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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 林金福(King-Fu Lin) | |
dc.contributor.author | Chih-Yang Ko | en |
dc.contributor.author | 柯志揚 | zh_TW |
dc.date.accessioned | 2021-05-20T21:33:41Z | - |
dc.date.available | 2011-08-18 | |
dc.date.available | 2021-05-20T21:33:41Z | - |
dc.date.copyright | 2010-08-18 | |
dc.date.issued | 2010 | |
dc.date.submitted | 2010-08-17 | |
dc.identifier.citation | 1. D. M. Chapin, C. S. Fuller, and G. L. Pearson, J. Appl. Phys. 25, 676 (1954)
2. B. O’Regan, M. Grätzel, Nature 353, 737 (1991) 3.L. Han, N. Koide, Y. Chiba, and T. Mitate, Appl. Phys. Lett. 84, 2433 (2004) 4. H. Gerischer, H. Tributsch, Ber. Bunsenges. Phys. Chem. 72, 437 (1968) 5. H. Tsubomura, M. Matsumura, Y. Nomura, and T. Amamiya, Nature 261, 402 (1976) 6. M. Grätzel, Nature 414, 338 (2001) 7. R. Y. Ogura, S. Nakane, M. Morooka, M. Orihashi, Y. Suzuki, and K. Noda, Applied Physics Letters 94, 073308 (2009) 8. Y. Saito, A. Ogawa, S. Uchida, T. Kubo, and H. Segawa, Chem. Lett. 39, 488489 (2010) 9. M. K. Nazeeruddin, R. Humphery-Baker, P. Liska, and M. Grätzel, J. Phys. Chem. B 107, 8981 (2003) 10.S. Y. Huang, G. Schlichthörl, A. J. Nozik, M. Grätzel, and A. J. Frank, J. Phys. Chem. B 101, 2576 (1997) 11. M. Grätzel, K. Kalyanasundaram, Curr. Sci. 66, 706 (1994) 12. R. Katoh, M. Kasuya, S. Kodate, A. Furube, N. Fuke, and N. Koide, J. Phys. Chem. C 113, 20738 (2009) 13.P. Pechy, F. P. Rotzinger, M. K. Nazeeruddin, O. Kohle, S. M. Zakeeruddin, R. Humphry-Baker, and M. Grätzel, J. Chem. Soc., Chem. Commun. 65 (1995) 14.O. Taratula, E. Galoppini, D. Chu, Z. Zhang, H. Chen, G. Saraf, and Y. Lu, J. Phys. Chem. B 110, 6506 (2006) 15.C. Klein, M. K. Nazeeruddin, D. D. Censo, P. Liska, and M. Grätzel, Inorg. Chem. 43, 4216 (2004) 16.H. Seo, M. K. Son, I. Shin, J. K. Kim, K. J. Lee, K. Prabakar, and H. J. Kim, Electrochimica Acta 55, 4120 (2010) 17.M. K. Nazeeruddin, A. Key, I. Rodicio, R. Humphry-Baker, E. Müller, P. Liska, N. Vlachopulos, and M. Grätzel, J. Am. Chem. Soc. 115, 6382 (1993) 18.A. Islam, H. Sugihara, K. Hara, L. P. Singh, R. Katoh, M. Yanagida, Y. Takahashi, S. Murata, and H. Arakawa, J. Photochem. Photobiol., A 145, 135 (2001) 19.M. K. Nazeeruddin, P. Pechy, and M. Grätzel, Chem. Commun. 1705 (1997) 20.D. Kuciauskas, M. S. Freund, H. B. Gray, J. R. Winkler, and N. S. Lewis, J. Phys. Chem. B 105, 392 (2001) 21.R. Argazzi, G. Larramona, C. Contado, and C. A. Bignozzi, J. Photochem. Photobiol., A 164, 15 (2004) 22.N. Robertson, Angew. Chem. Int. Edit. 45, 2338 (2006) 23.M. K. Nazeeruddin, A. Kay, I. Rodicio, R. Humphry-Baker, E. Mueller, P. Liska, N. Vlachopoulos, and M. Grätzel, J. Am. Chem. Soc. 115, 6382 (1993) 24.A. S. Polo, M. K. Itokazu, and N. Y. Murakami Iha, Coord. Chem. Rev. 248, 1343 (2004) 25. F. Gao, Y. Wang, D. Shi, J. Zhang, M. Wang, X. Jing, R. Humphry-Baker, P. Wang, S. M. Zakeeruddin, and M. Grätzel, J. Am. Chem. Soc. 130, 10720 (2008) 26.M. K. Nazeeruddin, S. M. Zakeeruddin, R. Humphry-Baker, M. Jirousek, P. Liska, N. Vlachopoulos, V. Shklover, Christian-H. Fischer, and M. Grätzel, Inorg. Chem, 38, 6298 (1999) 27.A. Hagfeldt, M. Grätzel, Chem. Rev. 95, 49 (1995) 28.A. Hagfeldt, M. Grätzel, Acc. Chem. Res. 33, 269 (2000) 29.S. M. Zakeeruddin, M. K. Nazeeruddin, R. Humphry-Baker, P. Péchy, P. Quagliotto, C. Barolo, G. Viscardi, and M. Grätzel, Langmuir 18, 952 (2002) 30.P. Wang, S. M. Zakeeruddin, J. E. Moser, M. K. Nazeeruddin, T. Sekiguchi, and M. Grätzel, Nat. Mater. 2, 402 (2003) 31.D. Kuang, S. Ito, B. Wenger, C. Klein, J.-E. Moser, R. Humphry- Baker, S. M. Zakeeruddin, and M. Grätzel, J. Am. Chem. Soc. 128, 4146 (2006) 32.D. Kuang, P. Wang, S. Ito, S. M. Zakeeruddin, and M. Grätzel, J. Am. Chem. Soc. 128, 7732 (2006) 33.M. K. Nazeeruddin, D. Di Censo, R. Humphry- Baker, and M. Grätzel, Adv. Funct. Mater. 16, 189 (2006) 34.M. K. Nazeeruddin, F. De Angelis, S. Fantacci, A. Selloni, G. Viscardi, P. Liska, S. Ito, B. Takeru, and M. Grätzel, J. Am. Chem. Soc. 127, 16835 (2005) 35.S. E. Koops, B. C. O’Regan, P. R. F. Barnes, and J. R. Durrant, J. Am. Chem Soc. 131, 4808 (2009) 36.D. Kuang, C. Klein, H. J. Snaith, L. E. Moser, R. H. Baker, P. Comte, S. M. Zakeeruddin, and M. Grätzel, Nano. Lett. 6, 769 (2006) 37.P. Wang, S. M. Zakeeruddin, J.-E. Moser, R. Humphry-Baker, P. Comte, V. Aranyos, A. Hagfeldt, M. K. Nazeeruddin, and M. Grätzel, Adv. Mater. 16, 1806 (2004) 38.M. Nazeeruddin, T. Bessho, L. Cevey, S. Ito, C. Klein, F. D. Angelis, S. Fantacci, P. Comte, P. Liska, H. Imai, and M. Grätzel, J. Photochem. Photobiol. A-Chem. 185, 331 (2007) 39.C. Y. Chen, S. J. Wu, C. G. Wu, J. G. Chen, and K. C. Ho, Angew.Chem. Int. Edit. 45, 5822 (2006) 40.C. Y. Chen, S. J. Wu, J. Y. Li, C. G. Wu, J. G. Chen, and K. C. Ho, Adv. Mater. 19, 3888 (2007) 41.K.-J. Jiang, N. Masaki, J. Xia, S. Nodab, and S. Yanagida, Chem. Commun. 2460 (2006) 42.F. Gao, Y. Wang, D. Shi, J. Zhang, M. Wang, X. Jing, R. Humphry-Baker, P. Wang, S. M. Zakeeruddin, and M. Grätzel, J. Am. Chem. Soc. 130, 10720 (2008) 43. F. Gao, Y. Cheng, Q. Yu, S. Liu, D. Shi, Y. Li, and P. Wang, Inorg. Chem. 48, 2664 (2009) 44.C. S. Karthikeyan, H. Wietasch, and M. Thelakkat, Adv. Mater. 19, 1091 (2007) 45.J. H. Yum, H. Jung, C. Baik, J. Ko, M. K. Nazeeruddin, and M. Grätzel, Energy Environ. Sci. 2, 100 (2009) 46.G. Redmond, D. Fitzmaurice, Chem. Mater. 6, 686 (1994) 47.P. V. Kamat, I. Bedja, S. Hotchandani, and L. K. Patterson, J. Phys. Chem. 100, 4900 (1996) 48.H. Rensmo, K. Keis, H. Lindstrom, S. Sodergren, A. Solbrand, A. Hagfeldt, and S. E. Lindquist, J. Phy. Chem. B 101, 2598 (1997) 49.D. Liu, G. L. Hug, and P. V. Kamat, J. Phys. Chem. 99, 16768 (1995) 50.I. Bedja, S. Hotchandani, and P. V. Kamat, J. Phys. Chem. 98, 4133 (1994) 51.M. K. Nazeeruddin, A. Kay, I. Rodicio, R. Humphry-Baker, E. Müller, P. Liska, N. Vlachopoulos, and M. Grätzel, J. Am. Chem. Soc. 115, 6382 (1993) 52.O. Kohle, S. Ruile, and M. Grätzel, Inorg. Chem. 35, 4779 (1996) 53.V. Shklover, M. K. Nazeeruddin, S. M. Zakeeruddin, C. Barbe, A. Kay, T. Haibach, W. Steurer, R. Hermann, H.-U. Nissen, and M. Grätzel, Chem. Mater. 9, 430 (1997) 54.R. Amadelli, R. Argazzi, C. A. Bignozzi, and F. Scandola, J. Am. Chem. Soc. 112, 7099 (1990) 55.R. Argazzi, C. A. Bignozzi, Inorg. Chem. 36, 2 (1997) 56.N. G. Park, J. Van de Langemaat, and A. J. Frank, J. Phys. Chem. B 104, 8989 (2000) 57.B. Sun, A. V. Vorontsov, and P. G. Smirniotis, Langmuir 19, 3151 (2003) 58.D. M. Antonelli, J. Y. Ying, Angew. Che. Int. Edit. 18, 2014 (1995) 59.S. D. Burnside, V. Shklover, C. Barbe, P. Comte, F. Arendse, K. Brooks, and M. Grätzel, Chem. Mater. 10, 2419 (1998) 60.J. Weidmann, T. Dittrich, E. Konstantinova, I. Lauermann, I. Uhlendorf, and F. Koch, Sol. Energy Mater. Sol. Cells 56, 153 (1999) 61.C. J. Barbé, F. Árendse, P. Comte, M. Jirousek, F. Lenzmann, V. Shklover, and M. Grätzel, J. Am. Cera. Soc. 80, 3157 (1997) 62. Y. Qiu, W. Chen, and S. Yang, Angew. Chem. 122, 3757 (2010) 63. M. Grätzel, Journal of Photochemistry and Photobiology A: Chemistry 164, 3 (2004) 64.A. Hauch, A. Georg, Electrochimica Acta 46, 3457 (2001) 65.A. Kay, M. Grätzel, Sol. Energy Mater Sol Cells 44, 99 (1996) 66.T. N. Murakami, S. Ito, Q. Wang, M. K. Nazeeruddin, T. Bessho, I. Cesar, P. Liska, R. Humphry-Baker, P. Comte, P. Péchy, and M. Grätzel, J. Electrochem. Soc. 153, 12, A2255-A2261 (2006) 67.Y. Saito, W. Kubo, T. Kitamura, Y. Wada, and S. Yanagida, J. Photochem. Photobiol. A, 164, 153 (2004) 68.R. Senadeera, N. Fukuri, Y. Saito, T. Kitamura, Y. Wada, and S. Yanagida, Chem. Commun., 2259 (2005) 69.G. Wolfbauer, A. M. Bond, J. C. Eklund, and D. R. MacFarlane, Sol. Energy Mater. Sol. Cells 70, 85 (2001) 70. Z. Yu, M. Gorlov, J. Nissfolk, G. Boschloo, and L. Kloo, J. Phys. Chem. C 114, 10612 (2010) 71.P. Wang, S. M. Zakeeruddin, J.-E. Moser, R. Humphry-Baker, and M. Grätzel, J. Am. Chem. Soc. 126, 7164 (2004) 72.Z. Zhang, P. Chen, T. N. Murakami, S. M. Zakeeruddin, and M. Grätzel, Adv. Funct. Mater. 18, 341 (2008) 73.S. Günes, N. S. Sariciftci, Inorganica Chimica Acta, 361, 581 (2008) 74.L. S. Mende, M. Grätzel, Thin Solid Film 500, 296 (2006) 75. E. Stathatos, P. Lianos, U. L. Stangar, B. Orel, Adv. Mater. 14, 5, 354 (2002) 76. T. C. Wei, C. C. Wan, Y. Y. Wang, Sol. Energy Mater. Sol. Cells 91, 1892, (2007) 77. P. J. Li, J. H. Wu, M. L. Huang, S. C. Hao, Z. Lan, Q. H. Li, S. J. Kang, Electrochim. Acta 53, 903 (2007) 78. P. Petrov, I. Berlinova, C. B. Tsvetanov, S. Rosselli, A. Schmid, A. B. Zilaei, T. Miteva, M. Dürr, A. Yasuda, G. Nelles, Macromol. Mater. Eng. 293, 598 (2008) 79.C. W. Tu, K. Y. Liu, A. T. Chien, M. H. Yen, T. H. Weng, K. C. Ho, and K. F. Lin, J. Polym. Sci. A 46, 47 (2008) 80.C. W. Tu, K. Y. Liu, A. T. Chien, C. H. Lee, K. C. Ho, and K. F. Lin, Euro. Polym. J. 44, 608 (2008) 81. P. Wang, S.M. Zakeeruddin, J.E. Moser, M. Grätzel, J. Phys. Chem. B 107, 13280 (2003) 82. M. Grätzel, J. Photochem. Photobiol. A-Chem. 164, 3 (2004) 83.T. Mitsumori, I. M. Craig, I. B. Martini, B. J. Schwartz, and F. Wudl, Macromolecules 38, 4698 (2005) 84.A. A. Farah, W. J. Pietro, Canadian Journal of Chemistry, 82, 595 (2004) 85.C. L. Donnicia, D. H. M. Filhoa, L. L. C. Moreiraa, G. T. Dos Reisa, E. S. Cordeiro, I. Ma. F. de Oliveira, S. Carvalho, and E. B. Paniago, J. Braz. Chem. Soc. 9, 455 (1998) 86. L. D. Ciana, W. J. Dressick, and A. Von Zelewsky, J. Heterocyclic Chem. 27, 163 (1990) 87.Q. Wang, J.-E. Moser, and M. Grätzel, J. Phys. Chem. B., 109, 14945 (2005) 88.K. M. Lee, V. Suryanarayanan, and K. C. Ho, Journal of Power Source, 185, 1605 (2008) 89.www.autolab-instruments.com 90.M. Zistler, P. Wachter, P. Wasserscheid, D. Gerhard, A. Hinsch, R. Sastrawan, and H. J. Gores, Electrochim. Acta. 52, 161 (2006) | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/10490 | - |
dc.description.abstract | 本研究合成一帶有可進行聚合反應之苯乙烯官能基的釕金屬染料Ru(4,4’-dicarboxylic acid) (4,4'-bis((4-vinylbenzyloxy)methyl) -2,2'- bipyridine)(NCS)2 簡稱 Ru-S 。利用NMR、IR、UV-Vis光譜等方式鑑定其結構,並進一步以UV-Vis光譜測試其吸附在TiO2表面後以Glycerol propoxylate triacrylate(GPTA)進行共聚合反應後的脫附實驗,探討其與TiO2鍵結的穩定性。在太陽能電池元件的表現上,以3-methoxypropyl nitrile (MPN)為溶劑的液態電解質時以不同濃度的GPTA進行表面聚合改質後,可以將原本7.53%的效率分別提升至7.88%。而以polymethacrylate膠態電解質製備的元件則能將效率從6.96%增加至7.57%。 另一部分則以改變液態電解質中Li+的濃度來觀察以GPTA表面改質前後的電池表現。 在缺乏或低濃度Li+的液態系統中,表面聚合改質皆可以在最佳化濃度下呈現出比原本較高的效率表現。 但在高濃度的Li+電解質下,由於改質後元件的短路電流提升效果不明顯,且Voc下降,造成效率並未得到改善。 從吸附在TiO2上Ru-S染料的IR光譜實驗可證明Ru-S染料本身即具有螯合Li+減緩因提高Li+濃度造成Voc下降的能力。量測IMPS/IMVS時發現,隨著LiI濃度提升,電子收集效率也會愈高,證明Li+有加速I-/I3-移動的能力。最後,我們選用PMA膠態電解質進行封裝,量測元件的長效性。於室溫下經過一個月發現效率仍可保有原先水準,唯獨以AIBN起始劑交聯的Crosslinked Ru-S的效率會略降。 | zh_TW |
dc.description.abstract | We synthesized the crosslinkable ruthenium complex with styryl groups attached on the bipyridine ligand, denoted as Ru-S which was characterized by NMR, IR, and UV-Vis spectroscopies. Its stability after crosslinking and copolymerization with Glycerol propoxylate triacrylate(GPTA) were measured by UV-Vis spectroscopy. By using the MPN based liquid electrolyte, the efficiency of DSSCs crosslinking with proper amounts GPTA increased from 7.53% to 7.88%. However, using the PMA-gelled electrolyte system, the device performance was raised from 6.96% to 7.57%. On the other hands, the DSSC with GPTA-crosslinked Ru-S dye and with various Li+ concentrations in liquid electrolytes were studied. At low Li+ concentration, the efficiency was increased with the content of Li+. However, at high Li+ concentration, although the short current was slightly increased with the content of Li+ but the Voc was decreased, leading to lower power efficiency. The Li+-coordination capability of Ru-S was then investigated by IR spectroscopy, which was used to explain the slow decreasing trend of Voc as the Li+ concentration was increased in the electrolyte system. | en |
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dc.description.tableofcontents | 第一章 緒論
1.1 背景………………………………………………………………………1 1.2 太陽能電池之檢測………………………………………………………2 1.2.1太陽能電池光電轉換效率的計算……………………………………….2 1.2.2 交流阻抗分析簡介……………………………………………………4 1.2.3 Intensity Modulated photocurrent spectroscopy(IMVS)簡介……………7 1.2.4 Intensity Modulated photovoltage spectroscopy(IMPS)簡介……………9 第二章 文獻回顧與研究目的 2.1 染料敏化太陽能電池簡介………………………………………………12 2.2 染料敏化太陽能電池工作原理…………………………………………13 2.3 染料………………………………………………………………………18 2.4 透明導電玻璃……………………………………………………………25 2.5 工作電極…………………………………………………………………25 2.6 對電極……………………………………………………………………29 2.7 電解質……………………………………………………………………31 2.7.1 液態電解質……………………………………………………………32 2.7.2 固態電解質…………………………………………………………….32 2.7.3 膠態電解質…………………………………………………………….34 2.7.4 離子液體電解質………………………………………………………35 2.8 實驗動機與架構…………………………………………………………35 第三章 實驗設備與方法 3.1 實驗藥品…………………………………………………………………37 3.2 實驗儀器與設備…………………………………………………………40 3.3 合成方法…………………………………………………………………41 3.3.1 合成Ru-S………………………………………………………………41 3.3.2 .合成1-methyl-3-propylimidazolium iodide (MPII) …………………45 3.4 二氧化鈦鍍液製備…………………………………………………….45 3.5 薄膜電極的製備……………………………………………………….46 3.5.1導電玻璃之清洗………………………………………………………46 3.5.2 FTO導電玻璃的清洗…………………………………………………46 3.5.3 ITO導電玻璃的清洗…………………………………………………46 3.5.4工作電極(二氧化鈦電極製備) ……………………………………… 46 3.5.5 白金對電極的製備……………………………………………………47 3.6 電解質之製備……………………………………………………………47 3.6.1 液態電解質……………………………………………………………47 3.6.2 膠態電解質…………………………………………………………….48 3.7 太陽能電池組裝………………………………………………………..48 3.7.1 電池元件組裝…………………………………………………………48 3.7.2 元件封裝. ……………………………………………………………49 3.8 太陽能電池光電化學測試………………………………………………49 3.8.1 光電流-電壓特徵曲線(Photocurrent-Voltage Characterization) ……49 3.8.2 交流阻抗分析(AC Impedance ) ………………………………………50 3.8.3 DSC之樣品製備和測試條件…………………………………………50 3.8.4入射光子-電流轉換效率 (Incident Photo to Current conversion Efficiency) …………………………………………………………….51 3.8.5 IMPS與IMVS之量測………………………………………………51 3.8.6元件封裝測試…………………………………………………………51 第四章 結果與討論 4.1 Ru-S鑑定……………………………………………………………….52 4.1.1 Ru-S染料的鑑定…………………………………………………….52 4.1.1.1 Ru-S染料的NMR鑑定……………………………………………52 4.1.1.2 Ru-S染料的紫外光/可見光光譜鑑定………………………………54 4.1.1.3 Ru-S染料的紅外線光譜鑑定………………………………………56 4.1.1.4 Ru-S染料的交聯性質………………………………………………56 4.1.1.4.1紅外光光譜. ……………………………………………………….56 4.1.1.4.2表面改質交聯劑Glycerol propoxylate triacrylate(GPTA) ………57 4.1.1.4.3紫外光/可見光光譜…………………………………………………58 4.2 不同電解質對未改質Ru-S及Crosslinked Ru-S元件性能之影響……60. 4.2.1 電解質A………………………………………………………………60 4.2.1.1 未加LiClO4之電解質A……………………………………………60 4.2.1.2 含0.05M LiClO4之電解質A. ……………………………………61 4.2.1.3 含0.25M LiClO4之電解質A…………………………………… 62 4.2.1.4 不同LiClO4濃度對Ru-S, Crosslinked Ru-S元件性能之影響……63 4.2.1.5 含電解質A之未改質 Ru-S元件交流阻抗分析…………………66 4.2.1.6 含電解質A之Crosslinked Ru-S元件交流阻抗分析……………70 4.2.2 Ru-S螯合Li+之IR分析……………………………………………74 4.2.3 電解質B…………………………………………………………76 4.2.3.1 含0.1M LiI之電解質B…………………………………………….76 4.2.3.2 改變LiI濃度(0-0.2M)之電解質B對未改質Ru-S元件性能的影響 ………………………………………………………………… 77 4.2.3.3 改變LiI濃度(0-0.2M)電解質B對未改質Ru-S元件之交流阻抗分 析………………………………………………………………78 4.2.3.4 改變LiI濃度(0-0.2M)之電解質B對Crosslinked Ru-S元件性能的 影響………………………………………………………………82 4.2.3.5 改變LiI濃度(0-0.2M)之電解質B對Crosslinked Ru-S元件交流阻 抗分析………………………………………………………………83 4.2.4 PMA膠態電解質………………………………………………………87 4.3 不同電解質對Ru-S-co-GPTA元件性能之影響………………………88 4.3.1 GPTA改質劑分子大小的計算…………………………………………88 4.3.2電解質A………………………………………………………………88 4.3.2.1 未加LiClO4之電解質A:針對不同濃度GPTA交聯之Ru-S元件88 4.3.2.2 含0.05M LiClO4之電解質A:針對不同濃度GPTA交聯之Ru-S 元件……………………………………………………………90 4.3.2.3 含0.25M LiClO4之電解質A:針對不同濃度GPTA交聯之Ru-S 元件……………………………………………………………91 4.3.2.4不同LiClO4濃度對Ru-S-co-GPTA元件性能之影響……………93 4.3.2.5 改變LiClO4濃度(0-0.25M)之電解質A對Ru-S-co-GPTA元件之交 流阻抗分析…………………………………………………………94 4.3.3 電解質B………………………………………………………………98 4.3.3.1 含0.1M LiI之電解質B:針對不同濃度GPTA交聯之Ru-S元件98 4.3.3.2改變LiI濃度(0-0.2M)之電解質B……………………………………99 4.3.3.3改變LiI濃度(0-0.2M)之電解質B對Ru-S-co-GPTA元件之交流阻 抗分析………………………………………………………………101 4.3.3.4改變LiI濃度(0-0.2M)之電解質B對IMVS/IMPS之探討…………105 4.3.3.4.1 於4.5mW/cm2光強度下之IMVS與IMPS之分析……………..106 4.3.3.4.2 於4.18mW/cm2光強度下之IMVS與IMPS之分析…………..109 4.3.3.4.3 於3.56mW/cm2光強度下之IMVS與IMPS之分析……………112 4.3.3.5電解質B(含0.1M LiI):針對不同光強度之IMVS/IMPS探討……115 4.3.4 PMA膠態電解質……………………………………………………119 4.3.4.1 PMA膠態電解質對Ru-S-co-GPTA元件性能的影響……………119 4.3.4.2 PMA膠態電解質對Ru-S、Crosslinked Ru-S及Ru-S-co-GPTA 之交流阻抗分析………………………………………………120 4.4 PMA膠態電解質之DSC及流變儀鑑定……………………………124 4.5 Ru-S在改質前後於液態和膠態電解質之IPCE 分析………………125 4.6元件長效性分析……………………………………………………127 第五章 結論……………………………………………………………131 參考資料………………………………………………………………133 附錄1…………………………………………………………………140 附錄2…………………………………………………………………145 | |
dc.language.iso | zh-TW | |
dc.title | 可交聯型釕金屬錯合物與其交聯劑在染料敏化太陽能電池之應用 | zh_TW |
dc.title | Applications of Crosslinkable Ruthenium Complex and Its Crosslinker on Dye-sensitized Solar Cells | en |
dc.type | Thesis | |
dc.date.schoolyear | 98-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 何國川(Kuo-Chuan Ho),邱文英(Wen-Yen Chiu),趙基揚(Chi-Yang Chao) | |
dc.subject.keyword | 太陽能電池,釕金屬錯合物,光電轉換效率, | zh_TW |
dc.subject.keyword | solar cells,ruthenium complex,power conversion efficiency, | en |
dc.relation.page | 151 | |
dc.rights.note | 同意授權(全球公開) | |
dc.date.accepted | 2010-08-18 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
顯示於系所單位: | 高分子科學與工程學研究所 |
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