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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/16683Full metadata record
| ???org.dspace.app.webui.jsptag.ItemTag.dcfield??? | Value | Language |
|---|---|---|
| dc.contributor.advisor | 邱勝賢(Sheng-Hsien Chiu) | |
| dc.contributor.author | Ke-Dian Wu | en |
| dc.contributor.author | 吳克典 | zh_TW |
| dc.date.accessioned | 2021-06-07T23:43:33Z | - |
| dc.date.copyright | 2014-07-29 | |
| dc.date.issued | 2014 | |
| dc.date.submitted | 2014-07-17 | |
| dc.identifier.citation | 1. Harris, J. M., Zalipsky, S. Eds. Poly(ethylene glycol): Chemistry and Biological Applications; ACS: San Francisco, 1997.
2. Noujeim, N.; Zhu, K.; Vukotic, V. N.; Loeb, S. J. Org. Lett. 2012, 14, 2484. 3. Niu, Z.; Huang, F.; Gibson, H. W. J. Am. Chem. Soc. 2011, 133, 2836. 4. Hsueh, S.-Y.; Cheng, K.-W,; Lai, C.-C and Chiu S.-H. Angew. Chem., Int. Ed. 2008, 47, 4436. 5. Tung, S.-T.; Lai, C.-C.; Liu, Y.-H.; Peng, S.-M.; Chiu, S.-H. Angew. Chem., Int. Ed. 2013, 52, 13269. 6. (a) Hsueh, S.-Y.; Cheng, K.-W.; Lai, C.-C.; Chiu, S.-H. Angew. Chem., Int. Ed. 2008, 47, 4436. (b) Hsu, C.-C.; Chen, N.-C.; Lai, C.-C.; Liu, Y.-H.; Peng, S.-M.; Chiu, S.-H. Angew. Chem., Int. Ed. 2008, 47, 7475. 7. Braun, O.; Vogtle, F. Synlett 1997, 1184. 8. Baskin, J. M.; Prescher, J. A.; Laughlin, S. T.; Agard, N.; Chang, P. V.; Miller, I. A.; Lo, A.; Codelli, J.; Bertozzi, C. R. Proc. Natl. Acad. Sci. USA. 2007, 104, 16793 9. McKay, C. S.; Moran, J.; Pezacki, J. P. Chem. Commun. 2010, 46, 931. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/16683 | - |
| dc.description.abstract | 我們發現寡聚乙二醇基團可藉由鈉離子模板穿隧大環分子BPX26C6，並在無溶劑的條件下合成其相對應的[2]車輪烷。在此類[2]車輪烷中，具有四甘醇基團者可表達分子開關的行為，利用加入或移除鉀離子，可使大環分子選擇性地在四甘醇基團或氨基甲酸酯(Carbamate)基團間來回移動。 | zh_TW |
| dc.description.abstract | Threading of di-, tri-, and tetra(ethylene glycol) through the macrocycle BPX26C6 in the presence of templating Na+ ions was proven by the synthesis of the corresponding [2]rotaxanes under solvent-free conditions. Among them, a [2]rotaxane featuring both tetra(ethylene glycol) and carbamate stations behaves as a molecular switch that can be controlled reversibly through the application of the KTFPB/[2.2.2]cryptand reagent pair. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-07T23:43:33Z (GMT). No. of bitstreams: 1 ntu-103-R01223178-1.pdf: 7709536 bytes, checksum: ce1873502dbe21cb64cb704fb79f64ae (MD5) Previous issue date: 2014 | en |
| dc.description.tableofcontents | 中文摘要 i
英文摘要 ii 論文發表 iii 目錄 iv 圖目錄 v 壹、以鈉離子為模板在無溶劑條件下合成車輪烷與分子開關之研究 1 1.1 研究動機 2 1.2 結果與討論 5 1.3 結論 15 貳、實驗部分 16 参、參考文獻 32 附錄 33 | |
| dc.language.iso | zh-TW | |
| dc.subject | 具開關行為之[2]車輪烷 | zh_TW |
| dc.subject | Na+ Ion Templated Threading of Oligo(ethylene glycol) Chains | en |
| dc.title | 以鈉離子為模板在無溶劑條件下合成車輪烷與分子開關之研究 | zh_TW |
| dc.title | Na+ Ion Templated Threading of Oligo(ethylene glycol) Chains through BPX26C6 Allows Synthesis of [2]Rotaxane under Solvent-Free Conditions | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 102-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 陳平,徐秀福,賴建成,李文山 | |
| dc.subject.keyword | 具開關行為之[2]車輪烷, | zh_TW |
| dc.subject.keyword | Na+ Ion Templated Threading of Oligo(ethylene glycol) Chains, | en |
| dc.relation.page | 71 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2014-07-17 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| Appears in Collections: | 化學系 | |
Files in This Item:
| File | Size | Format | |
|---|---|---|---|
| ntu-103-1.pdf Restricted Access | 7.53 MB | Adobe PDF |
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