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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 謝國煌(Kuo-Huang Hsieh) | |
dc.contributor.author | Yu-Ting Lin | en |
dc.contributor.author | 林俞廷 | zh_TW |
dc.date.accessioned | 2021-06-08T00:49:52Z | - |
dc.date.copyright | 2015-07-20 | |
dc.date.issued | 2015 | |
dc.date.submitted | 2015-07-09 | |
dc.identifier.citation | 1. Bayer, O., The Diisocyanate Polyaddition Process (Polyurethanes) Description of a New Principle for Building up High-Molecular Compounds. Angewandte Chemin, 1947. 59: p. 257-72.
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/18059 | - |
dc.description.abstract | 現在應用在醫療方面的生醫材料種類是越來越多,其中近年來以高透濕性材料為特色的應用有著很大的發展潛力,因此也引起許多國內外學者投入相關研究。
而本論文研究主要分成兩個部分: 第一個部分研究方向為提高聚氨酯的透濕能力與其機械強度,期望能在生醫材料方面有更廣泛用途,利用不同重量比的聚二元醇,聚乙二醇(Poly(ethylene glycol))與聚丙二醇(poly(propylene glycol))和1,6-己二異氰酸酯(Hexamethylene diisocyanate)進行聚氨酯合成反應後,再塗佈成膜對其進行熱性質、拉伸、水氣穿透、生物相容性等性質分析。 第二部分亦是第一部分的延伸,由直鏈型改為星狀型聚氨酯,研究方向為合成星狀聚氨酯水凝膠(Polyurethane hydrogel),利用聚丙三醇(Poly(propylene glycol) triol)和二異氰酸異佛爾酮(Isophorone diisocyanate, IPDI),調整不同比例的聚二元醇,聚乙二醇(Poly(ethylene glycol))與聚丙二醇(poly(propylene glycol))來合成星狀的聚氨酯水凝膠,並對其熱性質、水氣透過率、黏著性等進行分析探討。 | zh_TW |
dc.description.abstract | In my study, it was mainly composed of two major parts. The polymer materials were designed to be with high water vapor transmission rate and well mechanical properties. In the first part, both PEG(poly(ethylene glycol)) and PPG(poly(propylene glycol)) acted as the soft segment were introduced into the procedure of synthesizing polyurethane. We could find the influences of various molar ratio of PEG and PPG on their thermal property, mechanical property, water vapor transmission rate, biocompatibility, and so on.
In the second part of the study, it was followed by the first part. By using the PPG triol (Poly(propylene glycol) triol) and changing the molar ratio of polydiols, different star-shaped polyurethane hydrogel were produced. To see the performance of polyurethane hydrogel, thermal property, water vaper transmission rate, adhesion and so forth were analysized. | en |
dc.description.provenance | Made available in DSpace on 2021-06-08T00:49:52Z (GMT). No. of bitstreams: 1 ntu-104-R02524031-1.pdf: 5629239 bytes, checksum: a29982a782a00f93dee1f3888512b40c (MD5) Previous issue date: 2015 | en |
dc.description.tableofcontents | 致謝 I
中文摘要 II Abstract III 目錄 IV 圖目錄 VI 表目錄 VIII 第一章 緒論 1 1.1. 前言 1 1.2. 研究目的 2 第二章 文獻回顧 3 2.1. 聚氨酯 3 2.1.1. 聚氨酯簡介 3 2.1.2. 聚氨酯的微觀相分離 5 2.1.3. 聚氨酯的合成反應與催化劑 6 2.2. 聚氨酯材料 10 2.2.1. 聚氨酯薄膜與彈性體材料 10 2.2.2. 聚氨酯膠與水凝膠 12 2.3. 膠的簡介[57] 15 2.4. 黏著理論 17 2.4.1. 濕潤作用[64] 17 2.4.2. 黏著機制 19 2.5. 聚氨酯膠物性[68,69] 23 2.6. 皮膚構造簡介 25 2.7. 傷口癒合機制簡介[77] 29 第三章 實驗方法 33 3.1. 實驗藥品 33 3.2. 實驗儀器 35 3.3. 實驗步驟 38 3.3.1. 聚氨酯薄膜的合成 38 3.3.2. 聚氨酯水凝膠合成 41 3.4. 材料性質測試 44 第四章 結果與討論 49 4.1. 傅立葉轉換紅外線光譜分析( Fourier-Transformed Infrared Spectra, FT-IR ) 49 4.2. 熱重分析( Thermal Gravimetric Analysis , TGA ) 51 4.3. 微差掃描卡計儀分析(Differential Scanning Calorimetry, DSC) 54 4.4. 拉伸測試分析( Tensile Strength Test ) 59 4.5. 剝離強度測試分析 61 4.6. 初期力測試分析(Tack Rolling Ball) 62 4.7. 水氣透過率測試分析(Water Vapor Transmission Rate) 63 4.8. 細胞相容性分析 65 第五章 結論 68 參考文獻 70 | |
dc.language.iso | zh-TW | |
dc.title | 高透濕性聚氨酯材料研究應用 | zh_TW |
dc.title | Synthesis and Characterization of Highly Water-Permeable of PEG-based Polyurethane | en |
dc.type | Thesis | |
dc.date.schoolyear | 103-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 林江珍,陳思賢 | |
dc.subject.keyword | 聚氨酯,聚乙二醇,透濕性,生物相容性,黏著性, | zh_TW |
dc.subject.keyword | Polyurethane,Poly(ethylene glycol),WVTR,Biocompatibility,Adhesion, | en |
dc.relation.page | 78 | |
dc.rights.note | 未授權 | |
dc.date.accepted | 2015-07-09 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
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