, we simulated the spectra through the equivalent circuit model (ECM) of LIBs. In order to simulate the spectra precisely, we established a simulation method based on electrochemistry and mathematics. Besides, the parameters of the ECM, which were obtained from the simulation results, were analyzed and studied for understanding the effects on the impedance of LIBs caused by different experimental settings. Furthermore, one of the parameters in the ECM helped us gain an important electrochemical parameter--the diffusion coefficient of lithium-ion, which was critical for establishing electrochemical model of LIBs. The equivalent circuit model of LIBs could be further used to simulate the discharging behavior of LIBs. We also provided a method for estimating open-circuit voltage (OCV) of LIBs. This method could successfully predict the OCV of LIBs and thus decrease the time consumed during OCV measurement. | en |
dc.description.provenance | Made available in DSpace on 2021-06-08T01:20:48Z (GMT). No. of bitstreams: 1 ntu-103-R01543045-1.pdf: 4449847 bytes, checksum: 6141818a7e0982dd2ccad5d3526f9664 (MD5) Previous issue date: 2014 | en |
dc.description.tableofcontents | 中文摘要 I
Abstract II 誌謝 IV 目錄 V 圖目錄 VIII 表目錄 XIII 第一章、緒論 1 1.1前言 1 1.2研究動機 1 1.3論文架構 2 第二章、文獻回顧 5 2.1鋰離子電池 5 2.2鋰離子電池運作原理 6 2.3電池專有名詞與解釋 8 2.4電化學交流阻抗法 10 2.5 鋰離子電池等效電路 10 第三章、交流阻抗法與電池等效電路 15 3.1 交流阻抗法 15 3.1.1 交流電路 16 3.1.2 電池的等效電路[3] 19 3.2 法拉第阻抗[3, 4] 20 3.2.1 電化學系統特性 20 3.2.2 Rs、Cs與電化學參數的關係 22 3.2.3 法拉第阻抗與動力學參數 23 3.3 鋰離子電池等效電路模型 29 第四章、實驗設計 38 4.1不同電池電壓、電池放電量下EIS量測 38 4.2不同電池溫度下EIS量測 41 4.3不同電池循環充放電次數下EIS量測 42 4.4三極式電池EIS量測 43 4.5放電曲線量測 45 第五章、擬合方法建構 49 5.1擬合流程 49 5.1.1 MATLAB程式 50 5.1.2 擬合流程 51 5.2擬合結果 59 第六章、等效電路參數分析 70 6.1等效電路參數變化 70 6.2電化學模型參數與等效電路參數 72 6.2.1 利用電化學模型計算之i0找出Rct 72 6.2.2 利用sigma計算電極表面鋰離子擴散係數 78 6.3鋰離子電池等效電路參數與活化能 80 6.3.1 活化能 80 6.3.2 活化能在本文之應用 82 第七章、電池放電曲線模擬 87 7.1電池放電曲線 87 7.2電池放電曲線與電池等效電路 89 7.3電池開路電壓與開路電壓估算法 90 7.4電池放電曲線模擬結果 94 第八章、結論與未來展望 98 8.1結論 98 8.2未來展望 100 | |
dc.language.iso | zh-TW | |
dc.title | 利用電池等效電路探討鋰離子電池阻抗頻譜與放電行為 | zh_TW |
dc.title | Analysis of Spectrum and Discharging Behavior of Lithium-ion Battery Using Equivalent Circuit Model | en |
dc.type | Thesis | |
dc.date.schoolyear | 102-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 郭志禹(Chih-Yu Kuo) | |
dc.subject.keyword | 鋰離子電池,電化學阻抗頻譜法,電池阻抗頻譜,鋰離子電池等效電路,模擬方法,等效電路,電化學參數,電池放電行為,開路電壓, | zh_TW |
dc.subject.keyword | lithium-ion battery,Electrochemical Impedance Spectroscopy,spectra,simulation method,equivalent-circuit model,electrochemical parameter,discharging behavior,open circuit voltage, | en |
dc.relation.page | 100 | |
dc.rights.note | 未授權 | |
dc.date.accepted | 2014-08-08 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 應用力學研究所 | zh_TW |
顯示於系所單位: | 應用力學研究所 |
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