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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱勝賢(Sheng-Hsien Chiu) | |
| dc.contributor.author | Ming-Jhe Li | en |
| dc.contributor.author | 李明哲 | zh_TW |
| dc.date.accessioned | 2021-06-08T00:12:41Z | - |
| dc.date.issued | 2013 | |
| dc.date.submitted | 2013-08-05 | |
| dc.identifier.citation | (1) Robinson, G. M. J. Chem. Soc., Trans. 1915, 107, 267.
(2) (a) Lindsey, A. S. J. Chem. Soc. 1965, 1685. (b) Lindsey, A. S. Chem. Ind. (London, U. K.) 1963, 823. (3) Erdtman, H.; Haglid, F.; Ryhage, R. Acts Chem. Scand. 1964, 18, 1249. (4) Goldup, A.; Morrison, A. B.; Smith, G. W. J. Chem. Soc. 1965, 3864. (5) Zimmermann, H.; Tolstoy, P.; Limbach, H.-H.; Poupko, R.; Luz, Z. J. Phy. Chem. B 2004, 108, 18772. (6) Steed, J. W.; Junk, P. C.; Atwood, J. L.; Barnes, M. J.; Raston, C. L.; Burkhalter, R. S. J. Am. Chem. Soc. 1994, 116, 10346. (7) Matsubara, H.; Hasegawa, A.; Shiwaku, K.; Asano, K.; Uno, M.; Takahashi, S.; Yamamoto, K. Chem. Lett. 1998, 27, 923. (8) Huerta, E.; Metselaar, G. A.; Fragoso, A.; Santos, E.; Bo, C.; de Mendoza, J. Angew. Chem. Int. Ed. 2007, 46, 202. (9) Costante-Crassous, J.; Marrone, T. J.; Briggs, J. M.; McCammon, J. A.; Collet, A. J. Am. Chem. Soc. 1997, 119, 3818. (10) Garel, L.; Lozach, B.; Dutasta, J. P.; Collet, A. J. Am. Chem. Soc. 1993, 115, 11652. (11) Bartik, K.; Luhmer, M.; Dutasta, J.-P.; Collet, A.; Reisse, J. J. Am. Chem. Soc. 1998, 120, 784. (12) Mecozzi, S.; Rebek, J. J. Chem. Eur. J. 1998, 4, 1016. (13) Fogarty, H. A.; Berthault, P.; Brotin, T.; Huber, G.; Desvaux, H.; Dutasta, J.-P. J. Am. Chem. Soc. 2007, 129, 10332. (14) Akabori, S.; Miura, M.; Takeda, M.; Yuzawa, S.; Habata, Y.; Ishii, T. Supramol. Chem. 1996, 7, 187. (15) Garcia, C.; Humiliere, D.; Riva, N.; Collet, A.; Dutasta, J.-P. Org. Biomol. Chem. 2003, 1, 2207. (16) Hirsch, A. The chemistry of the fullerenes; G. Thieme Verlag: Stuttgart ;, 1994. (17) Kadish, K. M.; Ruoff, R. S. Fullerenes : chemistry, physics and technology; John Wiley: New York :, 2000. (18) Kroto, H. W.; Heath, J. R.; O'Brien, S. C.; Curl, R. F.; Smalley, R. E. Nature 1985, 318, 162. (19) Semenov, K. N.; Charykov, N. A.; Keskinov, V. A.; Piartman, A. K.; Blokhin, A. A.; Kopyrin, A. A. J. Chem. Eng. Data 2009, 55, 13. (20) Komatsu, K.; Murata, M.; Murata, Y. Science 2005, 307, 238. (21) Kurotobi, K.; Murata, Y. Science 2011, 333, 613. (22) Kawase, T.; Tanaka, K.; Seirai, Y.; Shiono, N.; Oda, M. Angew. Chem. Int. Ed. 2003, 42, 5597. (23) Kawase, T.; Fujiwara, N.; Tsutumi, M.; Oda, M.; Maeda, Y.; Wakahara, T.; Akasaka, T. Angew. Chem. Int. Ed. 2004, 43, 5060. (24) Iwamoto, T.; Watanabe, Y.; Sadahiro, T.; Haino, T.; Yamago, S. Angew. Chem. Int. Ed. 2011, 50, 8342. (25) Nielsen, K. A.; Sarova, G. H.; Martin-Gomis, L.; Stein, P. C.; Sanguinet, L.; Levillain, E.; Sessler, J. L.; Guldi, D. M.; Sastre-Santos, A.; Jeppesen, J. O. J. Am. Chem. Soc. 2007, 130, 460. (26) Grimm, B.; Santos, J.; Illescas, B. M.; Munoz, A.; Guldi, D. M.; Martin, N. J. Am. Chem. Soc. 2010, 132, 17387. (27) Yanagisawa, M.; Tashiro, K.; Yamasaki, M.; Aida, T. J. Am. Chem. Soc. 2007, 129, 11912. (28) Gil-Ramirez, G. n.; Karlen, S. D.; Shundo, A.; Porfyrakis, K.; Ito, Y.; Briggs, G. A. D.; Morton, J. J. L.; Anderson, H. L. Org. Lett. 2010, 12, 3544. (29) Song, J.; Aratani, N.; Shinokubo, H.; Osuka, A. J. Am. Chem. Soc. 2010, 132, 16356. (30) Meng, W.; Breiner, B.; Rissanen, K.; Thoburn, J. D.; Clegg, J. K.; Nitschke, J. R. Angew. Chem. Int. Ed. 2011, 50, 3479. (31) Hebard, A. F. Annu. Rev. Mater. Sci. 1993, 23, 159. (32) Whetten, R. L.; Thilgen, C.; Diederich, F. In Buckminsterfullerenes; Billups, W. E., Ciufolini, M. A., Eds.; VCH: New York, 1993, 59. (33) Suzuki, T.; Nakashima, K.; Shinkai, S. Chem. Lett. 1994, 23, 699. (34) Atwood, J. L.; Koutsantonis, G. A.; Raston, C. L. Nature 1994, 368, 229. (35) Inokuma, Y.; Arai, T.; Fujita, M. Nat. Chem. 2010, 2, 780. (36) Cram, D. J.; Karbach, S.; Kim, Y. H.; Baczynskyj, L.; Kalleymeyn, G. W. J. Am. Chem. Soc. 1985, 107, 2575. (37) Jasat, A.; Sherman, J. C. Chem. Rev. 1999, 99, 931. (38) Yoon, J.; Sheu, C.; Houk, K. N.; Knobler, C. B.; Cram, D. J. J. Org. Chem. 1996, 61, 9323. (39) Yoon, J.; Cram, D. J. J. Am. Chem. Soc. 1997, 119, 11796. (40) Houk, K. N.; Nakamura, K.; Sheu, C.; Keating, A. E. Science 1996, 273, 627. (41) Scrivens, W. A.; Bedworth, P. V.; Tour, J. M. J. Am. Chem. Soc. 1992, 114, 7917. (42) Andersson, T.; Nilsson, K.; Sundahl, M.; Westman, G.; Wennerstrom, O. J. Chem. Soc., Chem. Commun. 1992, 604. (43) Brabec, C., Dyakonov, V., Scherf, U., Eds.; Wiley-VCH Verlag GmbH & Co. KGaA: 2009. (44) Atwood, J. L.; Barbour, L. J.; Raston, C. L.; Sudria, I. B. N. Angew. Chem. Int. Ed. 1998, 37, 981. (45) Jurow, M.; Farley, C.; Pabon, C.; Hageman, B.; Dolor, A.; Drain, C. M. Chem. Commun. 2012, 48, 4731. (46) Zhang, C.; Wang, Q.; Long, H.; Zhang, W. J. Am. Chem. Soc. 2011, 133, 20995. (47) Kishi, N.; Li, Z.; Yoza, K.; Akita, M.; Yoshizawa, M. J. Am. Chem. Soc. 2011, 133, 11438. (48) Wong T.-H. Master Thesis, Dept. Chem. NTU (49) Chu Y.-C. Master Thesis, Dept. Chem. NTU (50) Huang C.-H. Master Thesis, Dept. Chem. NTU (51) Brotin, T.; Roy, V.; Dutasta, J.-P. J. Org. Chem. 2005, 70, 6187. (52) Quan, M. L. C.; Cram, D. J. J. Am. Chem. Soc. 1991, 113, 2754. (53) Diederich, F.; Whetten, R. L. Acc. Chem. Res. 1992, 25, 119. (54) Vostrowsky, O.; Hirsch, A. Chem. Rev. 2006, 106, 5191. (55) Rodriguez-Fortea, A.; Balch, A. L.; Poblet, J. M. Chem. Soc. Rev. 2011, 40, 3551. (56) Von dem Bussche-Hunnefeld, C.; Buhring, D.; Knobler, C. B.; Cram, D. J. J. Chem. Soc., Chem. Commun. 1995, 1085. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/17434 | - |
| dc.description.abstract | 在本研究中，我們合成出一以環三聚藜烴為基礎分子籠 1，發現在含有 C60 情形下傾向與 C70 在室溫下可被分離的活門囚籠錯合物 (hemicarceplex)，除了透過核磁共振光譜解析來研究其結合與解離的動力學行為與鍵結常數外，還利用這樣的選擇性應用在分離純化市售之富勒烯萃取物 (fullerene extract)。最後在不以高效率液相層析或再結晶的方式，而是透過超分子化學系統概念可以分離出相當高純度 C70 (≥99%)。 | zh_TW |
| dc.description.abstract | Herein we reported a cyclotriveratrylene-based molecular cage that favored the formation of a room temperature–isolable hemicarceplex with C70, in the presence of C60, has been developed. Significant differences in the association and dissociation kinetic properties of the molecular cage and buckyballs allowed the isolation of C70 in high purity (≥ 99.0%) from a commercial fullerene extract without the need for recrystallization or HPLC. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-08T00:12:41Z (GMT). No. of bitstreams: 1 ntu-102-D97223113-1.pdf: 9729448 bytes, checksum: 3c62c3a3aa2a572ec5a5ab7f09de4ff3 (MD5) Previous issue date: 2013 | en |
| dc.description.tableofcontents | 論文發表 iii
目錄 iv 圖目錄 v 表目錄 vii 流程目錄 vii 第一章 利用以CTV為基礎之分子容器分離純化富勒烯萃取物 1 1.1 簡介 2 1.1.1 環三聚藜烴家族 2 1.1.2 富勒烯家族 6 1.1.3 富勒烯在主客化學系統的應用 9 1.1.4 利用超分子化學分離與純化富勒烯 11 1.1.5 分子容器與客體分子的關係 14 1.2 研究動機 16 1.3 分子設計與合成 17 1.4 分子鍵結行為與穩定性 20 1.5 分離純化市售富勒烯萃取物中的 C70 26 1.6 結論 32 實驗部分 33 參考文獻 43 附錄 47 | |
| dc.language.iso | zh-TW | |
| dc.title | 利用以CTV 為基礎之分子容器分離純化富勒烯萃取物 | zh_TW |
| dc.title | Hemicarceplex Formation with a Cyclotriveratrylene-Based Molecular Cage Allows Isolation of High-Purity C70 Directly from Fullerene Extracts | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 101-2 | |
| dc.description.degree | 博士 | |
| dc.contributor.oralexamcommittee | 徐秀福,陳平,李文山,賴建成,薛聖耀 | |
| dc.subject.keyword | 富勒烯,環三聚藜烴,半囚籠錯合物, | zh_TW |
| dc.subject.keyword | fullerene,CTV,hemicarceplex, | en |
| dc.relation.page | 84 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2013-08-05 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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