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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 林江珍(Jiang-Jen Lin) | |
| dc.contributor.author | Yi-Fen Lan | en |
| dc.contributor.author | 藍伊奮 | zh_TW |
| dc.date.accessioned | 2021-05-20T21:20:50Z | - |
| dc.date.available | 2010-11-15 | |
| dc.date.available | 2021-05-20T21:20:50Z | - |
| dc.date.copyright | 2010-11-15 | |
| dc.date.issued | 2010 | |
| dc.date.submitted | 2010-10-29 | |
| dc.identifier.citation | 1 M. Ardenne, Zeitschrift für technische Physik, 1938, 19, 407.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/10329 | - |
| dc.description.abstract | 奈米技術發展數十年，各式各樣的奈米材料已被發現或製備，為了應用這些奈米材料，分散技術是關鍵點。在文獻中已提出各種化學或物理的分散方法，然而，這些技術仍無法配合分散和應用間的需求。因此，我們建立了一個新式的分散系統－幾何形態分散，其分散概念為利用材料在幾何形態上的高度差異性，可提升材料的分散性。在本研究中，各種奈米材料(奈米碳管、奈米碳球、奈米炭黑、
奈米銀粒子、奈米鐵粒子)、疏水性共軛高分子和有機顏料被用來應證“幾何形態影響分散”之通則性。 | zh_TW |
| dc.description.abstract | Nanotechnology has been developed for decades and various nanomaterials were created and discovered. To apply these nanomaterials in advanced applications, dispersion techniques are the key issue for utilizing the novel nanomaterials. In the literatures, a variety of dispersion methods involving chemical and physical approaches were proposed. However, these techniques are still not meeting the requirements for the applications. Therefore, we established a new dispersion method based on the concept of using the distinct difference of geometric shapes of
nanomaterials namely, “Geometric-Shape Inhomogeneity Factor” (GIF) for Dispersion. Various nanomaterials, including carbon nanotubes, carbon blacks, carbon nanocapsules, silver nanoparticles, iron-oxide nanoparticles, hydrophobic conjugated polymers and organic pigments were selected to generalize the GIF. All practical applications have been successfully improved on utilizing GIF for dispersing nanomaterials. | en |
| dc.description.provenance | Made available in DSpace on 2021-05-20T21:20:50Z (GMT). No. of bitstreams: 1 ntu-99-D95549006-1.pdf: 31567479 bytes, checksum: 57b43bee97848dbf7a8fefefbd58b4b0 (MD5) Previous issue date: 2010 | en |
| dc.description.tableofcontents | 國立臺灣大學博士學位論文口試委員會審定書...................................................................................... I
謝 誌..........................................................................................................................................................II CONTENT.............................................................................................................................................. III LIST OF TABLES....................................................................................................................................V LIST OF FIGURES................................................................................................................................ VI 摘 要........................................................................................................................................................ IX ABSTRACT..............................................................................................................................................X CHAPTER 1. INTRODUCTION OF DISPERSION TECHNIQUES FOR NANOMATERIALS- 12 - 1.1. HISTORY AND DEVELOPMENT OF NANOTECHNOLOGY AND DISPERSION TECHNIQUES ..........- 12 - 1.1.1. Dispersion Techniques for Carbon Nanotubes ................................................................ - 14 - 1.1.2. Dispersion Techniques for Nanoparticles ........................................................................ - 20 - 1.1.2.1. Dispersion Techniques for Carbon Nanoparticles.....................................................................- 20 - 1.1.2.2. Preparation and Dispersion Techniques for Silver Nanoparticles ............................................- 24 - 1.1.2.3. Preparation and Dispersion Techniques for Iron-Oxide Nanoparticles ...................................- 29 - 1.1.3. Dispersion Techniques for Hydrophobic Conjugated Polymers...................................... - 31 - 1.1.4. Dispersion Techniques for Organic Pigments.................................................................. - 34 - 1.2. NEW DISPERSION TECHNIQUES OF GEOMETRIC-SHAPE INHOMOGENEITY FACTOR ..............- 37 - CHAPTER 2. EXPERIMENTAL SECTION.................................................................................... - 39 - 2.1. MATERIALS................................................................................................................................- 39 - 2.1.1. Platelet-Like Clays ............................................................................................................ - 39 - 2.1.2. Tubular Nanomaterials..................................................................................................... - 40 - 2.1.3. Nanoparticles .................................................................................................................... - 40 - 2.1.4. Hydrophobic Conjugated Polymers.................................................................................. - 41 - 2.1.5. Poly(N-Isopropyl Acrylamide)-Tethered NSP .................................................................. - 43 - 2.1.6. Organic Pigments.............................................................................................................. - 44 - 2.2. PREPARATION OF NANOMATERIALS-CLAY HYBRIDS................................................................- 45 - 2.3. AMPHIPHILIC DISPERSION IN ORGANIC SOLVENTS OR WATER ...............................................- 45 - 2.4. CHARACTERIZATIONS...............................................................................................................- 46 - 2.4.1. Dispersion......................................................................................................................... - 46 - 2.4.2. Thermoresponsive Behavior ............................................................................................. - 46 - 2.4.3. Luminescence Property..................................................................................................... - 47 - 2.4.4. Conductivity Property........................................................................................................ - 47 - 2.4.5. Thermal Degradation, Particle Size and Zeta Potential Properties................................. - 47 - CHAPTER 3. RESULTS AND DISCUSSION.................................................................................. - 49 - 3.1. DISPERSION OF TUBULAR-LIKE NANOMATERIALS BY USING PLATELET-LIKE CLAYS ...........- 49 - 3.1.1. Dispersion of Carbon Nanotubes in the Presence of Clays ............................................. - 50 - 3.1.2. Amphiphilic Property for Dispersion................................................................................ - 55 - 3.1.3. Explanation for the Formation of Mica-CNT Microstructures....................................... - 59 - 3.1.4. Conclusion........................................................................................................................ - 60 - 3.2.1. Dispersion of Carbon Nanocapsules in the Presence of Clays........................................ - 62 - 3.2.2. Dispersion of Carbon Black in the Presence of Clays ..................................................... - 70 - 3.2.3. Preparation and Dispersion of Silver Nanoparticles in the Presence of Clays............... - 72 - 3.2.4. Preparation and Dispersion of Iron-Oxide Nanoparticles in the Presence of Clays ...... - 73 - 3.3. DISPERSION OF HYDROPHOBIC CONJUGATED POLYMERS BY USING PLATELET-LIKE CLAYS AND THEIR THERMORESPONSIVE PROPERTY...................................................................................- 75 - 3.3.1. Dispersion of CP/Clay in the Presence of Clays .............................................................. - 76 - 3.3.2. Optical Performance of CP/Mica Hybrids ....................................................................... - 83 - 3.3.3. Explanation for the Dispersion Behavior of CP/Clay...................................................... - 87 - 3.3.4. Thermoresponsive behavior of conjugated polymer induced by NSP-PNiPAAm........... - 89 - 3.3.5. Photoluminescence behavior of dispersion solution and solid film ................................ - 95 - 3.3.6. Conclusion........................................................................................................................ - 98 - 3.4. DISPERSION OF ORGANIC PIGMENTS BY USING PLATELET-LIKE CLAYS...............................- 100 - 3.4.1. Dispersion of Organic Pigments in the Presence of Clays ............................................ - 101 - 3.4.2. Conclusion...................................................................................................................... - 114 - CHAPTER 4. SUMMARY ............................................................................................................... - 115 - REFERENCES................................................................................................................................. - 117 - | |
| dc.language.iso | en | |
| dc.subject | 分散 | zh_TW |
| dc.subject | 米碳管 | zh_TW |
| dc.subject | 碳黑 | zh_TW |
| dc.subject | 米碳球 | zh_TW |
| dc.subject | 共軛高分子 | zh_TW |
| dc.subject | 顏料 | zh_TW |
| dc.title | 幾何形態影響分散因子之通則性 | zh_TW |
| dc.title | Generalization of Geometric-Shape Inhomogeneity Factor
for Dispersion | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 99-1 | |
| dc.description.degree | 博士 | |
| dc.contributor.oralexamcommittee | 謝國煌(Kuo-Huang Hsieh),邱文英(Wen-Yen Chiu),蔣見超(Raymond Chien-Chao Tsiang),李榮和(Rong-Ho Lee) | |
| dc.subject.keyword | 分散,奈,米碳管,碳黑,奈,米碳球,共軛高分子,顏料, | zh_TW |
| dc.subject.keyword | dispersion,carbon nanotube,carbon black,conjugated polymer,pigment, | en |
| dc.relation.page | 133 | |
| dc.rights.note | 同意授權(全球公開) | |
| dc.date.accepted | 2010-11-01 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-99-1.pdf | 30.83 MB | Adobe PDF | 檢視/開啟 |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。