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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 林金福(King-Fu Lin) | |
| dc.contributor.author | Chun-Hua Tseng | en |
| dc.contributor.author | 曾俊華 | zh_TW |
| dc.date.accessioned | 2021-05-20T20:59:13Z | - |
| dc.date.available | 2016-07-28 | |
| dc.date.available | 2021-05-20T20:59:13Z | - |
| dc.date.copyright | 2011-07-28 | |
| dc.date.issued | 2011 | |
| dc.date.submitted | 2011-07-25 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/10062 | - |
| dc.description.abstract | 本研究在於探討吡啶配位基上帶有不同羧基數的釕金屬錯合物染料分子(編號Ru-1A、Ru-11A、Ru-2A、Ru-3A、N3)的吸附行為與光伏效能。首先以NMR、FTIR鑑定染料的結構，並用UV-VIS的光譜測定染料的光學性質。由染料的MLCT吸收峰可以得知，當染料上帶有單邊羧基時會造成吸收峰有藍位移的現象。同時利用AFM、TEM、DLS觀察五種染料的吸附行為，可以發現染料會先形成較大的微胞顆粒在TiO2表面沉降，長時間後皆可均勻覆蓋TiO2表面。接著經由染料的吸附/脫附測試可以得知N3因吡啶配位基帶有四個羧基，容易平躺於TiO2，故單一分子表面積最大，吸附量最小。而其他染料則帶有單邊的羧基，因此會以某個角度吸附於TiO2，投影面積小，因此有較大的吸附量。最後將染料應用於染料敏化太陽能電池元件上，發現N3，Ru-3A，Ru-2A，Ru-11A，Ru-1A 染料的轉換效率分別為7.53%，6.72%，6.08%，4.20%，3.39%，Jsc為19.6mA、17.9mA、14.9mA、10.8mA、6.59mA，隨著染料上的羧基數目減少，轉換效率與Jsc有明顯下降的趨勢。此結果也可經由IPCE來支持。交流阻抗分析、IMVS、IMPS、電量收集分析中亦可以得到當染料上的羧基數目減少時，電子生命週期及流出的電量皆有下降的趨勢。 | zh_TW |
| dc.description.abstract | In this study, we compared the adsorption properties and photovoltaic performance among five ruthenium complex dyes having different number of carboxyl groups, denoted as Ru-1A, Ru-11A, Ru-2A, Ru-3A and N3, which have one, two, two, three and four carboxylic groups, respectively.
First, the dyes were characterized by NMR and FTIR. And their optical properties in ACN/t-BuOH solution were studied by UV-VIS spectrascopy. From the UV-Vis spectra, the MLCT absorption peak of the dyes blue-shifts with decreasing the number of carboxylic groups. The adsorption mechanism of the dyes were studied by TEM, DLS, AFM and adsorption/desorption test, which can be concluded by the following results: (1) The dye molecules in the solutions tend to form micelles, which deposited on TiO2 surface in micelle form; with increasing time, the dye molecules lead to a homogeneous surface with an approxmate height of one molecule. (2)Due to N3 had four carboxylic groups, it easily lied in flat form on the TiO2 surface,and thus has the smallest adsorption amount. Other dyes containing one-side carboxyl groups would attach to the TiO2 surface with a tilt and have larger adsorption amount. For the performance of DSSCs with MPN liquid electrolyte, N3, Ru-3A, Ru-2A, Ru-11A, Ru-1A attained power conversion efficiency of 7.53%, 6.72%, 6.08%, 4.20%, 3.39%, and the Jsc were 19.6mA, 17.9mA, 14.9mA, 10.8mA, 6.59mA with decreasing the number o f carboxyl groups. The IPCE, EIS, IMVS, IMPS, Voltage-decay tests also supported the results of Jsc and efficiency. | en |
| dc.description.provenance | Made available in DSpace on 2021-05-20T20:59:13Z (GMT). No. of bitstreams: 1 ntu-100-R98527021-1.pdf: 5401584 bytes, checksum: 2895f82f81d6efd9d9cc417ef60c229c (MD5) Previous issue date: 2011 | en |
| dc.description.tableofcontents | 中文摘要............................................................................................................ .I
英文摘要.............................................................................................................II 目錄…………………………………………………………...………………...III 圖目錄………………………………………………………………………..VII 表目錄………………………………………………………………………..XII 第一章 緒論 1 1-1 前言 1 1-2 太陽能電池簡介 2 1-2-1 矽系太陽能電池 2 1-2-2 化合物系太陽能電池 2 1-2-3 有機系太陽能電池 3 1-2-4 染料敏化太陽能電池的發展 4 1-3 文獻回顧 6 1-3-1 染料敏化太陽能電池的工作原理 6 1-3-2 透明導電玻璃 7 1-3-3 半導體薄膜電極 8 1-3-4 光敏劑 9 1-3-5 電解質 15 1-3-6 對電極 16 1-4 太陽能電池的評價 17 1-4-1 太陽光模擬光源 17 1-4-2 太陽能電池光電轉換效率的計算 18 1-4-3 單一波長的光電轉換效率 20 1-4-4 IMVS 20 1-4-5 IMPS 22 1-4-6 Open-circuit potential decay transients and charge extration measurement 23 1-5 研究目的 24 第二章 實驗設備與方法 28 2-1 實驗藥品 28 2-2 儀器設備 29 2-3 合成方法 31 2-3-1 Ligand 的合成 31 2-3-2 染料的合成 32 2-3-3 MPII離子液體之合成 33 2-4 樣品製備 37 2-4-1 核磁共振儀之樣品製備 37 2-4-2 紅外線光譜儀之樣品製備 37 2-4-3 紫外光/可見光吸收光譜儀樣品的製備 37 2-4-4 觀察染料奈米結構試片的製備 38 2-4-5 液態電解質的製備 39 2-4-6 二氧化鈦鍍液的製備 39 2-5 導電玻璃的清洗 39 2-5-1 FTO(F-doped tin oxide)玻璃清洗 39 2-5-2 ITO(Indium Tin Oxide)玻璃的清洗 40 2-6 電極的製備 40 2-6-1 二氧化鈦工作電極的製備 40 2-6-2 白金對電極的製備 40 2-7 元件組合 41 2-8 太陽能電池光電化學測試 41 2-8-1 光電流-電壓特徵曲線 41 2-8-2 交流阻抗分析 41 2-8-3 入射光子-電流轉換效率(IPCE) 42 2-8-4 IMVS與IMPS之量測 42 2-8-5 Voltage decay-charge extraction 實驗之量測 42 第三章 結果與討論 44 3-1 染料結構和性質鑑定 44 3-1-1 Ru-3A 結構和性質鑑定 44 3-1-2 Ru-2A 結構和性質鑑定 45 3-1-3 Ru-11A結構和性質鑑定 46 3-1-4 Ru-1A結構和性質鑑定 47 3-1-5 綜合討論 49 3-2 染料在ACN/t-BuOH溶劑中奈米結構探討 49 3-3 染料在燒結二氧化鈦上吸附之奈米結構探討 51 3-3-1 N3在燒結二氧化鈦上吸附之奈米結構 51 3-3-2 Ru-3A在燒結二氧化鈦上吸附之奈米結構 52 3-3-3 Ru-2A在燒結二氧化鈦上吸附之奈米結構 53 3-3-4 Ru-11A在燒結二氧化鈦上吸附之奈米結構 54 3-3-5 Ru-1A在燒結二氧化鈦上吸附之奈米結構 55 3-3-6 綜合討論 55 3-4 染料在燒結二氧化鈦上吸附量探討 56 3-4-1 染料吸附量對時間的關係 56 3-4-2 染料吸附角度的相對關係 57 3-5 染料應用於染料敏化太陽能電池之元件表現 58 3-5-1 光電轉換效率 58 3-5-2 單色光轉換效率IPCE 59 3-5-3 交流阻抗分析 60 3-5-4 IMPS、IMVS 61 3-5-5 Voltage decay-charge extraction實驗 61 第四章 結論 64 第五章 參考文獻 66 | |
| dc.language.iso | zh-TW | |
| dc.title | 含不同羧基數釕金屬錯合物染料之性質及光伏效能研究 | zh_TW |
| dc.title | Studies on Properties and Photovotaic Performance of Ruthenium Complex Dyes Having Different Number of Carboxyl Groups | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 99-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 何國川(Kuo-Chuan Ho),趙基揚 | |
| dc.subject.keyword | 染料敏化太陽能電池,釕金屬錯合物染料,羧基數,奈米結構,短路電流, | zh_TW |
| dc.subject.keyword | DSSC,Ruthenium complex dye,Number of carboxyl group,Nanostructure,Short-circuit current, | en |
| dc.relation.page | 117 | |
| dc.rights.note | 同意授權(全球公開) | |
| dc.date.accepted | 2011-07-25 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 材料科學與工程學系 | |
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