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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 許富鈞(fu-chiun hsu) | |
dc.contributor.author | Wei-Yang Chiou | en |
dc.contributor.author | 邱維揚 | zh_TW |
dc.date.accessioned | 2021-05-12T09:36:56Z | - |
dc.date.available | 2021-02-14 | |
dc.date.available | 2021-05-12T09:36:56Z | - |
dc.date.copyright | 2019-02-14 | |
dc.date.issued | 2018 | |
dc.date.submitted | 2019-02-11 | |
dc.identifier.citation | 王三太、王毓華. 1995. 莧菜, p. 399-402. 刊於:洪筆鋒編著. 台灣農家要覽. 豐年社.台北. 台灣.
王英偉. 2018. 每日飲食指南. 衛生福利部國民健康署. 台北. 台灣. 行政院環境保護署. 2018. 土壤汙染管制標準. 主管法規查詢系統.< https://goo.gl/ch7GCH>. 羅秋雄. 2005. 作物施肥手冊. 中華肥料協會. 台北. 台灣 李春樹. 2003. 銅鉛鋅在土壤中之化學型態及其萃取性研究. 國立成功大學環境工程學博士論文. 台南. 李豔琪、王銀波. 1992. 銅汙染臺灣各類土壤與作物生長關係之研究. 第三屆土壤汙染防治研討會論文集. p. 309-323. 吳家誠. 2003. 台灣地區不同土綱土壤中重金屬總量檢測分析. 行政院環境保護署. 台北. 台灣 林浩潭、翁愫慎、李國欽. 2002. 食品中重金屬含量及管制標準. 行政院農業委員會農業藥物毒物試驗所. 台北. 台灣. 林棟樑. 1995. 萵苣, p. 409-412. 刊於:洪筆鋒編著. 台灣農家要覽. 豐年社. 台北. 台灣. 林獻山、張添晉. 2006. 土壤汙染與整治復育. 高立出版社. 新北. 台灣. 莊作權. 2004. 土壤肥料. 三民書局. 台北. 台灣. 許正一. 2011. 土壤重金屬知多少. 科學發展. 468:54-59 郭孚熠. 1995. 茼蒿, p. 413-414. 刊於:洪筆鋒編著. 台灣農家要覽. 豐年社. 台北. 台灣. 郭魁士. 1997. 土壤學. 之宜出版社. 台北. 台灣. 黃舒瑜. 2003. 土壤重金屬0.1N HCl萃取量與全量濃度之相關性研究. 私立逢甲大學環境工程與科學研究所碩士論文. 台中 劉政道、林麗玉. 1995. 茼蒿, p. 403-408. 刊於:洪筆鋒編著. 台灣農家要覽. 豐年社. 台北. 台灣. 歐育憲. 2000. 土壤中重金屬汙染物之生物有效性意義研究. 私立逢甲大學環境工程與科學研究所碩士論文. 台中. 衛生福利部食品藥物管理署. 2018. 食品添加物使用範圍及限量. 食品法規查詢.< https://goo.gl/BSgWao >. 賴琬婷. 2008. 以不同化學抽出法評估台灣22 種土壤重金屬生物有效性濃度及小白菜吸收量. 國立屏東科技大學環境工程與科學系碩士學位論文. 屏東. ATSDR. 2004. Agency for Toxic Substances and Disease Registry <www.atsdr.cdc.gov/toxprofiles/tp.asp?id=206&tid=37>. Adrees, M., S. Ali, M. Rizwan, M. Ibrahim, F. Abbas, M. Farid, M. Zia-ur-Rehman, M.K. Irshad, and S.A. Bharwana, 2015. The effect of excess copper on growth and physiology of important food crops: a review. Environ Sci Pollut R 22:8148-8162. Ahmad, M.S.A., M. Hussain, S. Ijaz, and A.K. Alvi, 2008. Photosynthetic performance of two mung bean (Vigna radiata) cultivars under lead and copper stress. Int. J. Agric. Biol 10:167-172. Al-hakimi, a.-b.m. and a.m. Hamada, 2011. Ascorbic acid, thiamine or salicylic acid induced changes in some physiological parameters in wheat grown under copper stress. Plant Protect Sci 47:92-108. Ali, S., M. Shahbaz, A.N. Shahzad, H.A.A. Khan, M. Anees, M.S. Haider, and A. Fatima, 2015. Impact of copper toxicity on stone-head cabbage (Brassica oleracea var. capitata) in hydroponics. PeerJ 3:e1119. Allan, D.L. and W.M. Jarrell, 1989. Proton and copper adsorption to maize and soybean root cell walls. Plant physiology 89:823-832. Alonso, M.L., J.L. Benedito, M. Miranda, C. Castillo, J. Hernandez, and R.F. Shore, 2000. The effect of pig farming on copper and zinc accumulation in cattle in Galicia (North-Western Spain). Vet J 160:259-266. Ando, Y., S. Nagata, S. Yanagisawa, and T. Yoneyama, 2013. Copper in xylem and phloem saps from rice (Oryza sativa): the effect of moderate copper concentrations in the growth medium on the accumulation of five essential metals and a speciation analysis of copper-containing compounds. Funct Plant Biol 40:89-100. Badilla-Ohlbaum, R., R. Ginocchio, P.H. Rodriguez, A. Cespedes, S. Gonzalez, H.E. Allen, and G.E. Lagos, 2001. Relationship between soil copper content and copper content of selected crop plants in central Chile. Environ Toxicol Chem 20:2749-2757. Barbosa, R.H., L.A. Tabaldi, F.R. Miyazaki, M. Pilecco, S.O. Kassab, and D. Bigaton, 2013. Foliar copper uptake by maize plants: effects on growth and yield. Ciência Rural 43:1561-1568. Baszynski, T., A. Tukendorf, M. Ruszkowska, E. Skorzynska, and W. Maksymieci, 1988. Characteristics of the photosynthetic apparatus of copper non-tolerant spinach exposed to excess copper. J Plant Physiol 132:708-713. Belimov, A., N. Hontzeas, V. Safronova, S. Demchinskaya, G. Piluzza, S. Bullitta, and B. Glick, 2005. Cadmium-tolerant plant growth-promoting bacteria associated with the roots of Indian mustard (Brassica juncea L. Czern.). Soil Biology and Biochemistry 37:241-250. Benimeli, C.S., A. Medina, C.M. Navarro, R.B. Medina, M.J. Amoroso, and M.I. Gomez, 2010. Bioaccumulation of Copper by Zea mays: Impact on Root, Shoot and Leaf Growth. Water Air Soil Poll 210:365-370. Bravin, M.N., A.L. Marti, M. Clairotte, and P. Hinsinger, 2009. Rhizosphere alkalisation - a major driver of copper bioavailability over a broad pH range in an acidic, copper-contaminated soil. Plant Soil 318:257-268. Brun, L., J. Maillet, P. Hinsinger, and M. Pepin, 2001. Evaluation of copper availability to plants in copper-contaminated vineyard soils. Environmental Pollution 111:293-302. Brun, L.A., J. Maillet, J. Richarte, P. Herrmann, and J.C. Remy, 1998. Relationships between extractable copper, soil properties and copper uptake by wild plants in vineyard soils. Environmental Pollution 102:151-161. Carr, R., C.S. Zhang, N. Moles, and M. Harder, 2008. Identification and mapping of heavy metal pollution in soils of a sports ground in Galway City, Ireland, using a portable XRF analyser and GIS. Environ Geochem Hlth 30:45-52. Chaignon, V., F. Bedin, and P. Hinsinger, 2002. Copper bioavailability and rhizosphere pH changes as affected by nitrogen supply for tomato and oilseed rape cropped on an acidic and a calcareous soil. Plant Soil 243:219-228. Chaignon, V., I. Sanchez-Neira, P. Herrmann, B. Jaillard, and P. Hinsinger, 2003. Copper bioavailability and extractability as related to chemical properties of contaminated soils from a vine-growing area. Environmental Pollution 123:229-238. Chen, Z.S., 1991. Cadmium and Lead Contamination of Soils near Plastic Stabilizing Materials Producing Plants in Northern Taiwan. Water Air Soil Poll 57-8:745-754. Chojnacka, K., A. Chojnacki, H. Gorecka, and H. Górecki, 2005. Bioavailability of heavy metals from polluted soils to plants. Science of the Total Environment 337:175-182. Cook, C.M., E. Vardaka, and T. Lanaras, 1997. Concentrations of Cu, growth and chlorophyll content of field-cultivated wheat growing in naturally enriched Cu soil. B Environ Contam Tox 58:248-253. Dresler, S., A. Hanaka, W. Bednarek, and W. Maksymiec, 2014. Accumulation of low-molecular-weight organic acids in roots and leaf segments of Zea mays plants treated with cadmium and copper. Acta Physiologiae Plantarum 36:1565-1575. Dudka, S. and W.P. Miller, 1999. Accumulation of potentially toxic elements in plants and their transfer to human food chain. J Environ Sci Heal B 34:681-708. Duinker, J., G.T.M. van Eck, and R. Nolting, 1974. On the behaviour of copper, zinc, iron and manganese, and evidence for mobilization processes in the Dutch Wadden Sea. Netherlands Journal of Sea Research. Emsley, J. and S.W.R.C.D.J. Emsley, 2001. Nature's Building Blocks: An A-Z Guide to the Elements. Oxford University Press. Ernst, W., 1996. Bioavailability of heavy metals and decontamination of soils by plants. Applied geochemistry 11:163-167. Feigl, G., D. Kumar, N. Lehotai, N. Tugyi, Á. Molnár, A. Ördög, Á. Szepesi, K. Gémes, G. Laskay, and L. Erdei, 2013. Physiological and morphological responses of the root system of Indian mustard (Brassica juncea L. Czern.) and rapeseed (Brassica napus L.) to copper stress. Ecotox Environ Safe 94:179-189. Feng, M.-H., X.-Q. Shan, S. Zhang, and B. Wen, 2005. A comparison of the rhizosphere-based method with DTPA, EDTA, CaCl2, and NaNO3 extraction methods for prediction of bioavailability of metals in soil to barley. Environmental Pollution 137:231-240. Frigge, M., D.C. Hoaglin, and B.J.T.A.S. Iglewicz, 1989. Some implementations of the boxplot. 43:50-54. Gajewska, E. and M. SkŁodowska, 2010. Differential effect of equal copper, cadmium and nickel concentration on biochemical reactions in wheat seedlings. Ecotox Environ Safe 73:996-1003. Gang, A., A. Vyas, and H. Vyas, 2013. Toxic effect of heavy metals on germination and seedling growth of wheat. Journal of Environmental Research and Development 8:206. Guan, T.X., H.B. He, X.D. Zhang, and Z. Bai, 2011. Cu fractions, mobility and bioavailability in soil-wheat system after Cu-enriched livestock manure applications. Chemosphere 82:215-222. Guo, G.L., Q.X. Zhou, P.V. Koval, and G.A. Belogolova, 2006. Speciation distribution of Cd, Pb, Cu, and Zn in contaminated Phaeozem in north-east China using single and sequential extraction procedures. Aust J Soil Res 44:135-142. Guo, H.-y., T. Liu, C. Chu, C. Chiang, and P.-F. Römkens, 2007. Prediction of heavy metal uptake by different rice species in paddy soils near contaminated sites of Taiwan. Food & Fertilizer Technology Center. Gupta, S.K. and C. Aten, 1993. Comparison and Evaluation of Extraction Media and Their Suitability in a Simple-Model to Predict the Biological Relevance of Heavy-Metal Concentrations in Contaminated Soils. International Journal of Environmental Analytical Chemistry 51:25-46. Hammer, D. and C. Keller, 2002. Changes in the rhizosphere of metal-accumulating plants evidenced by chemical extractants. Journal of Environmental Quality 31:1561-1569. Haq, A.U., T.E. Bates, and Y.K. Soon, 1980. Comparison of Extractants for Plant-Available Zinc, Cadmium, Nickel, and Copper in Contaminated Soils. Soil Sci Soc Am J 44:772-777. Hunt, R., 2012. Basic Growth Analysis: Plant growth analysis for beginners. Springer Netherlands. İşeri, Ö.D., D.A. Körpe, E. Yurtcu, F.I. Sahin, and M. Haberal, 2011. Copper-induced oxidative damage, antioxidant response and genotoxicity in Lycopersicum esculentum Mill. and Cucumis sativus L. Plant cell reports 30:1713. Jang, M., 2010. Application of portable X-ray fluorescence (pXRF) for heavy metal analysis of soils in crop fields near abandoned mine sites. Environ Geochem Hlth 32:207-216. Jung, M.C., 2008. Heavy metal concentrations in soils and factors affecting metal uptake by plants in the vicinity of a Korean Cu-W mine. Sensors-Basel 8:2413-2423. Kabata-Pendias, A., 2010. Trace elements in soils and plants. CRC press. Kidd, P., M. Dominguez-Rodriguez, J. Diez, and C. Monterroso, 2007. Bioavailability and plant accumulation of heavy metals and phosphorus in agricultural soils amended by long-term application of sewage sludge. Chemosphere 66:1458-1467. Lebourg, A., T. Sterckeman, H. Ciesielski, and N. Proix, 1998. Trace metal speciation in three unbuffered salt solutions used to assess their bioavailability in soil. Journal of Environmental Quality 27:584-590. Li, Z., D.L. Liang, Q. Peng, Z.W. Cui, J. Huang, and Z.Q. Lin, 2017. Interaction between selenium and soil organic matter and its impact on soil selenium bioavailability: A review. Geoderma 295:69-79. Lo, I.M.C. and X.Y. Yang, 1998. Removal and redistribution of metals from contaminated soils by a sequential extraction method. Waste Manage 18:1-7. Lu, L.T., I.C. Chang, T.Y. Hsiao, Y.H. Yu, and H.W. Ma, 2007. Identification of pollution source of cadmium in soil - Application of material flow analysis and a case study in Taiwan. Environ Sci Pollut R 14:49-59. Mackie, K.A., T. Muller, and E. Kandeler, 2012. Remediation of copper in vineyards - A mini review. Environmental Pollution 167:16-26. Marschner, H., 2011. Marschner's Mineral Nutrition of Higher Plants. Elsevier Science. Meers, E., G. Du Laing, V. Unamuno, A. Ruttens, J. Vangronsveld, F.M.G. Tack, and M.G. Verloo, 2007. Comparison of cadmium extractability from soils by commonly used single extraction protocols. Geoderma 141:247-259. Michaud, A.M., M.N. Bravin, M. Galleguillos, and P. Hinsinger, 2007. Copper uptake and phytotoxicity as assessed in situ for durum wheat (Triticum turgidum durum L.) cultivated in Cu-contaminated, former vineyard soils. Plant Soil 298:99-111. Novozamsky, I., T.M. Lexmond, and V.J.G. Houba, 1993. A Single Extraction Procedure of Soil for Evaluation of Uptake of Some Heavy-Metals by Plants. International Journal of Environmental Analytical Chemistry 51:47-58. Pandey, R., 2015. Mineral Nutrition of Plants, p. 499-538, Plant Biology and Biotechnology. Springer. Peijnenburg, W.J.G.M., M. Zablotskaja, and M.G. Vijver, 2007. Monitoring metals in terrestrial environments within a bioavailability framework and a focus on soil extraction. Ecotox Environ Safe 67:163-179. Pätsikkä, E., E.-M. Aro, and E. Tyystjärvi, 1998. Increase in the quantum yield of photoinhibition contributes to copper toxicity in vivo. Plant Physiology 117:619-627. Quartacci, M.F., C. Pinzino, C.L. Sgherri, F. Dalla Vecchia, and F. Navari‐Izzo, 2000. Growth in excess copper induces changes in the lipid composition and fluidity of PSII‐enriched membranes in wheat. Physiologia Plantarum 108:87-93. Rao, C.R.M., A. Sahuquillo, and J.F.L. Sanchez, 2008. A review of the different methods applied in environmental geochemistry for single and sequential extraction of trace elements in soils and related materials. Water Air Soil Poll 189:291-333. Rauret, G., J.-F. López-Sánchez, A. Sahuquillo, E. Barahona, M. Lachica, A.M. Ure, C. Davidson, A. Gomez, D. Lück, and J. Bacon, 2000. Application of a modified BCR sequential extraction (three-step) procedure for the determination of extractable trace metal contents in a sewage sludge amended soil reference material (CRM 483), complemented by a three-year stability study of acetic acid and EDTA extractable metal content. Journal of Environmental Monitoring 2:228-233. Romkens, P.F., H.Y. Guo, C.L. Chu, T.S. Liu, C.F. Chiang, and G.F. Koopmans, 2009. Characterization of soil heavy metal pools in paddy fields in Taiwan: chemical extraction and solid-solution partitioning. J Soil Sediment 9:216-228. Sancenón, V., S. Puig, I. Mateu-Andrés, E. Dorcey, D.J. Thiele, and L. Peñarrubia, 2004. The Arabidopsis copper transporter COPT1 functions in root elongation and pollen development. Journal of Biological Chemistry 279:15348-15355. Semple, K.T., K.J. Doick, K.C. Jones, P. Burauel, A. Craven, and H. Harms, 2004. Defining bioavailability and bioaccessibility of contaminated soil and sediment is complicated. Environ Sci Technol 38:228a-231a. Shahbaz, M., M.H. Tseng, C.E.E. Stuiver, A. Koralewska, F.S. Posthumus, J.H. Venema, S. Parmar, H. Schat, M.J. Hawkesford, and L.J. De Kok, 2010. Copper exposure interferes with the regulation of the uptake, distribution and metabolism of sulfate in Chinese cabbage. J Plant Physiol 167:438-446. Singh, D., K. Nath, and Y.K. Sharma, 2007. Response of wheat seed germination and seedling growth under copper stress. Journal of Environmental Biology 28:409. SUN, X., Y. LIU, and W.J.C.J.o.A.H.I. CHEN, 2010. Application of Boxplot method in the validation of abnormal value of animal health data 27:66h68. Sutherland, R.A., 2002. Comparison between non-residual Al, Co, Cu, Fe, Mn, Ni, Pb and Zn released by a three-step sequential extraction procedure and a dilute hydrochloric acid leach for soil and road deposited sediment. Applied Geochemistry 17:353-365. Taiz, L., E. Zeiger, I. Moller, and A. Murphy, 2015. Plant Physiology and development 6th edition. Sinauer Assoc. Takeda, A., H. Tsukada, Y. Takaku, S. Hisamatsu, J. Inaba, and M. Nanzyo, 2006. Extractability of major and trace elements from agricultural soils using chemical extraction methods: Application for phytoavailability assessment. Soil Sci Plant Nutr 52:406-417. Taylor, R., I. Ibeabuchi, K. Sistani, and J. Shuford, 1993. Heavy metal concentration in forage grasses and extractability from some acid mine spoils. Water, Air, and Soil Pollution 68:363-372. Tipping, E., J. Rieuwerts, G. Pan, M. Ashmore, S. Lofts, M. Hill, M. Farago, and I. Thornton, 2003. The solid–solution partitioning of heavy metals (Cu, Zn, Cd, Pb) in upland soils of England and Wales. Environmental pollution 125:213-225. Turgut, C., M.K. Pepe, and T.J. Cutright, 2004. The effect of EDTA and citric acid on phytoremediation of Cd, Cr, and Ni from soil using Helianthus annuus. Environmental pollution 131:147-154. Van der Ent, A., A.J. Baker, R.D. Reeves, A.J. Pollard, H.J.P. Schat, and Soil, 2013. Hyperaccumulators of metal and metalloid trace elements: facts and fiction. 362:319-334. Verma, J.P., V. Singh, and J. Yadav, 2011. Effect of copper sulphate on seed germination, plant growth and peroxidase activity of Mung bean (Vigna radiata). Int. J. Bot 7:200-204. Wang, C., P.r. Guo, H.t. Chen, and Y.h. Shu, 2009. Evaluation of Bioavailability of Heavy Metals in Soils and Sediments. Rock and Mineral Analysis 2:008. Wang, C.H., Y.I. Lee, B.C. Chen, and K.W. Juang, 2011. Effects of Excess Copper on Plant Growth and Copper Concentration of Grapevine Cuttings. Taiwanese Journal of Agricultural Chemistry and Food Science 49:141-151. Wang, Q.Y., J.S. Liu, Y. Wang, and H.W. Yu, 2015. Accumulations of copper in apple orchard soils: distribution and availability in soil aggregate fractions. J Soil Sediment 15:1075-1082. Wei, B.G. and L.S. Yang, 2010. A review of heavy metal contaminations in urban soils, urban road dusts and agricultural soils from China. Microchem J 94:99-107. Wu, C.F., Y.M. Luo, and L.M. Zhang, 2010. Variability of copper availability in paddy fields in relation to selected soil properties in southeast China. Geoderma 156:200-206. Xiong, Z.-T., 1998. Lead uptake and effects on seed germination and plant growth in a Pb hyperaccumulator Brassica pekinensis Rupr. B Environ Contam Tox 60:285-291. Xu, J., L. Yang, Z. Wang, G. Dong, J. Huang, and Y. Wang, 2006. Toxicity of copper on rice growth and accumulation of copper in rice grain in copper contaminated soil. Chemosphere 62:602-607. Yruela, I., 2005. Copper in plants. Brazilian Journal of Plant Physiology 17:145-156. Zhang, M.-K., Z.Y. Liu, and H. Wang, 2010. Use of single extraction methods to predict bioavailability of heavy metals in polluted soils to rice. Communications in Soil Science and Plant Analysis 41:820-831. Zhao, X.P., Y. Jiang, X.Y. Gu, C. Gu, J.A. Taylor, and L.J. Evans, 2018. Multisurface modeling of Ni bioavailability to wheat (Triticum aestivum L.) in various soils. Environ Pollut 238:590-598. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/handle/123456789/1349 | - |
dc.description.abstract | 臺灣農地銅汙染案件數量多,可能造成作物食用安全問題。藉由調查於銅汙染土壤栽培之作物其生長及銅累積,可評估農產品的食用安全性,另外建立植體銅濃度預估模型則可達到預警的效果。本研究將台灣重要的四種食用蔬菜,蕹菜(Ipomoea aquatic F.)、白莧(Amaranthus inamoenus W.)、小白菜(Brassica rapa L. ssp. chinensis)及茼蒿(Chrysanthemum coronarium L.)種植於人工銅汙染之土壤中,調查各項生長指標以觀察作物受銅之危害,並量測植體銅濃度來評估作物食用安全性。
食用安全評估的試驗結果,在12-518 mg·kg-1的土壤銅濃度生長下的蕹菜、白莧、小白菜及茼蒿,外表型態、株高及鮮重會隨著土壤銅濃度的增加而下降,植體銅濃度則會隨之上升,以409-518 mg·kg-1的土壤銅濃度處理下有最高的植體銅濃度結果。小白菜在四種作物中有最高植體銅濃度為122 mg·kg-1,經過計算超過銅的每日建議攝取濃度,但由於生長被嚴重抑制,因此流入市面對人體的食用安全威脅較低。 植體銅濃度預估模型的建立依據,是各項的生物有效性因子(bioavailability),除了蒐集上述四種蔬菜於人工銅汙染土壤試驗中所記錄的資料外,也為臺灣重要糧食作物-水稻(Oryza sativa L.)的田間資料來建立預估模型。 套用已建立的植體銅濃度預估模型的公式計算,得到的植體銅濃度推估值,與實際值以迴歸驗證,得知蕹菜、白莧、小白菜及茼蒿最高的R2值分別為0.8319、0.8473、0.6340及0.7617,皆有高的植體銅濃度預估能力。當水稻銅濃度預估模型的土壤銅全量,以王水消化及X-ray Fluorescence Spectrometer(XRF)分析時,最高的R2值分別為0.2855和0.2981,兩者預估能力相近,因此未來可以選擇檢測需時較少的XRF作為分析方法。 | zh_TW |
dc.description.abstract | Large number of copper pollution cases in Taiwan's agricultural land may cause crop food safety problems. By investigating the growth and copper accumulation of crops grown in copper contaminated soils, the food safety of agricultural products can be assessed, and the early warning effect can be achieved by establishing a model for estimating the plant copper concentration. In this study, four important edible vegetables in Taiwan, including water spinach(Ipomoea aquatic F.), amaranth(Amaranthus inamoenus W.), pakchoi(Brassica rapa L. ssp. chinensis)and garland chrysanthemum(Chrysanthemum coronarium L.), were planted in artificial copper contaminated soil. Various growth indicators were utilized to evaluate the damage of crops to copper, and the plants copper concentration was measured to assess crop food safety.
The results of the food safety assessment of the four vegetables showed that the growth in plant height and fresh weight of the crops grown in the soil containing 12 to 518 mg·kg-1 decreased with the increase of soil copper concentration, while the plant copper concentration increased. The highest concentration of copper in the plant was obtained by the soil containing 409 to 518 mg·kg-1. Among the four crops, pakchoi had the highest copper concentration of plant in 122 mg·kg-1 , which was calculated to exceed the daily recommended intake of humans in copper, but it was less likely to enter the market due to severe suppression of growth. The prediction model of the plant copper concentration is based on the bioavailability factors. In addition to collecting the data recorded in the artificial copper contaminated soil test of the above four crops, the field data was also used to establish a prediction model for a Taiwan's important food crop, rice (Oryza sativa L.). Based on the formula of the established copper concentration prediction model, regression analysis of the estimated and actual value of copper concentration in plants. The estimated copper concentration of the plant was calculated by the formula of the established copper concentration prediction model, and then the estimated and actual values of the plant were analyzed by regression. The highest R2 values of water spinach, amaranth, pakchoi and garland chrysanthemum were 0.8319, 0.8473, 0.6340 and 0.7617, respectively, all of which had high ability to predict copper concentration in the plant. In the part of the rice copper concentration prediction model, the total amount of soil copper was analyzed by aqua regia digestion and X-ray Fluorescence Spectrometer (XRF), and the highest R2 values were 0.2855 and 0.2981, respectively. Because estimates using two methods are similar, the efficient and nondistructive detection approach using XRF is recommended. | en |
dc.description.provenance | Made available in DSpace on 2021-05-12T09:36:56Z (GMT). No. of bitstreams: 1 ntu-107-R05628129-1.pdf: 2394090 bytes, checksum: 24d5553ac5428d8484f1604275c9f9ee (MD5) Previous issue date: 2018 | en |
dc.description.tableofcontents | 誌謝 I
中文摘要 II Abstract III 目錄 V 圖目錄 VII 表目錄 VIII 第一章、前言 1 第二章、作物食用安全性 4 第一節 前人研究 4 一、銅在土壤中的來源 4 二、銅在土壤中的特性與生物有效性 4 三、植物銅的吸收、運移及累積 6 四、銅對植物生長的影響 7 第二節 材料與方法 8 一、試驗土壤 8 二、土壤理化性質分析 8 (一) 土壤粒徑分析 8 (二) 有機質含量 9 (三) pH值 9 (四) 陽離子交換容量 9 (五) 土壤銅全量分析 10 (六) 品保品管 10 三、土壤人工添加銅處理 10 (一) 硫酸銅溶液添加量 10 (二) 添加方法 12 四、盆栽試驗 12 (一) 作物選擇 12 (二) 土壤施肥 12 (三) 栽培 12 (四) 紀錄 13 (五) 植體前處理 13 (六) 植體銅濃度分析 13 (七) 品保品管 13 (八) 統計分析 13 第三節 結果與討論 14 一、土壤理化性質 14 二、人工添加硫酸銅溶液之土壤銅濃度在四次盆栽試驗後無明顯差異 14 三、四種作物之生長指標隨著銅處理濃度的增加而下降 18 (一) 外表型態 18 (二) 株高 23 (三) 鮮重 28 四、植體銅濃度隨著土壤處理銅濃度的增加而上升 34 (一) 蕹菜及白莧 34 (二) 小白菜及茼蒿 34 五、土壤銅汙染未造成四種作物之植體銅濃度超出食用安全性 34 (一) 蔬菜銅含量規範 34 (二) 蕹菜、白莧、小白菜及茼蒿之食用安全性 39 第三章、植體銅濃度預估模型的建立 41 第一節、前人研究 41 單一萃取法 41 (一)交換性試劑 43 (二)酸性試劑 43 (三)有機螯合劑 45 第二節 材料與方法 45 一、試驗土壤 45 二、土壤理化性質分析 45 三、土壤銅全量測量(X射線螢光光譜儀) 45 四、植體銅濃度分析 46 五、土壤生物有效性銅濃度測定 46 (一)EDTA 0.05 M萃取法 46 (二)HCl 0.1 M萃取法 46 (三)NaNO3 0.1 M萃取法 46 (四)CaCl2 0.01 M萃取法 47 六、植體銅濃度預估模型之建立 47 第三節 結果與討論 47 一、供試土壤的基本理化性質皆相似 47 二、土壤銅全量以XRF測量之數據,與王水消化法相關性高 48 三、現地試驗之土壤與植體銅濃度的相關性不高 48 四、銅可被EDTA及HCl有效萃取,與銅在土壤的結合型態有關 55 五、植體銅濃度預估模型中,以盆栽試驗的模型預測性較佳 65 (一)蕹菜 65 (二)白莧 65 (三)小白菜 73 (四)茼蒿 83 (五)水稻(土壤銅全量以王水消化法測量) 83 (六)水稻(土壤銅全量以XRF測量) 90 第四章、結論 100 第五章、參考文獻 101 附錄 107 | |
dc.language.iso | zh-TW | |
dc.title | 預估作物於銅汙染土壤生長之植體銅含量 | zh_TW |
dc.title | Estimation of Copper Content in Crops Cultivated in Copper Contaminated Soil | en |
dc.type | Thesis | |
dc.date.schoolyear | 107-1 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 林淑怡(Shu-I Lin),范致豪 | |
dc.subject.keyword | 生物有效性,單一化學萃取法,蕹菜,白莧,小白菜,茼蒿, | zh_TW |
dc.subject.keyword | bioavailability,single chemical extraction,water spinach,amaranth,pakchoi,garland chrysanthemum, | en |
dc.relation.page | 110 | |
dc.identifier.doi | 10.6342/NTU201900391 | |
dc.rights.note | 同意授權(全球公開) | |
dc.date.accepted | 2019-02-12 | |
dc.contributor.author-college | 生物資源暨農學院 | zh_TW |
dc.contributor.author-dept | 園藝暨景觀學系 | zh_TW |
顯示於系所單位: | 園藝暨景觀學系 |
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