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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 王大銘 | |
| dc.contributor.author | Yueh-Hsien Li | en |
| dc.contributor.author | 李岳憲 | zh_TW |
| dc.date.accessioned | 2021-06-07T17:52:47Z | - |
| dc.date.copyright | 2012-08-20 | |
| dc.date.issued | 2012 | |
| dc.date.submitted | 2012-08-20 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/15816 | - |
| dc.description.abstract | 本研究係利用紫外光硬化的方式，製備具有化學誘導相分離（Chemical Induced Phase Separation, CIPS）的多孔性薄膜，並探討其成膜機制。實驗中以雙酚A型樹脂Bisphenol-A-glycerolate dimethacrylate (Bis-GMA)與聚乙二醇二丙烯酸酯Poly(ethylene glycol) diacrylate (PEGDA)兩反應性單體，溶於乙醇溶劑中，進行紫外光固化成膜，硬化反應過程中，由於聚合物的分子量會隨反應時間增加，而使溶劑對聚合物高分子的溶解力下降，而引發相分離，形成多孔性高分子薄膜。
我們設計一套系統來偵測紫外光穿透高分子溶液的穿透量，利用偵測穿透量的變化，來決定相分離起始以及膠固化的時間，以及判斷相分離後孔洞成長的狀況。 研究結果顯示，隨乙醇溶劑含量增加，薄膜結構由緻密轉為多孔；並且由紫外光穿透偵測實驗結果中，我們能夠觀察得知，系統相分離起始及膠固化時間隨著溶劑含量增加而提早，其原因為反應速率差異所致。 此外，我們也發現可以利用文獻中提出的聚合反應速率表示式，進行迴歸分析，來定量地描述光起始劑濃度及單體濃度對於相分離起始與膠固化時間的影響，並且估算相對位置之熱力學三成份相圖。 同時，我們亦選用文獻中常見的DGEBA型環氧樹脂製備具化學誘導相分離薄膜，針對兩不同反應性系統作比較。結果顯示，不同於Bis-GMA/PEGDA系統，DGEBA型環氧樹脂系統能夠製備出較為規則狀的薄膜內部結構型態。其原因推測為：DGEBA/DIBK系統相較之下，其反應速率較慢，以致於它有較長的時間進行合併行為，發展出結構較為規則之圓球狀。 | zh_TW |
| dc.description.provenance | Made available in DSpace on 2021-06-07T17:52:47Z (GMT). No. of bitstreams: 1 ntu-101-R99549013-1.pdf: 3092338 bytes, checksum: 018fe11b64d2e27da6e3689e4e18ef5a (MD5) Previous issue date: 2012 | en |
| dc.description.tableofcontents | 摘要 I
Abstract III 目錄 V 圖索引 VII 表索引 XI 第一章、 緒論 1 1-1 薄膜的發展與應用 1 1-2 薄膜製備 3 1-2-1 熱誘導式相分離法（Thermal-Induced Phase Separation, TIPS） 3 1-2-2 乾式法（Solvent evaporation） 4 1-2-3 濕式法（Immersion precipitation） 4 1-2-4 蒸氣誘導式相分離法（Vapor-Induced Phase Separation, VIPS） 4 1-2-5 化學誘導相分離（Chemically-Induced Phase Separation, CIPS） 5 1-3 高分子溶液熱力學 6 1-3-1 Binodal Curve 9 1-3-2 Spinodal Curve 9 1-4 化學誘導相分離 10 1-5 光硬化型樹脂之簡介 14 1-5-1 光硬化型樹脂之起源 14 1-5-2 光硬化型樹脂之種類 15 1-5-2.1 乙烯基類樹脂 16 1-5-2.2 非乙烯基類樹脂 19 1-6 文獻回顧 24 1-7 研究動機與目的 31 第二章、 實驗 33 2-1 實驗藥品 33 2-2 實驗儀器 35 2-3 實驗方法 36 2-3-1 鑄膜液配製 36 2-3-2 薄膜之製備 36 2-4 薄膜分析方法 38 2-4-1 薄膜截面型態分析 38 2-4-2 相分離起始與膠固化時間量測 38 第三章、 結果與討論 41 3-1 自由基聚合反應系統 41 3-1-1 不同溶劑含量對薄膜結構型態之影響 41 3-1-2 相分離起始與膠固化時間之迴歸分析 45 3-1-3 相對位置熱力學相圖之估算 50 3-2 自由基聚合反應與陽離子聚合反應系統之比較 53 3-2-1 不同光起始劑含量對薄膜結構型態之影響 53 3-2-2 不同聚合系統之薄膜結構型態差異 58 第四章、 結論 63 參考文獻 65 附錄一、符號與縮寫對照表 71 附錄二、光起始劑含量對薄膜各層間結構之影響 75 | |
| dc.language.iso | zh-TW | |
| dc.title | 利用紫外光穿透偵測來探討化學誘導相分離之成膜機制 | zh_TW |
| dc.title | Investigation of the Membrane Formation Mechanism of Chemically-Induced Phase Separation by Detecting Ultraviolet Transmission | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 100-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 賴君義,李魁然,鄭國忠 | |
| dc.subject.keyword | 紫外光硬化,化學誘導相分離,多孔性薄膜,紫外光穿透偵測, | zh_TW |
| dc.subject.keyword | UV curing,chemically induced phase separation,porous membranes,light transmission, | en |
| dc.relation.page | 77 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2012-08-20 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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