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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 邱勝賢 | |
dc.contributor.author | Yu-Geng Wu | en |
dc.contributor.author | 吳宇耕 | zh_TW |
dc.date.accessioned | 2021-06-07T23:44:01Z | - |
dc.date.copyright | 2014-07-29 | |
dc.date.issued | 2014 | |
dc.date.submitted | 2014-07-14 | |
dc.identifier.citation | 參考文獻
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/16703 | - |
dc.description.abstract | 我們合成了一個可與C60形成室溫下可被分離之活門囚籠錯合物(hemicarceplex)之分子牢籠。利用此一分子,我們可以自市售之富勒烯萃取物(fullerene extract)中直接分離純化出純度≥98%之C60,毋須經過液相層析或再結晶的程序。 | zh_TW |
dc.description.abstract | A cyclotriveratrylene-based molecular cage that favors the formation of a room temperature isolable C60-incarcerated hemicarceplex had been synthesized. Significant differences in the association and dissociation kinetics of the molecular cage and fullerenes allowed the isolation of C60 in high purity (≥98.0%) from a commercial fullerene extract without the need for recrystallization or HPLC. | en |
dc.description.provenance | Made available in DSpace on 2021-06-07T23:44:01Z (GMT). No. of bitstreams: 1 ntu-103-R01223164-1.pdf: 3465975 bytes, checksum: e9819f064d026b634c47e38a9aefe08e (MD5) Previous issue date: 2014 | en |
dc.description.tableofcontents | 目錄.........iii
圖目錄.......iv 表目錄.......v 流程目錄.... vi 1.1 簡介.... ............................2 1.1.1 前言...... ........................2 1.1.2 環三聚藜烴 ....................... 3 1.1.3 富勒烯萃取物.......................4 1.1.4 分離純化富勒烯 ................... 6 1.1.5 分子容器與客體分子的關係.......... 9 1.2 研究動機............................ 10 1.3 分子設計與合成...................... 10 1.4 分子鍵結行為與穩定性................ 13 1.5 分離純化市售富勒烯萃取物中的C60..... 17 1.6 結論................................ 20 實驗部分 ............................... 21 參考文獻 ............................... 28 附錄.................................... 30 | |
dc.language.iso | zh-TW | |
dc.title | 利用準分子牢籠自富勒烯萃取物中分離純化C60 | zh_TW |
dc.title | Using Hemicarceplex to Isolate High Purity C60 Directly From Fullerene Extract | en |
dc.type | Thesis | |
dc.date.schoolyear | 102-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 徐秀福,賴建成,陳平,李文山 | |
dc.subject.keyword | 囚籠錯合物, | zh_TW |
dc.subject.keyword | Hemicarceplex, | en |
dc.relation.page | 56 | |
dc.rights.note | 未授權 | |
dc.date.accepted | 2014-07-14 | |
dc.contributor.author-college | 理學院 | zh_TW |
dc.contributor.author-dept | 化學研究所 | zh_TW |
顯示於系所單位: | 化學系 |
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