請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/102511完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 陳建彰 | zh_TW |
| dc.contributor.advisor | Jian-Zhang Chen | en |
| dc.contributor.author | 邱立大 | zh_TW |
| dc.contributor.author | Li-Da Chiu | en |
| dc.date.accessioned | 2026-07-08T16:14:05Z | - |
| dc.date.available | 2026-07-09 | - |
| dc.date.copyright | 2026-07-08 | - |
| dc.date.issued | 2026 | - |
| dc.date.submitted | 2026-06-29 | - |
| dc.identifier.citation | Chiu L-D, Yu S-E, Chueh C-C, Ni IC, Wu C-I, Cheng IC, et al. NiMoO4 Nanowires Supported on Stainless-Steel, Carbon, and Nickel Fiber Papers as Catalysts for the Oxygen Evolution Reaction in Anion Exchange Membrane Water Electrolysis. ACS Applied Nano Materials 2025;8(38):18446-57.
[2] Chiu L-D, Putra CL, Yu S-E, Cheng IC, Ni IC, Wu C-I, et al. Self-catalyzed NiFe foam anode fabricated via tape-casting for oxygen evolution reaction in anion exchange membrane water electrolysis. Fuel 2026;411:138060. [3] Guan D, Wang B, Zhang J, Shi R, Jiao K, Li L, et al. Hydrogen society: from present to future. Energy & Environmental Science 2023;16(11):4926-43. [4] Jordan KH, Jaramillo P, Karplus VJ, Adams PJ, Muller NZ. The Role of Hydrogen in Decarbonizing U.S. Iron and Steel Production. Environmental Science & Technology 2025;59(10):4915-25. [5] Stolten D, Emonts B. Hydrogen science and engineering, 2 volume set: materials, processes, systems, and technology. John Wiley & Sons; 2016. [6] Benblidia MA, Brik B, Esseghir M, Merghem-Boulahia L. Power Allocation and Energy Cost Minimization in Cloud Data Centers Microgrids: A Two-Stage Optimization Approach. IEEE Access 2022;10:66213-26. [7] Genovese M, Schlüter A, Scionti E, Piraino F, Corigliano O, Fragiacomo P. Power-to-hydrogen and hydrogen-to-X energy systems for the industry of the future in Europe. International Journal of Hydrogen Energy 2023;48(44):16545-68. [8] Balasubramanian V, Butti SK, Choudary NV, Parthasarathy R, Bhargava SK. Color-coded nomenclature of colorless hydrogen: which one is better? Chemical Communications 2025;61(80):15494-509. [9] Wang J, Wen J, Wang J, Yang B, Jiang L. Water electrolyzer operation scheduling for green hydrogen production: A review. Renewable and Sustainable Energy Reviews 2024;203:114779. [10] Zhang Y, Chen J, Han Y, Gong Z, Chen L, Wang X, et al. Electrolysis of Seawater and Salt-Lake Water for Hydrogen Production: A Review on Technical Challenges, Material Design, and Future Directions. Energy & Fuels 2026;40(8):4076-99. [11] Finger S, Fritsch B, Wu M, Lahn L, Hoffmeister D, Will J, et al. Degradation phenomena in PEMWE revealed by correlative electrochemical and nanostructure analysis. Energy & Environmental Science 2025;18(22):9877-94. [12] Wang Y, Pang Y, Xu H, Martinez A, Chen KS. PEM Fuel cell and electrolysis cell technologies and hydrogen infrastructure development – a review. Energy & Environmental Science 2022;15(6):2288-328. [13] Li Q, Kuang K, Sun Y, Zheng Y, Liu Q, Chan SH, et al. Deficiency of hydrogen production in commercialized planar Ni-YSZ/YSZ/LSM-YSZ steam electrolysis cells. International Journal of Hydrogen Energy 2022;47(56):23514-9. [14] Bi L, Boulfrad S, Traversa E. Steam electrolysis by solid oxide electrolysis cells (SOECs) with proton-conducting oxides. Chemical Society Reviews 2014;43(24):8255-70. [15] Du N, Roy C, Peach R, Turnbull M, Thiele S, Bock C. Anion-Exchange Membrane Water Electrolyzers. Chemical Reviews 2022;122(13):11830-95. [16] Tüysüz H. Alkaline Water Electrolysis for Green Hydrogen Production. Accounts of Chemical Research 2024;57(4):558-67. [17] Lv H, Pan Q, Song Y, Liu X-X, Liu T. A Review on Nano-/Microstructured Materials Constructed by Electrochemical Technologies for Supercapacitors. Nano-Micro Letters 2020;12(1):118. [18] Yu J, He Q, Yang G, Zhou W, Shao Z, Ni M. Recent advances and prospective in ruthenium-based materials for electrochemical water splitting. Acs Catalysis 2019;9(11):9973-10011. [19] Lazanas AC, Prodromidis MI. Electrochemical Impedance Spectroscopy─A Tutorial. ACS Measurement Science Au 2023;3(3):162-93. [20] Zhao Z, Zou Y, Liu P, Lai Z, Wen L, Jin Y. EIS equivalent circuit model prediction using interpretable machine learning and parameter identification using global optimization algorithms. Electrochimica Acta 2022;418:140350. [21] Morales DM, Risch M. Seven steps to reliable cyclic voltammetry measurements for the determination of double layer capacitance. Journal of Physics: Energy 2021;3(3):034013. [22] Kiniman V, Kanokwhale C, Boonto P, Pholauyphon W, Nantasaksiri K, Charoen-amornkitt P, et al. Modeling cyclic voltammetry responses of porous electrodes: An approach incorporating faradaic and non-faradaic contributions through porous model and constant phase element. Journal of Energy Storage 2024;83:110804. [23] Kang SY, Park JE, Jang GY, Kim O-H, Kwon OJ, Cho Y-H, et al. High-performance and durable water electrolysis using a highly conductive and stable anion-exchange membrane. International Journal of Hydrogen Energy 2022;47(15):9115-26. [24] Kraglund MR. Alkaline membrane water electrolysis with non-noble catalysts. 2017. [25] Lakhan MN, Hanan A, Hussain A, Ali Soomro I, Wang Y, Ahmed M, et al. Transition metal-based electrocatalysts for alkaline overall water splitting: advancements, challenges, and perspectives. Chemical Communications 2024;60(39):5104-35. [26] Hou L, Jang H, Gu X, Cui X, Tang J, Cho J, et al. Design strategies of ruthenium-based materials toward alkaline hydrogen evolution reaction. EcoEnergy 2023;1(1):16-44. [27] Xiong L, Qiu Y, Peng X, Liu Z, Chu PK. Electronic structural engineering of transition metal-based electrocatalysts for the hydrogen evolution reaction. Nano Energy 2022;104:107882. [28] Feng J, Sun X, Li Z, Hao X, Fan M, Ning P, et al. Plasma-Assisted Reforming of Methane. Advanced Science 2022;9(34):2203221. [29] Stenson EV, Horn-Stanja J, Stoneking MR, Pedersen TS. Debye length and plasma skin depth: two length scales of interest in the creation and diagnosis of laboratory pair plasmas. Journal of Plasma Physics 2017;83(1):595830106. [30] Fu Y, Zhang P, Verboncoeur JP, Wang X. Electrical breakdown from macro to micro/nano scales: a tutorial and a review of the state of the art. Plasma Research Express 2020;2(1):013001. [31] Babich L, Tat’yana VL. Generalized Paschen’s law for overvoltage conditions. IEEE Transactions on Plasma Science 2016;44(12):3243-8. [32] Ramos A, Rouboa A. Life cycle thinking of plasma gasification as a waste-to-energy tool: Review on environmental, economic and social aspects. Renewable and Sustainable Energy Reviews 2022;153:111762. [33] El-Sheekh MM, Abd Al-Halim MA, Mohammed SA. Algae processing by plasma discharge technology: A review. Algal Research 2023;70:102983. [34] Plasma Science and Technology. London: IntechOpen; 2016. [35] Wang Z, Chen J, Sun S, Huang Z, Zhang X, Li X, et al. Plasma-enabled synthesis and modification of advanced materials for electrochemical energy storage. Energy Storage Materials 2022;50:161-85. [36] Bertin M, Leitao EM, Bickerton S, Verbeek CJR. A review of polymer surface modification by cold plasmas toward bulk functionalization. Plasma Processes and Polymers 2024;21(5):2300208. [37] Qu J, Zeng M, Zhang D, Yang D, Wu X, Ren Q, et al. A review on recent advances and challenges of ionic wind produced by corona discharges with practical applications. Journal of Physics D: Applied Physics 2022;55(15):153002. [38] Farhadi M, Sohbatzadeh F. Influence of a transient spark plasma discharge on producing high molecular masses of chemical products from l-cysteine. Scientific Reports 2023;13(1):2059. [39] Gudmundsson JT, Hecimovic A. Foundations of DC plasma sources. Plasma Sources Science and Technology 2017;26(12):123001. [40] Chen F, Yan T-H, Bashir S, Liu JL. Chapter 2 - Synthesis of nanomaterials using top-down methods. In: Liu JL, Yan T-H, Bashir S, editors. Advanced Nanomaterials and Their Applications in Renewable Energy (Second Edition). Elsevier; 2022, p. 37-60. [41] Fan W, Sheng Z, Dong L, Liu F, Zhong X, Cui Y, et al. Formation of side discharges in dielectric barrier discharge. Scientific Reports 2017;7(1):8368. [42] Park S, Choe W, Moon SY, Shi JJ. Electron Information in Single- and Dual-Frequency Capacitive Discharges at Atmospheric Pressure. Scientific Reports 2018;8(1):7516. [43] Zhu H, Huang Y, Yin S, Zhang W. Microwave plasma setups for CO2 conversion: A mini-review. Green Energy and Resources 2024;2(1):100061. [44] Kawano T, Wang M-J, Andou Y. Surface Modification of a Regenerated Cellulose Film Using Low-Pressure Plasma Treatment with Various Reactive Gases. ACS Omega 2022;7(48):44085-92. [45] Huhtamäki T, Tian X, Korhonen JT, Ras RHA. Surface-wetting characterization using contact-angle measurements. Nature Protocols 2018;13(7):1521-38. [46] Deng Y, Peng C, Dai M, Lin D, Ali I, Alhewairini SS, et al. Recent development of super-wettable materials and their applications in oil-water separation. Journal of Cleaner Production 2020;266:121624. [47] Measurlabs, Contact angle measurement; Available from: https://measurlabs.com/methods/contact-angle-measurement/. [48] What Is X-ray Diffraction?; Available from: https://rigaku.com/products/x-ray-diffraction-and-scattering/xrd/learning/what-is-xrd. [49] Munir N, Hanif M, Dias DA, Abideen Z. The role of halophytic nanoparticles towards the remediation of degraded and saline agricultural lands. Environmental Science and Pollution Research 2021;28(43):60383-405. [50] Field Emission Scanning Electron Microscope; Available from: https://photon-center.com/en/service/chemical-fesem. [51] PHYSICAL ELECTRONICS, XPS Available from: https://www.phi.com/surface-analysis-techniques/xps-esca.html. [52] TORAY, X-ray Photoelectron Spectroscopy : XPS; Available from: https://www.toray-research.co.jp/en/technical-info/analysis/XPS.html. [53] Shen C, Zhou P, Guo D. Potential profile of electrolytic cell and influence of electrolyte resistance in three-electrode electrochemical testing. Electrochimica Acta 2025;530:146428. [54] Yu S-E, Wang Y-C, Tseng C-Y, Cheng IC, Chen J-Z. Characteristics of low-pressure-plasma-processed NiRu-MOFs/nickel foam for Hydrogen evolution reaction. Physica Scripta 2024;99(4):045605. [55] Al-Salihy A, Zhu Q, Hu J, Liang C, Radwan AB, Salah A, et al. Synergistic Effect of NiMoO4 Nanorods with Polyaniline for Efficient Electrochemical Water Splitting. ACS Applied Materials & Interfaces 2025;17(19):28199-210. [56] Qiao S, Rao C, Chen H, Xiong M, Xu Q, Ci S. Enhanced hydrogen production via catalytic water and urea oxidation in a hybrid acid-base electrolytic cell with NiFe-LDH/NiMoO4/NF. Journal of Alloys and Compounds 2024;1004:175823. [57] Silva VD, Raimundo RA, Simões TA, Loureiro FJA, Fagg DP, Morales MA, et al. Nonwoven Ni–NiO/carbon fibers for electrochemical water oxidation. International Journal of Hydrogen Energy 2021;46(5):3798-810. [58] Meng X, Yuan B, Liu Y, Zhao Z, Li K, Lin Y. Amorphous Fe–Mo–O Nanostructures for Catalytic Water Oxidation. ACS Applied Nano Materials 2022;5(7):9427-34. [59] Li M-X, Xiao B, Zhao Z-Y, Ma Y, Zhou Y-N, Zhang X-Y, et al. Morphology evolution regulation of dual-doped S, Fe-NiMoO4 microrods based on precipitation-dissolution equilibrium for oxygen evolution. Fuel 2023;336:126769. [60] Kumbhar VS, Lee W, Lee K. Self-assembly of NiMoO4 nanoparticles on the ordered NiCo2O4 ultra-thin nanoflakes core-shell electrode for high energy density supercapacitors and efficient oxygen evolution reaction. Ceramics International 2020;46(14):22837-45. [61] Chen C, Wang S, Luo X, Gao W, Huang G, Zeng Y, et al. Reduced ZnCo2O4@NiMoO4·H2O heterostructure electrodes with modulating oxygen vacancies for enhanced aqueous asymmetric supercapacitors. Journal of Power Sources 2019;409:112-22. [62] Ye C, Pan Z, Zhang Q, Yin F, Wang Y, Li Y, et al. Heterostructured metal oxides realized by quenching-induced structural transformation. Energy & Environmental Science 2024;17(1):332-43. [63] Yang Y, Ma Y, Sun C, Bu C, Yan Y, Li X. Porous NiMoO4@NiMn-LDH Core–Shell Nanocomposites Anchored on Nickel Foam: Application in Asymmetric Supercapacitors with a High Specific Capacitance. ACS Applied Energy Materials 2025;8(8):5110-22. [64] Zhou L, Zeng S, Zheng D, Zeng Y, Wang F, Xu W, et al. NiMoO4 nanowires supported on Ni/C nanosheets as high-performance cathode for stable aqueous rechargeable nickel-zinc battery. Chemical Engineering Journal 2020;400:125832. [65] Jiang T, Jiang X, Hnát J, Michalcova A, Biswas I, Reissner R, et al. One step electrochemical fabrication of high performance Ni@Fe-doped Ni(oxy)hydroxide anode for practical alkaline water electrolysis. Journal of Materials Chemistry A 2022;10(44):23863-73. [66] Wan L, Liu J, Li X, Zhang Y, Chen J, Du C, et al. Fabrication of core-shell NiMoO4@MoS2 nanorods for high-performance asymmetric hybrid supercapacitors. International Journal of Hydrogen Energy 2020;45(7):4521-33. [67] Hu Q, Kang C, Cao S, Zhou C, Liu Q. NiMoO4 nanosheets grown on MOF-derived leaf-like Co3O4 nanosheet arrays for high-performance supercapacitors. Journal of Alloys and Compounds 2021;883:160867. [68] Davidrichetson A, Thiruvengadam D, Nithiasri R, Santhosh Kumar K, Jayabharathi J. Highly Efficient Oxygen Vacancy-Enriched MD-NiMoO4: A Surface Reactivity Descriptor for Energy-Saving Green Hydrogen Generation. ACS Applied Energy Materials 2025;8(1):503-17. [69] Sadeghi E, Chamani S, Erdem E, Peighambardoust NS, Aydemir U. NiMo/CoMoO4 Heterostructure with Confined Oxygen Vacancy for Active and Durable Alkaline Hydrogen Evolution Reaction. ACS Applied Energy Materials 2023;6(14):7658-71. [70] Ma L, Zhang M, Wei Z, Meng X, Chen R, Qin M, et al. Cobalt oxide/cerium oxide/carbon heterostructure nanoflowers derived from CoCe-ZIF-67 as efficient electrocatalyst for oxygen evolution reaction. Ceramics International 2025;51(5):6244-52. [71] Panneerselvam P, Singh C, Jayaraj SK, Doulassiramane T, Padmanaban R, Samal AK, et al. Unveiling the impact of oxygen vacancies in engineered bimetallic oxides for enhanced oxygen evolution reaction: insights from experimental and theoretical approaches. Journal of Materials Chemistry A 2024;12(30):19149-67. [72] Yi T-F, Qiu L-Y, Mei J, Qi S-Y, Cui P, Luo S, et al. Porous spherical NiO@NiMoO4@PPy nanoarchitectures as advanced electrochemical pseudocapacitor materials. Science Bulletin 2020;65(7):546-56. [73] Zhang W, Shi Y, Li C, Jiang Y, Xiao W, Zhu S, et al. Composite-induced FeO(OH) phase transition as a highly efficient electrocatalyst for robust overall water splitting. Ceramics International 2024;50(11, Part B):20624-31. [74] Rajput A, Adak MK, Chakraborty B. Intrinsic Lability of NiMoO4 to Excel the Oxygen Evolution Reaction. Inorganic Chemistry 2022;61(29):11189-206. [75] Yu T, Xu Q, Chen J, Qian G, Zhuo X, Yang H, et al. Boosting urea-assisted water splitting by constructing sphere-flower-like NiSe2-NiMoO4 heterostructure. Chemical Engineering Journal 2022;449:137791. [76] Wang Z, Sun Y, Zhang Y, Wang X, Bai Q, Wang Y. Intrinsic electronegativity-driven design of high entropy perovskite oxide for efficient water splitting. Ceramics International 2025;51(14):19293-301. [77] Jeon SS, Kang PW, Klingenhof M, Lee H, Dionigi F, Strasser P. Active Surface Area and Intrinsic Catalytic Oxygen Evolution Reactivity of NiFe LDH at Reactive Electrode Potentials Using Capacitances. ACS Catalysis 2023;13(2):1186-96. [78] Yu X, Zhang M, Tong Y, Li C, Shi G. A Large-Scale Graphene–Bimetal Film Electrode with an Ultrahigh Mass Catalytic Activity for Durable Water Splitting. Advanced Energy Materials 2018;8(21):1800403. [79] Jiang J, Sun F, Zhou S, Hu W, Zhang H, Dong J, et al. Atomic-level insight into super-efficient electrocatalytic oxygen evolution on iron and vanadium co-doped nickel (oxy)hydroxide. Nature Communications 2018;9(1):2885. [80] Jiang T, Jiang X, Kyriakou V, Bouzek K, Liao H. Deep reconstruction of Ni–Al-based pre-catalysts for a highly efficient and durable anion-exchange membrane (AEM) electrolyzer. Journal of Materials Chemistry A 2023;11(47):26011-22. [81] Wang R, Ohashi M, Ishida M, Ito H. Water transport analysis during cathode dry operation of anion exchange membrane water electrolysis. International Journal of Hydrogen Energy 2022;47(97):40835-48. [82] Cho MK, Park H-Y, Lee HJ, Kim H-J, Lim A, Henkensmeier D, et al. Alkaline anion exchange membrane water electrolysis: Effects of electrolyte feed method and electrode binder content. Journal of Power Sources 2018;382:22-9. [83] Dürr RN, Maltoni P, Tian H, Jousselme B, Hammarström L, Edvinsson T. From NiMoO4 to γ-NiOOH: Detecting the Active Catalyst Phase by Time Resolved in Situ and Operando Raman Spectroscopy. ACS Nano 2021;15(8):13504-15. | - |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/102511 | - |
| dc.description.abstract | 陰離子交換膜水電解 (anion exchange membrane water electrolysis, AEMWE) 系統中，設計兼具高活性與長期穩定性的陽極材料仍為關鍵挑戰之一。其中，催化劑層 (catalyst layer, CL) 與多孔傳輸層 (porous transport layer, PTL) 的界面整合，對於電荷傳輸效率、界面電阻以及操作穩定性具決定性影響。因此，如何透過材料與結構設計優化CL/PTL界面耦合，成為提升AEMWE性能的重要研究方向。本研究採用水熱法於不同導電基板上原位成長NiMoO4奈米線，以碳紙 (carbon paper, CP)、不鏽鋼纖維紙 (stainless steel fiber paper, SSP) 及鎳纖維紙 (nickel fiber paper, NFP) 導電基板作為多孔傳輸層，製備無黏結劑之整合型CL/PTL電極。此結構不僅可避免傳統催化層中黏結劑引入之界面阻抗，同時提升電極導電性與機械穩定性。實驗結果表明，相較於CP與NFP基板，SSP提供了更有利的界面化學與電子結構環境。在水熱成長過程中，SSP中Fe元素的溶出與引入，促進NiMoO4奈米線的Ni3+比例，並有效調控氧缺陷濃度，同時維持Mo5+/Mo6+之適當比例，進而提升析氧反應 (oxygen evolution reaction, OER) 之催化活性。在AEMWE模組測試中，於70 °C且陰極濕式操作條件下，NiMoO4/SSP電極在2.0 V下達2.67 A cm-2之高電流密度；在陰極乾式 (Cathode-dry) 仍可維持1.83 A cm-2，顯著優於NiMoO4/CP與NiMoO4/NFP電極。60小時長時間測試電壓僅輕微上升，展現良好的操作穩定性。進一步的結構與表面分析結果指出，在長時間模組操作過程中Mo發生部分浸出，並誘發NiMoO4表面自發重構為具有高OER活性的γ-NiOOH相，此轉變被認為是提升長期催化性能的重要機制之一。總而言之，本研究證實透過基板工程 (substrate engineering) 策略，結合界面耦合強化與基板衍生元素摻雜效應，能有效提升AEMWE陽極之電催化性能與耐久性，為未來高效且穩定之水電解系統設計提供具體方向。 | zh_TW |
| dc.description.abstract | In anion exchange membrane water electrolysis (AEMWE), developing anodic materials with both high activity and long-term durability remains a key challenge, where the catalyst layer/porous transport layer (CL/PTL) interface critically governs charge transfer and stability. Herein, NiMoO4 nanowires were directly grown on carbon paper (CP), stainless steel fiber paper (SSP), and nickel fiber paper (NFP) via a hydrothermal method to construct binder-free integrated CL/PTL electrodes. This design eliminates binder-induced resistance and mechanical degradation, while enhancing conductivity and structural integrity. Among the substrates, SSP provides the most favorable interfacial environment. Fe species introduced during growth modulate the electronic structure of NiMoO4, increasing Ni3+ content, regulating oxygen vacancies, and maintaining a balanced Mo5+/Mo6+ ratio, thereby enhancing oxygen evolution reaction (OER) activity. In AEMWE testing, NiMoO₄/SSP achieves 2.67 A cm-2 at 2.0 V under wet cathode conditions at 70 °C and retains 1.83 A cm-2 under dry operation, outperforming CP and NFP counterparts. The system also exhibits stable operation over 60 h with minimal voltage increase. Post-analysis reveals partial Mo leaching and in situ reconstruction into an active γ-NiOOH phase, which contributes to sustained catalytic performance. Overall, this work highlights substrate engineering as an effective strategy to enhance both the activity and durability of AEMWE anodes by integrating interfacial coupling with substrate-induced modulation. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2026-07-08T16:14:05Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2026-07-08T16:14:05Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 致謝 i
摘要 ii Abstract iii 目次 iv 圖次 vii 表次 xii 第一章 緒論 1 1.1 前言 1 1.2 研究動機 2 1.3 論文大綱 3 第二章 文獻回顧與理論介紹 4 2.1 氫能科技 4 2.1.1 電解水產氫 4 2.1.2 水電解技術路線 9 2.2 電化學分析 18 2.2.1 電化學活性與反應動力學 18 2.2.2 電化學阻抗圖譜 22 2.2.3 循環伏安法與電化學活性比表面積 25 2.3 多孔傳輸層與膜電極製備 26 2.4 催化層與催化材料 29 2.4.1 貴金屬催化材料 31 2.4.2 非貴金屬催化材料 32 2.5 電漿製程技術 34 2.5.1 電漿原理 34 2.5.2 電漿之粒子碰撞 40 2.5.3 電漿放電方式 42 第三章 實驗流程與儀器設備 48 3.1 實驗化學藥品與設備清單 48 3.1.1 化學藥品與材料 48 3.1.2 實驗設備與分析儀器 50 3.2 製程設備 52 3.2.1 低壓電漿清洗機 52 3.3 材料分析儀器 53 3.3.1 水接觸角量測儀 53 3.3.2 X射線繞射儀 55 3.3.3 場發射掃描式電子顯微鏡 57 3.3.4 X射線光電子能譜儀 60 3.3.5 電化學工作站 63 3.3.6 陰離子交換膜水電解模組量測 64 3.4 實驗流程 65 3.4.1 基材之親水性預處理 65 3.4.2 基板上沉積NiMoO4奈米線製備CL/PTL整合型陽極 65 3.4.3 製備Ru/SSP陰極 66 3.4.4 陰離子交換膜水電解系統組裝與量測 66 第四章 結果與討論 68 4.1 水接觸角量測電極表面性質 68 4.2 材料晶體結構分析 69 4.3 表面形貌與元素組成分析 71 4.4 表面氧化態分析 73 4.5 電極之電化學分析 79 4.5.1 線性掃描伏安法與塔弗斜率計算 79 4.5.2 電化學阻抗圖分析 81 4.5.3 循環伏安法與電雙層電容 81 4.6 陰離子交換膜水電解模組測試 83 4.6.1 極化曲線性能測試 84 4.6.2 長時間穩定性測試 88 第五章 結論 93 第六章 附錄：以薄帶成型法創新製備自催化鎳鐵泡沫應用於陰離子交換膜水電解之析氧反應 94 6.1 摘要 94 6.2 實驗步驟 94 6.3 結果與討論 96 6.3.1 材料分析 96 6.3.2 電化學分析 100 6.3.3 AEMWE模組性能評估 101 6.4 結論 105 個人期刊發表 106 參考文獻 107 | - |
| dc.language.iso | zh_TW | - |
| dc.subject | 析氧反應 | - |
| dc.subject | 陰離子交換膜水電解 | - |
| dc.subject | 奈米線 | - |
| dc.subject | 鎳鉬氧化物 | - |
| dc.subject | 電催化 | - |
| dc.subject | 薄膜 | - |
| dc.subject | Oxygen evolution reaction | - |
| dc.subject | Anion exchange membrane water electrolysis | - |
| dc.subject | Nanowires | - |
| dc.subject | NiMoO4 | - |
| dc.subject | Electrocatalysis | - |
| dc.subject | Thin film | - |
| dc.title | 基板誘導之鎳鉬氧化物奈米線電子調控於陰離子交換膜水電解析氧反應之研究 | zh_TW |
| dc.title | Substrate-Induced Electronic Modulation of NiMoO4 Nanowires for Oxygen Evolution Reaction in Anion Exchange Membrane Water Electrolysis | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 114-2 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 陳奕君;陳志鴻;李昭仁 | zh_TW |
| dc.contributor.oralexamcommittee | I-Chun Cheng;Chih-Hung Chen;Chao-Jen Li | en |
| dc.subject.keyword | 析氧反應; 陰離子交換膜水電解; 奈米線; 鎳鉬氧化物; 電催化; 薄膜 | zh_TW |
| dc.subject.keyword | Oxygen evolution reaction; Anion exchange membrane water electrolysis; Nanowires; NiMoO4; Electrocatalysis; Thin film | en |
| dc.relation.page | 113 | - |
| dc.identifier.doi | 10.6342/NTU202601485 | - |
| dc.rights.note | 同意授權(全球公開) | - |
| dc.date.accepted | 2026-06-30 | - |
| dc.contributor.author-college | 重點科技研究學院 | - |
| dc.contributor.author-dept | 奈米工程與科學學位學程 | - |
| dc.date.embargo-lift | 2026-07-09 | - |
| 顯示於系所單位： | 奈米工程與科學學位學程 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-114-2.pdf | 12.89 MB | Adobe PDF | 檢視/開啟 |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。