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  1. NTU Theses and Dissertations Repository
  2. 工學院
  3. 化學工程學系
請用此 Handle URI 來引用此文件: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/103115
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dc.contributor.advisor陳誠亮zh_TW
dc.contributor.advisorCheng-Liang Chenen
dc.contributor.author李俊誠zh_TW
dc.contributor.authorChun-Cheng Lien
dc.date.accessioned2026-08-05T16:09:33Z-
dc.date.available2026-08-06-
dc.date.copyright2026-08-05-
dc.date.issued2026-
dc.date.submitted2026-07-28-
dc.identifier.citationRefferences
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2.Aziz, M., A.T. Wijayanta, and A.B.D. Nandiyanto, Ammonia as effective hydrogen storage: A review on production, storage and utilization. Energies, 2020. 13(12): p. 3062.
3.Abudureyimu, A., et al., A Comprehensive Review of Green Hydrogen Technology: Electrolysis Methods, Topologies and Control Strategies, Applications. Materials, 2025. 18(21): p. 4826.
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8.Jallal, C. New Aframax exceeds latest environmental standards. 2020 10 Mar 2020; Available from: https://www.rivieramm.com/news-content-hub/news-content-hub/new-aframax-exceeds-latest-environmental-standards-58451.
9.Croatian Shipbuilding Corporation, Tankers. 2014, Croatian Shipbuilding Corporation: Zagreb, Croatia.
10.Valera-Medina, A., et al., Ammonia for power. Progress in Energy and Combustion Science, 2018. 69: p. 63-102.
11.Kobayashi, H., et al., Science and technology of ammonia combustion. Proceedings of the combustion institute, 2019. 37(1): p. 109-133.
12.Tornatore, C., et al., Ammonia as Green Fuel in Internal Combustion Engines: State-of-the-Art and Future Perspectives. Frontiers in Mechanical Engineering, 2022. Volume 8 - 2022.
13.Lesmana, H., et al., NH3 as a Transport Fuel in Internal Combustion Engines: A Technical Review. Journal of Energy Resources Technology, 2019. 141(7).
14.Glarborg, P., et al., Oxidation of formaldehyde and its interaction with nitric oxide in a flow reactor. Combustion and flame, 2003. 132(4): p. 629-638.
15.Mashruk, S., et al., Evolution of N2O production at lean combustion condition in NH3/H2/air premixed swirling flames. Combustion and Flame, 2022. 244: p. 112299.
16.Zhu, Y., et al., The combustion chemistry of ammonia and ammonia/hydrogen mixtures: A comprehensive chemical kinetic modeling study. Combustion and Flame, 2024. 260: p. 113239.
17.Kim, T.S. and S.H. Hwang, Techno-economic sensitivity analysis and thermoeconomic optimization of advanced J- and H-class gas turbine combined cycle power plants. Energy Conversion and Management, 2023. 284: p. 116982.
18.Okubo, M., Gas Turbine Combined Cycle (GTCC) and Renewable Energy Technologies, in Electrical Sustainable Energy for Mechanical Engineering. 2025, Springer. p. 169-191.
19.Valera-Medina, A., et al., Review on ammonia as a potential fuel: from synthesis to economics. Energy & Fuels, 2021. 35(9): p. 6964-7029.
20.Langer, R., et al., Adjoint sensitivity analysis of kinetic, thermochemical, and transport data of nitrogen and ammonia chemistry. Proceedings of the Combustion Institute, 2021. 38(1): p. 777-785.
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22.Dyson, D. and J. Simon, Kinetic expression with diffusion correction for ammonia synthesis on industrial catalyst. Industrial & engineering chemistry fundamentals, 1968. 7(4): p. 605-610.
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26.Busca, G., et al., Chemical and mechanistic aspects of the selective catalytic reduction of NOx by ammonia over oxide catalysts: A review. Applied Catalysis B: Environmental, 1998. 18(1-2): p. 1-36.
27.Forzatti, P., Present status and perspectives in de-NOx SCR catalysis. Applied Catalysis A: General, 2001. 222(1-2): p. 221-236.
28.Han, L., et al., Selective Catalytic Reduction of NOx with NH3 by Using Novel Catalysts: State of the Art and Future Prospects. Chemical Reviews, 2019. 119(19): p. 10916-10976.
29.Pai, L., Preparation and Characterization of Honeycomb Catalyst for Selective Catalytic Reduction of NO. 9023, National Taiwan University: Taipei, Taiwan.
30.International Renewable Energy Agency, Renewable power generation costs in 2024. 2025, International Renewable Energy Agency: Abu Dhabi.
31.Fischer, T. and J. Gier. Design and Operational Capabilities of the New Siemens Energy HL-Class Gas Turbines. in Proceedings of the ASME Turbo Expo. 2021.
32.Psaraftis, H.N. and C.A. Kontovas, Speed models for energy-efficient maritime transportation: A taxonomy and survey. Transportation Research Part C: Emerging Technologies, 2013. 26: p. 331-351.
33.Cariou, P. and T. Notteboom, Bunker costs in container liner shipping: are slow steaming practices reflected in maritime fuel surcharges. Current issues in shipping, ports and logistics, 2011: p. 69-82.
34.Lindstad, H., B.E. Asbjørnslett, and A.H. Strømman, Reductions in greenhouse gas emissions and cost by shipping at lower speeds. Energy policy, 2011. 39(6): p. 3456-3464.
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dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/103115-
dc.description.abstract全球氣候變遷與綠電分布不均,需要系統性的整合轉型策略。本研究建立完整的「電轉氨轉電(P2A2P)」零碳供應鏈模型,利用綠氨作為儲存氫氣的載體,將國外豐富的再生能源直接運送至缺乏能源的台灣,支持 2050 年淨零碳排目標。出口國製氫分析顯示高溫固態氧化物電解槽(SOEC)的長期成本將顯著下降。雖然 SOEC 在 2020 年成本超過 2,200 $/kW,但預計自動化量產將在 2040 年降至 600 $/kW,2050 年降至 500 $/kW,證實本研究採用 1250 $/kW 作為計算基準的合理性。此外,製程整合了空氣分離裝置(ASU)提供氮氣。優化結果顯示,將合成氨反應的大量廢熱回收用於預熱電解槽蒸汽,並平衡 SOEC 熱需求,能省下大量電力,成功將整個供應鏈的總回程效率(RTE)提高到 33.13%。海運物流評估顯示,氨氣在 -34°C 即可液化運送,技術與成本顯著優於需要 -253°C 的液態氫。靈敏度分析指出船速與成本呈「U型」關係:低於 5 節會浪費時間並增加蒸發損失,高於 20 節則因水阻力導致燃料消耗飆升。模型精準算出 15 節(knots) 是台灣進口總成本最低的黃金船速。GTCC 發電模擬利用 Aspen Plus 進行,當氨燃氣渦輪複合循環電廠在 30 bar 高壓與 1750°C 高溫下運作時,發電端可達到 60.54% 的高效率,並穩定輸出 715 MW 電力。針對氨氣燃燒時氮氧化物(NOx)污染飆升至天然氣 100 倍的缺陷,本研究整合煙氣再循環(FGR)與 30 級觸媒脫硝(SCR)系統,成功將終端排煙 NOx 濃度壓低至 9 ppm,符合嚴格環保法規。
整體經濟評估全面攤提了建造與營運成本,在出口國綠電價格為 30 $/MWh 的基準下,輸配至台灣的終端度電成本收斂在 223 $/MWh。此成本架構面對國際碳稅風險時展現出極佳的經濟韌性。本研究透過量化模擬結果證明綠氨進口策略的可行性,為台灣未來 2050 年規劃綠能採購與電網動態平衡時,提供了一套具備實務價值的評估架構與定量分析視角。
zh_TW
dc.description.abstractGlobal climate change and the uneven distribution of green electricity require integrated, system-level energy transition strategies. This study develops a complete Power-to-Ammonia-to-Power (P2A2P) zero-carbon energy supply chain model using green ammonia as a hydrogen storage medium to transport abundant renewable energy from international exporters directly to energy-scarce Taiwan, supporting the 2050 net-zero emissions target.
Exporter hydrogen production analysis reveals significant long-term cost reductions for high-temperature Solid Oxide Electrolyzer Cells (SOEC). While SOEC capital costs exceeded 2,200 $/kW in 2020, automated mass production is projected to drive costs down to 600 $/kW by 2040 and 500 $/kW by 2050. This decline validates using 750 $/kW as a reasonable calculation basis in this study. Furthermore, an Air Separation Unit (ASU) is integrated to supply the required nitrogen. Process optimization shows that recycling ammonia synthesis waste heat to preheat electrolyzer steam, while balancing SOEC thermal demands, saves substantial electricity and raises the total supply chain Round-Trip Efficiency (RTE) to 33.13%.
Maritime transport evaluations show that liquefying ammonia at -34°C offers major advantages over liquid hydrogen at -253°C. Sensitivity analysis identifies a "U-shaped" relationship between shipping speed and delivered costs: sailing below 5 knots incurs heavy time and boil-off penalties, while exceeding 20 knots spikes fuel consumption due to water resistance. The model identifies 15 knots as the optimal shipping speed that minimizes total import costs for Taiwan.
GTCC power generation simulations using Aspen Plus show that an ammonia gas turbine combined cycle plant operating at 30 bar and 1750°C achieves a power generation efficiency of 60.54% and a stable output of 715 MW at the destination. To mitigate nitrogen oxide (NOx) emissions—which can spike to 100 times that of methane—the integration of Flue Gas Recirculation (FGR) and a 30-block Selective Catalytic Reduction (SCR) system successfully curtails exhaust NOx down to 9 ppm, meeting strict environmental standards.
Overall economic evaluation factoring in all construction and operating costs shows that under a baseline export green electricity price of 30 $/MWh, the final delivered cost of electricity generated in Taiwan converges at 223 $/MWh. This framework demonstrates strong financial resilience against potential international carbon taxes. These quantitative model outcomes prove the viability of the green ammonia import strategy, serving as a practical evaluation framework and a quantitative analysis perspective for Taiwan’s future 2050 green procurement and grid stability.
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dc.description.tableofcontentsCONTENTS
誌謝 i
中文摘要 ii
ABSTRACT iii
CONTENTS v
LIST OF FIGURES vii
LIST OF TABLES x
Chapter 1 Introduction 1
1.1 Background and motivation 1
1.2 Rationale for selecting ammonia as an energy carrier 2
Chapter 2 Methodology 7
2.1 Renewable energy exporters 7
2.1.1 Evaluation and selection of electrolyzer configurations 7
2.1.2 Hydrodynamic resistance and ship fuel consumption prediction models 10
2.2 Renewable energy importers 15
2.2.1 Ammonia physical and thermodynamic constraints 15
2.2.2 Ammonia combustion mechanism 17
2.2.3 Gas turbine combined cycle (GTCC) 21
Chapter 3 Process simulation 24
3.1 Air separation unit 24
3.1.1 Thermodynamics validation 24
3.1.2 Process simulation 26
3.1.3 ASU techno-economic analysis 30
3.2 Ammonia synthesis 36
3.2.1 Thermodynamic validation 36
3.2.2 Kinetic model 37
3.2.3 Process simulation 40
3.2.4 Waste heat recovery and process integration for SOEC 43
3.2.5 Synthesis techno-economic analysis 46
3.3 Ammonia-fueled gas turbine combined cycle (GTCC) 52
3.3.1 Thermodynamic & kinetic model 52
3.3.2 Process simulation 52
3.3.3 NOx emissions analysis and power generation 56
3.3.4 Selective catalytic reduction (SCR) for NOx emission control 62
3.3.5 Power generation sensitivity and operational strategy 67
3.3.6 GTCC techno-economic analysis 73
Chapter 4 Economic discussion 79
4.1 Techno-economic framework & boundary conditions 79
4.1.1 Boundary conditions and exporter electricity cost formulations 79
4.1.2 Capital and operational costing by process stage 82
4.1.3 Economic and sensitivity analysis of ammonia maritime shipping 84
4.2 Techno-economic metrics of the integrated P2A2P Supply Chain 89
4.2.1 Round-trip efficiency and terminal LCOE formulations 89
4.2.2 Sensitivity analysis 92
Chapter 5 Conclusion 99
Refferences 101

LIST OF FIGURES
Fig. 1 1 Evolution of energy sources toward a sustainable future 1
Fig. 1 2 Benchmarking physical properties of three key hydrogen carriers 4
Fig. 1 3 Supply chain of ammonia-fueled GTCC system. 5
Fig. 2 1 Model validation for fuel consumption 13
Fig. 2 2 contour map of ship fuel consumption (displacement vs. speed) 14
Fig. 2 3 Pressure-dependent laminar flame speeds of hydrogen-seeded ammonia flames. 16
Fig. 2 4 Comparison of flame propagation evolution and temporal development between pure NH3 and hydrogen-seeded ammonia mixtures. 17
Fig. 2 5 Schematic of NH3 combustion reaction mechanism. 19
Fig. 2 6 Integrated topping brayton and bottoming rankine cycles. 22
Fig. 2 7 GTCC with a reheat supercritical steam cycle 23
Fig. 3 1 Thermodynamic verification for ASU 25
Fig. 3 2 Design and simulation result of air separation unit. 29
Fig. 3 3 Distribution of equipment capital expenditure for the ASU 31
Fig. 3 4 Vapor-liquid equilibrium (P-xy) diagrams for the binary systems at various temperatures 37
Fig. 3 5 Validation of reaction kinetics. 40
Fig. 3 6 Design and simulation result of N2 hydrogenation process for NH₃ synthesis. 42
Fig. 3 7 Energy demand for the unintegrated baseline SOEC system. 44
Fig. 3 8 Energy savings through the proposed SOEC waste heat integration. 45
Fig. 3 9 Distribution of equipment capital expenditure for the synthesis 47
Fig. 3 10 Key technical issues in ammonia-based GTCC plants. 53
Fig. 3 11 Design and simulation result of gas turbine combined cycle (GTCC). 55
Fig. 3 12 NOx emission of various conventional and alternative fuels 56
Fig. 3 13 Baseline NOx emission characteristics without flue gas recirculation 58
Fig. 3 14 Integrated effects of air flow and FGR on combustion 60
Fig. 3 15 Schematic representation of the selective catalytic reduction (SCR) process 62
Fig. 3 16 Multi-scale structural design of the honeycomb catalyst bed. 64
Fig. 3 17 Impact of catalyst scaling on de-NOₓ performance. 66
Fig. 3 18 Sensitivity analysis of GTCC performance for pressure. 68
Fig. 3 19 Thermal efficiency contour map as a function of operating pressure and combustion temperature with the designated design point. 70
Fig. 3 20 Parametric sensitivity map of the levelized cost of electricity (LCOE). 71
Fig. 3 21 Distribution of equipment capital expenditure for the GTCC 74
Fig. 4 1 Levelized cost of renewable power generation from 1984 to 2024. 80
Fig. 4 2 Levelized cost of energy for renewable power generations in 2024 81
Fig. 4 3 Global average levelized cost of energy (LCOE) for newly commissioned renewable power generation technologies in 2024 ($/MWh). 82
Fig. 4 4 Effects of operating pressure on efficiency and LCOE at 1750°C. 84
Fig. 4 5 Shipping cost sensitivity analysis. 87
Fig. 4 6 Green ammonia-fueled international renewable energy supply chains. 90
Fig. 4 7 Supply-chain exergy destruction breakdown. 92
Fig. 4 8 Sensitivity analysis of imported electricity price as a function of exporter electricity cost. 93
Fig. 4 9 Sensitivity analysis of imported electricity price as a function of SOEC efficiency. 94
Fig. 4 10 Sensitivity analysis of imported electricity price as a function of SOEC unit cost. 94
Fig. 4 11 Sensitivity analysis of imported electricity price as a function of transport distance. 96
Fig. 4 12 Sensitivity analysis of imported electricity price as a function of unit cost of MeOH ship. 96
Fig. 4 13 Sensitivity analysis of imported electricity price as a function of speed of shipping. 97
Fig. 4 14 ensitivity analysis of imported electricity price as a function of plant life. 98
Fig. 4 15 Sensitivity analysis of imported electricity price as a function of interest. 98
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dc.language.isoen-
dc.subject綠氨-
dc.subject然氣渦輪複循環-
dc.subject固態氧化物電解槽-
dc.subjectGreen Ammonia-
dc.subjectGas Turbine Combined Cycle-
dc.subjectSolid Oxide Electrolyzer Cell-
dc.titleGTCC電廠綠色氨基電力供應鏈的技術經濟評估zh_TW
dc.titleTechno-Economic Assessment of a Green Ammonia-based Power Supply Chain for GTCC Plantsen
dc.typeThesis-
dc.date.schoolyear114-2-
dc.description.degree碩士-
dc.contributor.oralexamcommittee吳哲夫;李瑞元;王聰偉zh_TW
dc.contributor.oralexamcommitteeJeffrey D. Ward;Jui-Yuan Lee;Chong-Wei Ongen
dc.subject.keyword綠氨; 然氣渦輪複循環; 固態氧化物電解槽zh_TW
dc.subject.keywordGreen Ammonia; Gas Turbine Combined Cycle; Solid Oxide Electrolyzer Cellen
dc.relation.page104-
dc.identifier.doi10.6342/NTU202602204-
dc.rights.note同意授權(限校園內公開)-
dc.date.accepted2026-07-29-
dc.contributor.author-college工學院-
dc.contributor.author-dept化學工程學系-
dc.date.embargo-lift2031-07-24-
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