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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/101700完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 柯淳涵 | zh_TW |
| dc.contributor.advisor | Chun-Han Ko | en |
| dc.contributor.author | 吳玠融 | zh_TW |
| dc.contributor.author | Jie-Rong Wu | en |
| dc.date.accessioned | 2026-02-26T16:49:28Z | - |
| dc.date.available | 2026-02-27 | - |
| dc.date.copyright | 2026-02-26 | - |
| dc.date.issued | 2026 | - |
| dc.date.submitted | 2026-02-05 | - |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/101700 | - |
| dc.description.abstract | 本研究藉由熱重分析 (Thermogravimetric Analyzer, TGA)、傅立葉轉換紅外光譜 (Fourier-transform infrared spectroscopy, FT-IR) 與圓錐量熱儀 (Cone Calorimeter) 探討環氧樹脂 (Epoxy resin, EP) 在添加聚磷酸銨 (Ammonium Polyphosphate, APP) 與柳杉木粉 (Wood flour, WF) 後的熱穩定性與燃燒行為。TGA 結果顯示，單獨添加 APP 能有效提升殘留炭量，而加入 WF 雖在高溫階段能成炭提高殘重但缺乏結構支撐炭層；當同時添加 APP 與 WF 時，其殘留重量優於單一添加，顯示出良好的協同效應。
FT-IR 光譜分析中觀察到添加 APP 後於高溫下形成 O-P-O 與 P-O-C 等結構，有助於生成穩定的磷含炭層，添加 WF 則保留芳香環訊號，顯示其部分結構參與炭化反應。Cone Calorimeter 結果驗證阻燃性能的提升，APP 有效降低熱釋放速率 (HRR) 與總熱釋放量 (THR)，而 WF 的加入則在延遲熱釋放與形成炭層方面提供額外貢獻。 | zh_TW |
| dc.description.abstract | This study investigates the thermal stability and combustion behavior of epoxy resin (EP) after the incorporation of ammonium polyphosphate (APP) and wood flour (WF) using thermogravimetric analysis (TGA), Fourier-transform infrared spectroscopy (FT-IR), and a cone calorimeter.
The TGA results indicate that the addition of APP alone effectively increases the residual char yield, while the incorporation of WF promotes char formation at high temperatures and enhances the residual mass, albeit without forming a structurally robust char layer. When APP and WF are added simultaneously, the residual weight is higher than that obtained with either additive alone, demonstrating a pronounced synergistic effect. FT-IR spectral analysis reveals that the presence of APP leads to the formation of O-P-O and P-O-C structures at elevated temperatures, which contributes to the generation of a stable phosphorus-containing char layer. In contrast, samples containing WF retain signals associated with aromatic rings, indicating that portions of the WF structure participate in the carbonization process. Cone calorimeter results further confirm the improvement in flame-retardant performance. APP significantly reduces the heat release rate (HRR) and total heat release (THR), while the addition of WF provides additional contributions by delaying heat release and promoting char layer formation. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2026-02-26T16:49:28Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2026-02-26T16:49:28Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 口試委員會審定書 I
誌謝 II 摘要 III Abstract IV 目次 V 圖次 VIII 表次 X 第1章 前言 1 第2章 文獻回顧 2 2.1、 燃燒行為 2 2.1.1 熱裂解和可燃性 2 2.1.2 聚合物複合材料的火災行為和可燃性 2 2.1.3 木質材料燃燒行為 2 2.1.4 木質材料熱反應性 3 2.2、 環氧樹脂 5 2.2.1 雙酚 A 二縮水甘油醚 (DGEBA) 6 2.2.2 DGEBA 環氧樹脂之熱性質 7 2.3、 阻燃劑 8 2.3.1 添加型阻燃劑 8 2.3.2 反應性阻燃劑 9 2.3.3 阻燃劑-酸源 9 2.3.4 阻燃劑-炭化劑 9 2.4、 添加型阻燃劑-磷系阻燃劑 10 2.4.1 聚磷酸銨 (Ammonium Polyphosphate, APP) 10 2.4.2 聚磷酸銨與纖維材料作用 10 2.4.3 聚磷酸銨與環氧樹脂作用 11 2.5、 熱重分析 11 2.6、 傅立葉轉換紅外線光譜儀 (Fourier-Transform Infrared Spectrometer, FT-IR) 12 2.7、 圓錐量熱儀 (Cone Calorimeter) 13 2.8、 CNS 14705-1 A3386-1 16 第3章 材料與方法 18 3.1、 實驗設計 18 3.2、 試驗材料 19 3.2.1 實驗材料 19 3.2.2 塗料製備 19 3.3、 試驗設備 21 3.4、 固形分 Solid content 22 3.5、 熱重分析 (Thermogravimetric analysis of materials, TGA) 22 3.6、 活化能 (Activation energy) 22 3.6.1 Kissinger 方法 23 3.6.2 Flynn-Wall-Ozawa 方法 23 3.7、 高溫爐受熱試驗 24 3.8、 官能基測定 (傅立葉轉換紅外光譜, FT-IR) 24 3.9、 燃燒模擬試驗 (圓錐量熱儀, Cone Calorimeter) 24 第4章 結果與討論 25 4.1、 熱重分析 (Thermogravimetric analysis of materials) 25 4.1.1 環氧樹脂添加不同比例木粉之熱重分析 27 4.1.2 環氧樹脂添加不同比例聚磷酸銨之熱重分析 28 4.1.3 環氧樹脂添加聚磷酸銨與木粉之熱重分析 29 4.2、 活化能計算 31 4.2.1 Kissinger 31 4.2.2 Flynn-Wall-Ozawa 40 4.3、 高溫爐受熱試驗 44 4.4、 ATR-FTIR 45 4.5、 圓錐量熱儀 (Cone Calorimeter) 49 4.5.1 熱釋放速率 (Heat release rate, HRR) 和總熱釋放量 (Total heat released, THR) 50 4.5.2 有效熱釋放 (Effective Heat of Combustion, EHC) 56 4.5.3 總煙霧釋放量 (Total Smoke Release, TSR) 57 第5章 結論 60 第6章 參考文獻 61 | - |
| dc.language.iso | zh_TW | - |
| dc.subject | 熱重分析儀 | - |
| dc.subject | 傅立葉轉換紅外光譜 | - |
| dc.subject | 圓錐量熱儀 | - |
| dc.subject | 環氧樹脂 | - |
| dc.subject | 聚磷酸銨 | - |
| dc.subject | Thermogravimetric Analyzer | - |
| dc.subject | Fourier-transform infrared spectroscopy | - |
| dc.subject | Cone Calorimeter | - |
| dc.subject | Epoxy resin | - |
| dc.subject | Ammonium Polyphosphate | - |
| dc.title | 木粉及聚磷酸銨作為環氧樹脂阻燃塗料配方之應用 | zh_TW |
| dc.title | Application of Wood Flour and Ammonia Polyphosphate in Epoxy Flame-Retardant Coating Formulation | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 114-1 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 藍浩繁;張芳志;莊智勝 | zh_TW |
| dc.contributor.oralexamcommittee | Haw-Farn Lan;Fang-Chih Chang;Chih-Shen Chuang | en |
| dc.subject.keyword | 熱重分析儀,傅立葉轉換紅外光譜圓錐量熱儀環氧樹脂聚磷酸銨 | zh_TW |
| dc.subject.keyword | Thermogravimetric Analyzer,Fourier-transform infrared spectroscopyCone CalorimeterEpoxy resinAmmonium Polyphosphate | en |
| dc.relation.page | 67 | - |
| dc.identifier.doi | 10.6342/NTU202504395 | - |
| dc.rights.note | 同意授權(全球公開) | - |
| dc.date.accepted | 2026-02-08 | - |
| dc.contributor.author-college | 生物資源暨農學院 | - |
| dc.contributor.author-dept | 森林環境暨資源學系 | - |
| dc.date.embargo-lift | 2031-01-26 | - |
| 顯示於系所單位： | 森林環境暨資源學系 | |
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