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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/16365完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 陳俊維(Chun-Wei Chen) | |
| dc.contributor.author | Chi-Jie Wang | en |
| dc.contributor.author | 王麒傑 | zh_TW |
| dc.date.accessioned | 2021-06-07T18:11:35Z | - |
| dc.date.copyright | 2012-07-16 | |
| dc.date.issued | 2012 | |
| dc.date.submitted | 2012-06-29 | |
| dc.identifier.citation | Chapter1:Yunfei Zhou,Michael Eck ,Michael Kruger, Bulk-heterojunction hybrid solar cells based on colloidal nanocrystals and conjugated polymers, Energy Environ. Sci, 3, 1851-1864, 2010
(2) Kevin M. Coakley and Michael D. McGehee Conjugated Polymer Photovoltaic Cells Chem. Mater. 16, 4533 – 4542, 2004 (3) Waldo J.E. Beek and Rene A.J. Janssen, Hybrid Polymer-Inorganic Photovoltaic Cells Hybrid Nanocomposites for Nanotechnology ,321-385, 2009 (4) Yunfei Zhou,Michael Eck and Michael Kruger, Organic-Inorganic Hybrid Solar Cells: State of the Art, Challenges and Perspectives ,Solar Cells,New Aspects and Solutions, 95-120 (5) Brian R. Saunders, Advances in Colloid and Interface Science 1381 – 23, (2008) (6) Magdalena Skompska, Hybrid conjugated polymer/semiconductor photovoltaic cells, Synthetic Metals 160 ,1–15, (2010) (7) Kevin M. Coakley and Michael D. McGehee, Conjugated Polymer Photovoltaic Cells ,Chem. Mater. 16, 4533 – 4542, 2004 (8) Eva Bundgaard, Low band gap polymers for Organic Photovoltaics ,ELSEVIER 954–985, 2007 (9) N. C. Greenham, X. G. Peng and A. P. Alivisatos, Charge separation and transport in conjugated-polymer/semiconductor-nanocrystal composites studied by photoluminescence quenching and photoconductivity, Phys. Rev. B:Condens. Matter, 54, 17628–17637, 1996 (10) X. G. Peng, L. Manna, W. D. Yang, J. Wickham, E. Scher, A. Kadavanich and A. P. Alivisatos, Shape control of CdSe nanocrystals, Nature, 404, 59–61, 2000 (11) W. U. Huynh, J. J. Dittmer and A. P. Alivisatos, Hybrid Nanorod-Polymer Solar Cells, Science, 295,2425–2427, 2002 (12) J. D. Olson, G. P. Gray and S. A. Carter, Optimizing hybrid photovoltaics through annealing and ligand choice, Sol. Energy Mater. Sol.Cells, 93, 519–523, 2009 Chapter2:(1) Nikolay Radychev, Irina Lokteva, Florian Witt, Joanna Kolny-Olesiak, Holger Borchert, and J?urgen Parisi, Physical Origin of the Impact of Different Nanocrystal Surface Modifications on the Performance of CdSe/P3HT Hybrid Solar Cells, J. Phys. Chem, 14111–14122, 2011 (2) Adam J. Moule, Lilian Chang, Chandru Thambidurai, Ruxandra Vidu and Pieter Stroeve ,Hybrid solar cells: basic principles and the role of ligands ,J. Mater. Chem., 22, 2351-2368, 2012 (3) Wendy U. Huynh, Janke J. Dittmer, William C. Libby ,Gregory L. Whiting ,A Paul Alivisatos ,Controlling the Morphology of Nanocrystal-Polymer Composites for Solar Cells, Adv.Funct.Mater,13,NO.1,2003 (4) Elif Arici, N. Serdar Sariciftci, Hybrid Solar Cells ,Nanoscience and Nanotechnology , 929-944,2004 (5) Cunningham, Paul D, Ph.D, Optical pump terahertz probe studies of semiconducting polymers, UNIVERSITY OF MARYLAND, BALTIMORE COUNTY, 2010 (6)Biswajit Ray , Pradeep R. Nair, Muhammad A. Alam ,Annealing dependent performance of organic bulk-heterojunction solar cells: A theoretical perspective, ELSEVIER ,3287–3294, 2011 (7)Brian R. Saunders a, Michael L. Turnerb Nanoparticle ,polymer photovoltaic cells, ELSEVIER ,1–23, 2008 Chapter3:(1) Irina Lokteva, Nikolay Radychev, Florian Witt, Holger Borchert, Ju‥rgen Parisi, and Joanna Kolny-Olesiak ,Surface Treatment of CdSe Nanoparticles for Application in Hybrid Solar Cells: The Effect of Multiple Ligand Exchange with Pyridine, Physical Chemistry, 12784-12791,2010 (2) Nikolay Radychev, Irina Lokteva, Florian Witt, Joanna Kolny-Olesiak, Holger Borchert, and Jurgen Parisi ,Physical Origin of the Impact of Different Nanocrystal Surface Modifications on the Performance of CdSe/P3HT Hybrid Solar Cells ,J. Phys. Chem.,14111–14122 , 2011 (3) Yun-Yue Lin, Tsung-Hung Chu, Shao-Sian Li, Chia-Hao Chuang, Chia-Hao Chang, Wei-Fang Su, Ching-Pin Chang, Ming-Wen Chu, and Chun-Wei Chen, Interfacial Nanostructuring on the Performance of Polymer/TiO2 Nanorod Bulk Heterojunction Solar Cells ,J. AM. CHEM. SOC., 131, 3644–3649, 2009 (4) Wendy U. Huynh, Janke J. Dittmer, William C. Libby, Gregory L. Whiting,A Paul Alivisatos ,Controlling the Morphology of Nanocrystal-Polymer Composites for Solar Cells Adv.Funct.13 ,2003 (5) Jangwon Seo,Won Jin Kim,Sung Jin Kim,Kwang-Sup Lee,A. N. Cartwright,And Paras N. Prasad ,Polymer nanocomposite photovoltaics utilizing CdSe nanocrystals capped with a thermally cleavable solubilizing ligand ,Appl. Phys. Lett. 94, 133302, 2009 (6) Yunfei Zhou, Frank S. Riehle, Ying Yuan, Hans-Frieder Schleiermacher, Michael Niggemann et al. ,Improved efficiency of hybrid solar cells based on non-ligand-exchanged CdSe quantum dots and poly(3-hexylthiophene) ,Appl. Phys. Lett. 96, 013304 (2010) (7) Yunfei Zhou,Michael Eck and Michael Kruger, Bulk-heterojunction hybrid solar cells based on colloidal nanocrystals and conjugated polymers , Energy Environ. Sci, 3, 1851-1864., 2010 (8) Jinsong Liu, Toru Tanaka, Kevin Sivula, A. Paul Alivisatos, and Jean M. J. Fre′chet Employing End-Functional Polythiophene ,To Control the Morphology of Nanocrystal-Polymer Composites in Hybrid Solar Cells, J Am Chem Soc. , 6550-1, 2004 (9) Wendy U. Huynh, Janke J. Dittmer, A. Paul Alivisatos ,Hybrid Nanorod-Polymer Solar Cells ,Science ,2425-2427, 2002 (10) Shao-Sian Li, Ching-Pin Chang, Chih-Cheng Lin, Yun-Yue Lin, Chia-Hao Chang, Jer-Ren Yang, Ming-Wen Chu,and Chun-Wei Chen, Interplay of Three-Dimensional Morphologies and Photocarrier Dynamics of Polymer/TiO 2 Bulk Heterojunction Solar Cells, J. Am. Chem. Soc., 133, 11614 – 11620, 2011 (11) Magdalena Skompska ,Hybrid conjugated polymer/semiconductor photovoltaic cells ,ELSEVIER , 1–15,2010 (12) Ilan Gur, Neil A. Fromer, Chih-Ping Chen, Antonios G. Kanaras,and A. Paul Alivisatos, Hybrid Solar Cells with Prescribed Nanoscale Morphologies Based on Hyperbranched Semiconductor Nanocrystals ,Nano Lett. ,409-14, 2007 (13) Tingting Xu and Qiquan Qiao ,Conjugated polymer–inorganic semiconductor hybrid solar cells, Energy Environ. Sci. , 4, 2700-2720, 2011 (14) Kevin M. Coakley, Yuxiang Liu, Chiatzun Goh,and Michael D. McGehee, Ordered Organic–Inorganic Bulk Heterojunction Photovoltaic Cells ,MRS BULLETIN ,30, 2005 (15) Waldo J.E. Beek and Rene A.J. Janssen ,Hybrid Polymer-Inorganic Photovoltaic Cells ,Hybrid Nanocomposites for Nanotechnology , 321-385, 2009 (16) C. Y. Kuo, W. C. Tang, C. Gau, T. F. Guo, and D. Z. Jeng, Ordered bulk heterojunction solar cells with vertically aligned TiO2 nanorods embedded in a conjugated polymer ,Applied Physics Letters, 93, 2008 (17) Yun-Yue Lin,Chun-Wei Chen, Tsung-Hung Chu, Wei-Fang Su, Chih-Cheng Lin, Chen-Hao Ku, Jih-Jen Wu and Cheng-Hsuan Chen, Nanostructured metal oxide/conjugated polymer hybrid solar cells by low temperature solution processes, J. Mater. Chem., 17, 4571–4576, 2007 (18) Yunfei Zhou,Michael Eck and Michael Kruger ,Bulk-heterojunction hybrid solar cells based on colloidal nanocrystals and conjugated polymers ,Energy Environ. Sci., 3, 1851-1864, 2010 (19) Tingting Xu, Qiliang Chen, Dai-Hong Lin, Hsueh-Yu Wu, Ching-Fuh Lin, and Qiquan Qiao ,Self-assembled thienylsilane molecule as interfacial layer for ZnO nanowire/polymer hybrid system ,J. Photon. Energy 1, 011107,2011 (20) Sanja Tepavcevic, Seth B. Darling, Nada M. Dimitrijevic, Tijana Rajh, and StevenJ. Sibener ,Improved Hybrid Solar Cells via in situ UV Polymerization, small, 1776–1783, 2009 (21) Irene Gonzalez-Valls and Monica Lira-Cantu ,Vertically-aligned nanostructures of ZnO for excitonic solar cells: a review, Energy Environ. Sci. 2, 19-34, 2009 (22) Pedro Atienzar ,Thilini Ishwara,Benoit N. Illy,Mary P. Ryan,Brian C. O'Regan,James R. Durrant,and Jenny Nelson, Control of Photocurrent Generation in Polymer/ZnO Nanorod Solar Cells by Using a Solution-Processed TiO2 Overlayer, J. Phys. Chem. Lett., 708–713, 2010 (23) Lidan Wang,Dongxu Zhao,Zisheng Su,Binghui Li,Zhenzhong Zhang,and Dezhen Shen ,Enhanced Efficiency of Polymer/ZnO Nanorods Hybrid Solar Cell Sensitized by CdS Quantum Dots ,J. Electrochem. Soc., H804-H807, 2011 (24) Yanzhong Hao, Yinhu Cao, Bao Sun, Yingpin Li, Yanhui Zhang, Dongsheng Xu, A novel semiconductor-sensitized solar cell based on P3HT@CdS@TiO2 core-shell nanotube array ,Solar Energy Materials and Solar Cells, 101, 1a07-113, 2012 Chapter4:(1) K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang,S. V. Dubonos, I. V. Grigorieva and A. A. Firsov, Science,306, 666 , 2004 (2) Xin Li, Solar Cell with Graphene and Carbon Nanotube Hybrid Systems (3) Tao Song,aShuit-Tong Leeb and Baoquan Sun ,Prospects and challenges of organic/group IV nanomaterial solar cells, J. Mater. Chem., 22,4216-4232, 2012 (4) Shao-Sian Li, Kun-Hua Tu, Chih-Cheng Lin, Chun-Wei Chen and Manish Chhowalla ,Solution-Processable Graphene Oxide as an Efficient Hole Transport Layer in Polymer Solar Cells ,ACS ,3169–3174 .2010 (5) Kim, Y.-H.; Lee, S.-H.; Noh, J.; Han, S.-H. ,Performance and Stability of Electroluminescent Device with Self-Assembled Layers of Poly(3,4-ethylenedioxythiophene) Poly(styrenesulfonate) and Polyelectrolytes., Thin Solid Films, 510, 305–310, 2006 (6) Lagemaat, J.; Barnes, T. M.; Rumbles, G.; Shaheen, S. E.;Coutts, T. J.; Weeks, C.; Levitsky, I.; Peltola, J.; Glatkowski, P., Organic Solar Cells with Carbon Nanotubes Replacing In2O3 :Sn as the Transparent Electrode. Appl. Phys. Lett., 88, 233503, 2006 (7) Yanfei Xu, Yan Wang, Jiajie Liang, Yi Huang, Yanfeng Ma, Xiangjian Wan, and Yongsheng Chen ,A Hybrid Material of Graphene and Poly (3,4-ethyldioxythiophene) with High Conductivity, Flexibility, and Transparency ,Nano Res 2: 343 348, 2009 (8) Luca Valentini, Marta Cardinali,Silvia Bittolo Bon,Diego Bagnis,Raquel Verdejo,Miguel Angel Lopez-Manchado and Jose M. Kenny ,Use of butylamine modified graphene sheets in polymer solar cells, J. Mater. Chem., 20, 995-1000, 2010 (9) Chih-Cheng Lin, Di-Yan Wang, Kun-Hua Tu, You-Ting Jiang, Meng-Hsiang Hsieh, Chia-Chun Chen, and Chun-Wei Chen ,Enhanced infrared light harvesting of inorganic nanocrystal photovoltaic and photodetector on graphene electrode ,APPLIED PHYSICS LETTERS 98, 263509, 2011 (10) Yu-Ying Lee, Kun-Hua Tu, Chen-Chieh Yu, Shao-Sian Li, Jeong-Yuan Hwang, Chih-Cheng Lin, Kuei-Hsien Chen, Li-Chyong Chen, Hsuen-Li Chen, and Chun-Wei, Chen Top Laminated Graphene Electrode in a Semitransparent Polymer Solar Cell by Simultaneous Thermal Annealing/Releasing Method ,ACS NANO, 6564–6570,2011 (11) Yan Li , Yue Hu , Yang Zhao , Gaoquan Shi , Lier Deng , Yanbing Hou , and Liangti Qu, An Electrochemical Avenue to Green-Luminescent Graphene Quantum Dots as Potential Electron-Acceptors for Photovoltaics, Advanced Materials ,776–780, 2011 (12) Qian Liu, Zunfeng Liu, Xiaoyan Zhang, Nan Zhang, Liying Yang et al ,Organic photovoltaic cells based on an acceptor of soluble graphene Appl. Phys. Lett. 92, 223303 ,2008 (13) Qian Liu, Zunfeng Liu, Xiaoyan Zhang, Liying Yang, Nan Zhang,Guiling Pan, Shougen Yin, Yongsheng Chen, and Jun Wei ,Polymer Photovoltaic Cells Based on Solution-Processable Graphene and P3HT ,Adv. Funct. Mater., 19, 894–904, 2009 (14) Zhiyong Liu, Dawei He n , Yongsheng Wang n , Hongpeng Wu, Jigang Wang ,Solution-processable functionalized graphene in donor/acceptor-type organic photovoltaic cells,Solar Energy Materials and Solar Cells, 94, 1196-1200, 2010 | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/16365 | - |
| dc.description.abstract | 有機無機混參太陽能電池導入了無機奈米材料高電子傳輸率及高電負度的特性 ,改善了高分子遷移率低的缺點, 並增加紅外光吸收範圍。
但是,由於無機奈米材料的低溶解度,集中分佈導致不連續的傳輸路徑,有機無機界面載子分離受無機奈米材料表面不易導電的ligands及高復合率的影響使其效率沒有預期來的好. 本篇論文從光電流產生過程的角度來看影響有機無機混參太陽能電池效率的因素,探討morphology與無機奈米材料表面性質、幾何形狀/尺寸及維度的關係。 並探討如何藉由控制無機奈米材料表面電子性質及奈米結構來改善morphology以增進效率,我們討論如何修飾有機無機界面狀態,及利用無機奈米材料建構連續電子傳輸路徑,討論core shell structure來解決有機無機界面接觸面積小的問題，回顧及討論無機奈米材料對有機無機混參太陽能電池的限制及影響。 最後總結近來有機無機混參太陽能電池的發展現況,比如利用TiO2,ZnO,CdSe作為受體和電子傳輸介質並修飾其介面來改善載子分離，並形成二維、三維奈米結構來改善載子傳輸以及介紹二維奈米碳材graphene、graphene oxide作為透明電極、受體及電洞傳輸層在有機無機混參太陽能電池的應用。 | zh_TW |
| dc.description.abstract | Due to introduction of inorganic nano-semiconductor, organic-inorganic hybrid solar cell combines with high electron mobility and affinity to improve low mobility of conducting polymer and extended absorption range in red region.
However, the efficiency are limited by aggregation due to low solubility of inorganic nanocrystal in conducting polymer matrix and inefficient charge transfer between organic-inorganic interface due to insulating surface ligands capping on inorganic nanocrystal. In this essay, we study factors affecting efficiency from photocurrent generation process and research relationship between inorganic surface capping ligands/geometry/dimension and morphology and study how to control inorganic semiconductor surface properties and nanostructure to improve morphology and device performance. We discuss how to modify organic-inorganic interface and how to construct continuous electron transport pathway and discuss core shell structure to solve inefficient charge separation due to low interface area at interface, then review and discuss effect of inorganic nano-semiconductor on the organic-inorganic hybrid solar cell. Finally we sum up recent developments of organic-inorganic hybrid solar cell such as taking TiO2,ZnO,CdSe as electron acceptor and transport medium and modify the interface to improve charge separation and forming 2D、3D and prescribed nanostructure to improve charge transport and introduce 2D nano-carbon material graphene、graphene oxide as transparent electrode、electron acceptor and hole transport layer and discuss application in organic0inorganic hybrid solar cells. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-07T18:11:35Z (GMT). No. of bitstreams: 1 ntu-101-R98527065-1.pdf: 3186628 bytes, checksum: f993b26de4f086626c536e0d013709c9 (MD5) Previous issue date: 2012 | en |
| dc.description.tableofcontents | Contents
口試委員會審定書................................................................................................................................ I Acknowledgement.................................................................................................................................II 摘要………………………………………………………………………..........................................III Abstract……………………………………………………………………........................................IV Contents…………………………………………………………………….......................................VI List of Figure…………………………………………………………………………………………IX List of Table…………………………………………………………………………………………XX Chapter 1 Introduction………………………………………………………………………………...1 1.1 Research backgrounds…………………………………………………………………………1 1.1.1 Solar Cell Characterization………………………………………………………….....1 1.1.1.1 Basic Parameter………………………………………………………………..1 1.1.2 Classification of Solar Cell………………………………………………………….....4 1.1.2.1 Conventional Inorganic Solar Cell…………………………………………………4 1.1.2.2 Organic Solar Cell……………………………………….........................................5 1.1.2.3 Hybrid Solar Cell………………………………………..........................................7 1.1.3 Basic Device Structure…………………………………………………………………8 1.1.3.1 Bilayer…………………………………………………...........................................8 1.1.3.2 Bulk heterojunction Structure……………………………………………………...9 1.1.4 Current Generation Process…………………………………......................................10 1.2 Material Review……………………………………………………………………………...14 1.2.1 Donor Conducting Polymer…………………………………......................................14 1.2.2 Acceptor Inorganic Nanocrystal…………………………….......................................17 1.3 Motivation……………………………………………………………………………………20 1.4 Reference……………………………………………………………………………………..22 Chapter 2 Performance Limiting Factor……………………………………………………………...24 2.1 Surface capping ligands…………………………………………............................................24 2.2 Morphology…………………………………………………………………………………..27 2.3 Summary……………………………………………………………………………………..31 2.4 Reference……………………………………………………………………………………..34 Chapter 3 Performance Improve Approach…………………………………………………………..35 3.1Morphology Control…………………………………………………………………………..36 3.1.1Interface Modification-ligand exchange/thermal anneal/solvent mixture…………………………………………………………………………………………...36 3.1.2Inorganic nanostructure engineering………….......................................................................................................49 3.2 Core shell Structure……………………………………………..............................................66 3.3 Reference………………………………………………………..............................................73 Chapter 4 Novel Material in Hybrid photovoltaics…………………………………………………..77 4.1 Graphene……………………………………………………………………………………..77 4.2 Graphene transparent Electrodes………………………..........................................................78 4.3 Graphene acceptor……………………………………………………………………………87 4.4 Graphene Oxide Hole Transport Layer………………………………………………………91 4.5 Reference……………………………………………….........................................................94 Chapter 5 Conclusion……………………………………………………………………………....97 | |
| dc.language.iso | zh-TW | |
| dc.subject | 石墨烯 | zh_TW |
| dc.subject | 有機無機混參太陽能電池 | zh_TW |
| dc.subject | 無機奈米材料電子性質 | zh_TW |
| dc.subject | 奈米結構 | zh_TW |
| dc.subject | Nanomaterial | en |
| dc.subject | Inorganic Semiconductor Material Electronic Properties | en |
| dc.subject | Organic-inorganic Solar Cell | en |
| dc.subject | Graphene | en |
| dc.title | 奈米材料在有機太陽能電池之應用回顧 | zh_TW |
| dc.title | Review on the applications of nanomaterials in polymer solar cell | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 100-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 李紹先(Shao-Sian Li),王迪彥(Di-Yan Wang) | |
| dc.subject.keyword | 有機無機混參太陽能電池,無機奈米材料電子性質,奈米結構,石墨烯, | zh_TW |
| dc.subject.keyword | Organic-inorganic Solar Cell,Inorganic Semiconductor Material Electronic Properties,Nanomaterial,Graphene, | en |
| dc.relation.page | 98 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2012-06-29 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 材料科學與工程學系 | |
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