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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 顏溪成(Shi-Chern Yen) | |
dc.contributor.author | Yu-Chieh Huang | en |
dc.contributor.author | 黃昱傑 | zh_TW |
dc.date.accessioned | 2021-05-12T09:34:20Z | - |
dc.date.available | 2019-07-06 | |
dc.date.available | 2021-05-12T09:34:20Z | - |
dc.date.copyright | 2018-07-06 | |
dc.date.issued | 2018 | |
dc.date.submitted | 2018-07-02 | |
dc.identifier.citation | 1. 陳國帝, 白明德, 韓忠正, 吳劭易, 盧智芬, 楊慧筠, 盧文章, and 萬皓鵬, 微生物燃料電池技術處理應用於廢水廢棄物處理與能源化. Journal of Solar and New Energy, 2016. 18: p. 3-9.
2. Gude, V.G., Energy and Water Autarky of Wastewater Treatment and Power Generation Systems. Renewable and Sustainable Energy Reviews, 2015. 45: p. 52-68. 3. Shizas, I., and D.M. Bagley, Experimental Determination of Energy Content of Unknown Organics in Municipal Wastewater Streams. J. Energy engin., 2004. 130: p. 45-53. 4. Zhang, Q., J. Hu, and D.J. Lee, Microbial Fuel Cells as Pollutant Treatment Units: Research Updates. Bioresour Technol, 2016. 217: p. 121-128. 5. Fan, Y., E. Sharbrough, and H. Liu, Quantification of the Internal Resistance Distribution of Microbial Fuel Cells. Environ Sci Technol, 2008. 42: p. 8101-8107. 6. Potter, M.C., Electrical Effects Accompanying the Decomposition of Organic Compounds. Royal Society, 1911. 84: p. 260-276. 7. Chong, S., T.K. Sen, A. Kayaalp, and H.M. Ang, The Performance Enhancements of Upflow Anaerobic Sludge Blanket (Uasb) Reactors for Domestic Sludge Treatment--a State-of-the-Art Review. Water Res, 2012. 46(11): p. 3434-3470. 8. Bennetto, H.P., M.E. Dew, and J.L. Stirling, Rates of Reduction of Phenothiazine `Redox' Dyes by E. Coli. Chem. Ind, 1981. 7: p. 776-778. 9. Park, D.H., M. Laivenieks, M.V. Guettler, M.K. Jain, and J.G. Zeikus, Microbial Utilization of Electrically Reduced Neutral Red as the Sole Electron Donor for Growth and Metabolite Production. Appl Environ Microbiol, 1999. 65: p. 2912-2917. 10. Schröder, U., J. Nießen, and F. Scholz, A Generation of Microbial Fuel Cells with Current Outputs Boosted by More Than One Order of Magnitude. Angewandte Chemie International Edition, 2003. 42(25): p. 2880-2883. 11. Park, D.H., and J.G. Zeikus, Electricity Generation in Microbial Fuel Cells Using Neutral Red as an Electronophore. Appl Environ Microbiol, 2000. 66: p. 1292-1297. 12. Bond, D.R., D.E. Holmes, L.M. Tender, and D.R. Lovley, Electrode-Reducing Microorganisms That Harvest Energy from Marine Sediments. Science, 2002. 295(5554): p. 483-485. 13. Li, D., Surface Effects of Monolayer-Protected Gold Nanoparticles on the Redox Reactions between Ferricyanide and Thiosulfate. Science in China Series B, 2005. 48(5): p. 424. 14. Rabaey, K., and W. Verstraete, Microbial Fuel Cells: Novel Biotechnology for Energy Generation. Trends Biotechnol, 2005. 23(6): p. 291-298. 15. Grzebyk, M., and G. Poźniak, Microbial Fuel Cells (Mfcs) with Interpolymer Cation Exchange Membranes. Separation and Purification Technology, 2005. 41(3): p. 321-328. 16. Mohan, Y., S. Manojmuthukumar, and D. Das, Electricity Generation Using Microbial Fuel Cells. International Journal of Hydrogen Energy, 2008. 33(1): p. 423-426. 17. Liu, X., M. Hao, M. Feng, L. Zhang, Y. Zhao, X. Du, and G. Wang, A One-Compartment Direct Glucose Alkaline Fuel Cell with Methyl Viologen as Electron Mediator. Applied Energy, 2013. 106: p. 176-183. 18. Kim, B.H., D.H. Park, P.K. Shin, I.S. Chang, and H.J. KIM, Mediator-Less Biofuel Cell. Patent 5976719, 1999. 19. Rabaey, K., N. 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Guiot, A Comparison of Air and Hydrogen Peroxide Oxygenated Microbial Fuel Cell Reactors. Biotechnol. Prog, 2006. 22: p. 241-246. 29. Oh, S.E., and B.E. Logan, Proton Exchange Membrane and Electrode Surface Areas as Factors That Affect Power Generation in Microbial Fuel Cells. Appl Microbiol Biotechnol, 2006. 70(2): p. 162-169. 30. Santoro, C., A.G. Agrios, B. Li, and P. Cristiani, The Correlation of the Anodic and Cathodic Open Circuit Potential (Ocp) and Power Generation in Microbial Fuel Cells (Mfcs). 2012: p. 45-53. 31. Logan, B.E., H.V. Hamelers, R. Rozendal, U. Schroder, J. Keller, S. FRreguia, W. Verstraete, P. Aelterman, S. FRreguia, and K. Rabaey, Microbial Fuel Cells: Methodology and Technology. Environ Sci Technol, 2006. 40: p. 5181-5192. 32. Min, B., and B.E. Logan, Continuous Electricity Generation from Domestic Wastewater and Organic Substrates in a Flat Plate Microbial Fuel Cell. environ Sci Technol, 2004. 38: p. 5809-5814. 33. Logan, B.E., S. Cheng, V. Watson, and G. Estadt, Graphite Fiber Brush Anodes for Increased Power Production in Air-Cathode Microbial Fuel Cells. environ Sci Technol, 2007. 41: p. 3341-3346. 34. KIM, H.J., H.S. Park, M.S. Hyun, I.S. Chang, M. Kim, and B.H. Kim, A Mediator-Less Microbial Fuel Cell Using a Metal Reducing Bacterium, Shewanella Putrefaciens. Enzyme and Microbial Technology, 2002. 30: p. 145-152. 35. Chaudhuri, S.K., and D.R. Lovley, Electricity Generation by Direct Oxidation of Glucose in Mediatorless Microbial Fuel Cells. Nat Biotechnol, 2003. 21(10): p. 1229-1232. 36. Bond, D.R., and D.R. Lovley, Electricity Production by Geobacter Sulfurreducens Attached to Electrodes. Applied and Environmental Microbiology, 2003. 69(3): p. 1548-1555. 37. Liu, Y., F. Harnisch, K. Fricke, U. Schroder, V. Climent, and J.M. Feliu, The Study of Electrochemically Active Microbial Biofilms on Different Carbon-Based Anode Materials in Microbial Fuel Cells. Biosens Bioelectron, 2010. 25(9): p. 2167-2171. 38. Gorby, Y., and T.J. Beveridge, Composition, Reactivity, and Regulation of Composition, Reactivity, and Regulation of Extracellular Extracellular Metal-Reducing Structures Metal-Reducing Structures (Nanowires) Produced by (Nanowires) Produced by Dissimilatory Dissimilatory Metal Reducing Bacteria Reducing Bacteria. Warrenton VA, 2005. 39. Reguera, G., K.D. McCarthy, T. Mehta, J.S. Nicoll, M.T. Tuominen, and D.R. Lovley, Extracellular Electron Transfer Via Microbial Nanowires. Nature, 2005. 435(7045): p. 1098-1101. 40. Lv, Z., D. Xie, X. Yue, C. Feng, and C. Wei, Ruthenium Oxide-Coated Carbon Felt Electrode: A Highly Active Anode for Microbial Fuel Cell Applications. Journal of Power Sources, 2012. 210: p. 26-31. 41. Varanasi, J.L., A.K. Nayak, Y. Sohn, D. Pradhan, and D. Das, Improvement of Power Generation of Microbial Fuel Cell by Integrating Tungsten Oxide Electrocatalyst with Pure or Mixed Culture Biocatalysts. Electrochimica Acta, 2016. 199: p. 154-163. 42. Pandey, P., V.N. Shinde, R.L. Deopurkar, S.P. Kale, S.A. Patil, and D. Pant, Recent Advances in the Use of Different Substrates in Microbial Fuel Cells toward Wastewater Treatment and Simultaneous Energy Recovery. Applied Energy, 2016. 168: p. 706-723. 43. ElMekawy, A., S. Srikanth, S. Bajracharya, H.M. Hegab, P.S. Nigam, A. Singh, S.V. Mohan, and D. Pant, Food and Agricultural Wastes as Substrates for Bioelectrochemical System (Bes): The Synchronized Recovery of Sustainable Energy and Waste Treatment. Food Research International, 2015. 73: p. 213-225. 44. Liu, H., S. Cheng, and B.E. Logan, Production of Electricity from Acetate or Butyrate Using a Single-Chamber Microbial Fuel Cell. Environ Sci Technol, 2005. 39: p. 658-662. 45. Oliveira, V.B., M. Simões, L.F. Melo, and A.M.F.R. Pinto, Overview on the Developments of Microbial Fuel Cells. Biochemical Engineering Journal, 2013. 73: p. 53-64. 46. Liu, H., S. Cheng, and B.E. Logan, Power Generation in Fed-Batch Microbial Fuel Cells as a Function of Ionic Strength, Temperature, and Reactor Configuration. Environ Sci Technol, 2005. 39: p. 5488-5493. 47. Martin, E., O. Savadogo, S.R. Guiot, and B. Tartakovsky, The Influence of Operational Conditions on the Performance of a Microbial Fuel Cell Seeded with Mesophilic Anaerobic Sludge. Biochemical Engineering Journal, 2010. 51(3): p. 132-139. 48. Rismani-Yazdi, H., S.M. Carver, A.D. Christy, and O.H. Tuovinen, Cathodic Limitations in Microbial Fuel Cells: An Overview. Journal of Power Sources, 2008. 180(2): p. 683-694. 49. Dumas, C., A. Mollica, D. Féron, R. Basséguy, L. Etcheverry, and A. Bergel, Marine Microbial Fuel Cell: Use of Stainless Steel Electrodes as Anode and Cathode Materials. Electrochimica Acta, 2007. 53(2): p. 468-473. 50. Fraiwan, A., S.P. Adusumilli, D. Han, A.J. Steckl, D.F. Call, C.R. Westgate, and S. Choi, Microbial Power-Generating Capabilities on Micro-/Nano-Structured Anodes in Micro-Sized Microbial Fuel Cells. Fuel Cells, 2014. 14(6): p. 801-809. 51. Hou, J., Z. Liu, S. Yang, and Y. Zhou, Three-Dimensional Macroporous Anodes Based on Stainless Steel Fiber Felt for High-Performance Microbial Fuel Cells. Journal of Power Sources, 2014. 258: p. 204-209. 52. Ren, H., S. Pyo, J.-I. Lee, T.-J. Park, F.S. Gittleson, F.C.C. Leung, J. Kim, A.D. Taylor, H.-S. Lee, and J. Chae, A High Power Density Miniaturized Microbial Fuel Cell Having Carbon Nanotube Anodes. Journal of Power Sources, 2015. 273: p. 823-830. 53. Sonawane, J.M., A. Yadav, P.C. Ghosh, and S.B. Adeloju, Recent Advances in the Development and Utilization of Modern Anode Materials for High Performance Microbial Fuel Cells. Biosens Bioelectron, 2017. 90: p. 558-576. 54. Chen, S., G. He, X. Hu, M. Xie, S. Wang, D. Zeng, H. Hou, and U. Schroder, A Three-Dimensionally Ordered Macroporous Carbon Derived from a Natural Resource as Anode for Microbial Bioelectrochemical Systems. ChemSusChem, 2012. 5(6): p. 1059-1063. 55. Zhang, J., J. Li, D. Ye, X. Zhu, Q. Liao, and B. Zhang, Tubular Bamboo Charcoal for Anode in Microbial Fuel Cells. Journal of Power Sources, 2014. 272: p. 277-282. 56. Zhang, Y., G. Mo, X. Li, W. Zhang, J. Zhang, J. Ye, X. Huang, and C. Yu, A Graphene Modified Anode to Improve the Performance of Microbial Fuel Cells. Journal of Power Sources, 2011. 196(13): p. 5402-5407. 57. Zhang, C., P. Liang, X. Yang, Y. Jiang, Y. Bian, C. Chen, X. Zhang, and X. Huang, Binder-Free Graphene and Manganese Oxide Coated Carbon Felt Anode for High-Performance Microbial Fuel Cell. Biosens Bioelectron, 2016. 81: p. 32-38. 58. Yuan, H., L. Deng, Y. Chen, and Y. Yuan, Mno2/Polypyrrole/Mno2 Multi-Walled-Nanotube-Modified Anode for High-Performance Microbial Fuel Cells. Electrochimica Acta, 2016. 196: p. 280-285. 59. Peng, X., H. Yu, X. Wang, Q. Zhou, S. Zhang, L. Geng, J. Sun, and Z. Cai, Enhanced Performance and Capacitance Behavior of Anode by Rolling Fe3o4 into Activated Carbon in Microbial Fuel Cells. Bioresour Technol, 2012. 121: p. 450-453. 60. Rosenbaum, M., F. Zhao, U. Schröder, and F. Scholz, Interfacing Electrocatalysis and Biocatalysis with Tungsten Carbide: A High-Performance, Noble-Metal-Free Microbial Fuel Cell. Angewandte Chemie, 2006. 118(40): p. 6810-6813. 61. Wang, Y., B. Li, L. Zeng, D. Cui, X. Xiang, and W. Li, Polyaniline/Mesoporous Tungsten Trioxide Composite as Anode Electrocatalyst for High-Performance Microbial Fuel Cells. Biosens Bioelectron, 2013. 41: p. 582-588. 62. Qiao, Y., S.J. Bao, C.M. Li, X.Q. Cui, Z.S. Lu, and J. Guo, Nanostructured Polyaniline/Titanium Dioxide Composite Anode for Microbial Fuel Cells. ACS Nano, 2008. 2(1): p. 113-119. 63. Li, C., L. Zhang, L. Ding, H. Ren, and H. Cui, Effect of Conductive Polymers Coated Anode on the Performance of Microbial Fuel Cells (Mfcs) and Its Biodiversity Analysis. Biosens Bioelectron, 2011. 26(10): p. 4169-4176. 64. Yang, L., W. Deng, Y. Zhang, Y. Tan, M. Ma, and Q. Xie, Boosting Current Generation in Microbial Fuel Cells by an Order of Magnitude by Coating an Ionic Liquid Polymer on Carbon Anodes. Biosens Bioelectron, 2017. 91: p. 644-649. 65. Wang, X., N. Gao, Q. Zhou, H. Dong, H. Yu, and Y. Feng, Acidic and Alkaline Pretreatments of Activated Carbon and Their Effects on the Performance of Air-Cathodes in Microbial Fuel Cells. Bioresour Technol, 2013. 144: p. 632-636. 66. Zhu, N., X. Chen, T. Zhang, P. Wu, P. Li, and J. Wu, Improved Performance of Membrane Free Single-Chamber Air-Cathode Microbial Fuel Cells with Nitric Acid and Ethylenediamine Surface Modified Activated Carbon Fiber Felt Anodes. Bioresour Technol, 2011. 102(1): p. 422-426. 67. Saito, T., M. Mehanna, X. Wang, R.D. Cusick, Y. 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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/handle/123456789/1212 | - |
dc.description.abstract | 生物燃料電池是利用微生物分解廢水中的有機物產生電力,目前的生物燃料電池受限於低功率密度與高成本,為了改善此問題,本研究使用石墨氈為陽極材料,針對石墨氈基材進行表面改質,並探討石墨氈在生物燃料電池中的電性表現。本研究以陽極材料作為研究對象,使用稻田底泥的厭氧產電菌作為母菌,石墨氈做為陽極材料,以無膜式空氣陰極裝置操作生物燃料電池。石墨氈分別以硝酸與硫酸進行表面改質,並嘗試加熱改變石墨氈的表面官能基,藉此改善石墨氈的親水性與生物親和性,並觀察陽極材料表面改質對於生物燃料電池的電性表現影響。以水滴定實驗測得石墨氈經過泡硝酸並加熱130℃後的親水性改善最佳,在循環伏安法中觀察到活化面積比未經表面改質的石墨氈增加超過30倍。生物燃料電池操作中,泡硝酸並加熱的石墨氈達到2253 mW/m2的功率密度,比未改質的石墨氈高出111%(1070 mW/m2),電池的內阻也降低了45%。不論有無經過表面改質,電池的庫倫效率都維持在50%以上,且在進行40天的電池操作,電池的電壓輸出也相當穩定。在增加了陰極面積與縮短電極距離後,降低了活化過電位,使得生物燃料電池的最高功率密度達到3413 mW/m2。在本研究中成功使用簡易且低成本的製程改善了石墨氈的親水性與生物親和性,並成功達到擁有高功率、高庫倫效率與高穩定性的生物燃料電池。 | zh_TW |
dc.description.abstract | Microbial fuel cell (MFC) is a kind of fuel cells that convert chemical energy into electric energy. It inoculates exoelectrogenic bacteria attached to the anode as a catalyst and degrades organic matter by electrode reaction. Bacteria transfers electrons to the surface of anode, and electrons flow to the cathode through the external circuits. On the other hand, oxygen is reduced electrochemically at cathode and water is produced. The overall reaction involves organic matter and oxygen, chemical energy is converted into electric energy, in which water and carbon dioxide are produced. In this work, graphite felts serve as anode which provide high specific surface area for bacteria to attach. Graphite felts were employed to nitric acid treatment (AT-N) and combination of nitric acid and heat treatment (AT-NH) to improve hydrophilicity. Linear Sweep Voltammetry and cyclic voltammetry analyses indicated AT-NH graphite felts provided the best electrochemical performance in this work. Maximum power density of microbial fuel cell equipped with AT-NH graphite felts was 2253 mW/m2 which was 111% and 21% higher than unmodified graphite felts and AT-N graphite felts, respectively. The internal resistance of microbial fuel cell equipping with AT-NH was reduced dramatically and AT-NH graphite felts contributed less than 16.5% of the internal resistance. By reducing the electrode distance and increasing the cathode area, maximum power density of MFC was increased to 3413 mW/m2. This work demonstrates a simple way to fabricate hydrophilic graphite felts and improve power generation of MFC. | en |
dc.description.provenance | Made available in DSpace on 2021-05-12T09:34:20Z (GMT). No. of bitstreams: 1 ntu-107-R05524035-1.pdf: 5326655 bytes, checksum: af985df4dea700b50bb0ae2404efdf43 (MD5) Previous issue date: 2018 | en |
dc.description.tableofcontents | 中文摘要 i
英文摘要 ii 圖目錄 v 表目錄 viii 第一章 緒論 1 1.1 研究動機 1 1.2 生物燃料電池簡介 4 第二章 文獻回顧 7 2.1 生物燃料電池工作原理 7 2.2 生物燃料電池結構 10 2.2.1生物燃料電池系統 10 2.2.2微生物 13 2.2.3陽極材料 17 2.2.4陰極材料 19 2.3 微生物功率動力學 20 第三章 生物燃料電池之性能分析 24 3.1 極化現象 24 3.2 電池性能測定 26 3.2.1內阻分析 26 3.2.2庫倫效率 27 第四章 研究方法 28 4.1 實驗藥品與器材 28 4.2 實驗器材與設備 29 4.3 電池製備 30 4.3.1微生物母菌培養 30 4.3.2陽極材料製備 30 4.3.3電解液製備 32 4.3.4特性分析 33 4.4 分析方法 35 4.4.1材料分析 35 4.4.2電化學分析 36 第五章 結果與討論 37 5.1 陽極材料分析 37 5.1.1表面接觸角量測 37 5.1.2表面元素分析 40 5.1.3循環伏安法測試 43 5.1.4線性掃描伏安法 44 5.1.5交流阻抗分析 45 5.2 生物燃料電池測試 48 5.2.1極化曲線 48 5.2.2庫倫效率 54 5.2.3電池穩定性 55 5.2.4 陰極面積與電極距離的影響 56 5.3 生物陽極材料分析 60 -5.3.1微生物附著樣貌 60 5.3.2生物陽極循環伏安法測試 63 第六章 結論 65 參考文獻 66 | |
dc.language.iso | zh-TW | |
dc.title | 生物燃料電池石墨氈陽極材料改質與特性分析 | zh_TW |
dc.title | Acid and heat treatment of graphite felt for improving performance of single-chamber air-cathode microbial fuel cells | en |
dc.type | Thesis | |
dc.date.schoolyear | 106-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 周偉龍(Wei-Lung Chou),吳永富(Yong-Fu Wu),蔡子萱(Tzu-Hsuan Tsai) | |
dc.subject.keyword | 生物燃料電池,陽極,石墨氈,表面改質,親水性, | zh_TW |
dc.subject.keyword | Microbial fuel cell,Anode,Graphite felt,Modification,Hydrophilic, | en |
dc.relation.page | 72 | |
dc.identifier.doi | 10.6342/NTU201801187 | |
dc.rights.note | 同意授權(全球公開) | |
dc.date.accepted | 2018-07-02 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
文件中的檔案:
檔案 | 大小 | 格式 | |
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ntu-107-1.pdf | 5.2 MB | Adobe PDF | 檢視/開啟 |
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