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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 連雙喜(Shuang-Shii Lian) | |
| dc.contributor.author | Sheng-Wen Chiang | en |
| dc.contributor.author | 姜勝文 | zh_TW |
| dc.date.accessioned | 2021-06-08T00:13:42Z | - |
| dc.date.copyright | 2013-08-09 | |
| dc.date.issued | 2013 | |
| dc.date.submitted | 2013-08-02 | |
| dc.identifier.citation | [1] 衣寶廉, '燃料電池-原理與應用,' 2005.
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K. Lin, K. H. Huang, and K. L. Ou, 'Improvement on hardness and corrosion resistance of ferritic stainless steel via PVD-(Ti,Cr)N coatings,' Surface and Coatings Technology. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/17448 | - |
| dc.description.abstract | 傳統固態氧化物燃料電池(SOFC)是以Ni-YSZ複合材料作為陽極支撐，其缺點在於Ni的成本過高，而且以碳氫氣體作為燃料時，會有積碳的現象發生，造成能量轉換效率降低。而Fe-Cr合金或不鏽鋼，製造的陽極支撐材，其成本低，與Ni-YSZ陽極熱膨脹係數的匹配性佳，並有良好的高溫抗氧化性。
本研究的目的在於探討新發展的多孔支撐材之性質，材料以不鏽鋼為主，用旋轉電極製備的雙層金屬粉末，其內層是430不鏽鋼，外層是Cu以改善積碳能力。製備出來的粉末將與商業430不鏽鋼粉混和，並添加PMMA造孔劑，以粉末冶金的方式燒結。燒結後之燒結品作以下性質分析：孔隙率、高溫氧化實驗、高溫電阻實驗、透氣率實驗以及維氏硬度實驗。 | zh_TW |
| dc.description.abstract | Conventional anode support of solid oxide fuel cell (SOFC) was made with Ni-YSZ cermet materials which had drawbacks of high cost and performance reduce due to carbon deposition with hydrocarbon fuel gas. The high chromium contained Fe-Cr alloy are good candidates for anode support due to its low cost and pretty well high temperature oxidation resistance. Besides, the coefficient of thermal expansion of Fe-Cr alloy is close to the solid electrolyte.
The aim of this research is to develop copper contained dual layer powders to improve porous substrate. The metal powders were made by rotating electrode process and the powder has a structure of dual layers. The inner layer is ss430 and the outer layer is copper to reduce carbon soot. We mixed the powders with commercial ss430 fine powders and PMMA pore formers. Porous substrates were prepared by die-pressing and sintered in hydrogen. The sintered specimens were then evaluated with high temperature oxidation resistance test, porosity, high temperature ASR test, permeability test and Vickers hardness test. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-08T00:13:42Z (GMT). No. of bitstreams: 1 ntu-102-R00527039-1.pdf: 12098288 bytes, checksum: 898dbe601b474fff47aa49586125f9fa (MD5) Previous issue date: 2013 | en |
| dc.description.tableofcontents | 口試委員會審定書 #
謝誌 i 中文摘要 ii ABSTRACT iii 目錄 iv 圖目錄 vii 表目錄 xi 符號表 xii 第一章 序論 1 第二章 文獻回顧 3 2.1燃料電池理論 3 2.1.1 固態氧化物燃料電池(SOFC)簡介 3 2.1.2 固態氧化物燃料電池工作原理 4 2.1.3 固態氧化物燃料電池之陽極性質介紹 9 2.1.4 固態氧化物燃料電池之陽極支撐材發展現況 12 2.1.5 肥粒鐵系不鏽鋼陽極支撐材之工作溫度 16 2.2 常見陽極與陽極支撐材造孔劑 19 2.3 雙自熔旋轉電極理論 20 2.3.1 離心噴霧理論 20 2.3.2旋轉電極製粉方式與特性 25 第三章 實驗設計與分析 26 3.1 實驗設計 26 3.2 雙自熔旋轉電極製粉 27 3.2.1 旋轉電極簡介 27 3.2.2電極棒材料選擇 29 3.2.3 雙自熔旋轉電極製粉程序 30 3.3 雙層粉末性質分析 31 3.3.1 粉末粒徑分析 31 3.3.2 粉末高溫氧化增重實驗 32 3.3.3掃描穿透式電子顯微鏡(Scanning Electron Microscope, SEM)與能量分散光譜儀(Energy Dispersive Spectrometer, EDS)分析 33 3.4 粉末冶金燒結實驗 34 3.5 陽極支撐材性質分析 37 3.5.1 支撐材形貌及截面分析 37 3.5.2 孔隙率計算 38 3.5.3 高溫氧化增重實驗 38 3.5.4 維氏硬度實驗 39 3.5.5 四點探針電阻量測 40 3.5.6 透氣率量測 41 第四章 結果與討論 43 4.1 雙層粉末性質分析結果 43 4.2 陽極支撐材性質分析結果 48 4.2.1 陽極支撐材金相 48 4.2.2 陽極支撐材截面及孔隙率計算 57 4.2.3 高溫氧化增重 63 4.2.4 高溫氧化後試片形貌分析 66 4.2.5 高溫電阻量測結果 72 4.2.6 透氣率量測結果 73 4.2.7 維氏硬度試驗 74 第五章 結論 75 參考文獻 77 | |
| dc.language.iso | zh-TW | |
| dc.title | 以雙自熔旋轉電極製備多孔支撐材性質之探討 | zh_TW |
| dc.title | Property of Porous Substrate Made with Double Consumable Rotating Electrode Powder Technology | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 101-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 王錫福(Xi-Fu Wang),林立夫(Li-Fu Lin),李瑞益(Ruey-Yi Lee) | |
| dc.subject.keyword | 固態氧化物燃料電池,陽極支撐材,粉末冶金,旋轉電極,PMMA造孔劑, | zh_TW |
| dc.subject.keyword | solid oxide fuel cell,anode support,powder metallurgy,rotating electrode process,PMMA pore formers, | en |
| dc.relation.page | 79 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2013-08-02 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 材料科學與工程學系 | |
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