請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/10013
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 錢義隆 | |
dc.contributor.author | Chung-Han Lee | en |
dc.contributor.author | 李宗翰 | zh_TW |
dc.date.accessioned | 2021-05-20T20:55:45Z | - |
dc.date.available | 2014-08-11 | |
dc.date.available | 2021-05-20T20:55:45Z | - |
dc.date.copyright | 2011-08-11 | |
dc.date.issued | 2011 | |
dc.date.submitted | 2011-07-29 | |
dc.identifier.citation | 參考文獻
[中文] (1) 何瑞鴻,[理想系統之反應性分隔內壁蒸餾塔設計與節能研究], 國立台灣大學化學工程研究所碩士論文(2009) (2) 許智鈞,[乙酸甲酯水解反應之反應性分隔內壁蒸餾塔架構設計與 控制],國立台灣大學化學工程研究所碩士論文(2008) [英文] [1] Al-Arfaj, M.; Luyben, W. L., Comparison of alternative control structures for an ideal two-product reactive distillation column. Ind. Eng. Chem. Res. 2000, 39, (9), 3298-3307. [2] Al-Arfaj, M. A.; Luyben, W. L., Control study of ethyl tert-butyl ether reactive distillation. Ind. Eng. Chem. Res. 2002, 41, (16), 3784-3796. [3] Amminudin, K. A.; Smith, R., Design and optimization of fully thermally coupled distillation columns part 2: Application of dividing wall columns in retrofit. Chem. Eng. Res. Des. 2001, 79, (A7), 716-724. [4] Barbosa, D.; Doherty, M. F., The Simple Distillation of Homogeneous Reactive Mixtures. Chem. Eng. Sci. 1988, 43, (3), 541-550. [5] Barroso-Munoz, F. O.; Hernandez, S.; Segovia-Hernandez, J. G.; Hernandez-Escoto, H.; Aguilera-Alvarado, A. F., Thermally coupled distillation systems: Study of an energy-efficient reactive case. Chem. Biochem. Eng. Q. 2007, 21, (2), 115-120. [6] Ciric, A. R.; Miao, P. Z., Steady-State Multiplicities in an Ethylene-Glycol Reactive Distillation Column. Ind. Eng. Chem. Res. 1994, 33, (11), 2738-2748. [7] Doherty, M. F.; Buzad, G., Reactive Distillation by Design. Chem. Eng. Res. Des. 1992, 70, (A5), 448-458 [8] Fidkowski, Z.; Krolikowski, L., Minimum Energy-Requirements of Thermally Coupled Distillation Systems. AIChE J. 1987, 33, (4), 643-653. [9] Gangadwala, J.; Mankar, S.; Mahajani, S.; Kienle, A.; Stein, E., Esterification of Acetic Acid with Butanol in the Presence of Ion-exchange Resins as Catalysts, Ind. Eng. Chem. Res., 42, 2146-2155 (2003). [10] Hauan, S.; Hertzberg, T.; Lien, K. M., Why Methyl Tert-Butyl Ether Production by Reactive Distillation May Yield Multiple Solutions. Ind. Eng. Chem. Res. 1995, 34, (3), 987-991. [11] Hernandez, S.; Sandoval-Vergara, R.; Barroso-Munoz, F. O.; Murrieta-Duenas, R.; Hernandez-Escoto, H.; Segovia-Hernandez, J. G.; Rico-Ramirez, V., Reactive dividing wall distillation columns: Simulation and implementation in a pilot plant. Chem. Eng. Process 2009, 48, (1), 250-258. [12] Jacobs, R.; Krishna, R., Multiple Solutions in Reactive Distillation for Methyl Tert-Butyl Ether Synthesis. Ind. Eng. Chem. Res. 1993, 32, (8), 1706-1709. [13] Kim, Y. H., Rigorous design of extended fully thermally coupled distillation columns. Chem. Eng. J. 2002, 89, (1-3), 89-99. [14] Kim, Y. H., Structural design and operation of a fully thermally coupled distillation column. Chem. Eng. J. 2002, 85, (2-3), 289-301. [15] Lee, M. J.; Wu, H. T.; Kang, C. H.; Lin, H. M., Kinetic Behavior of Amyl Acetate Synthesis Catalyzed by Acidic Cation Exchange Resin, J. Chin. Inst. Chem. Eng., 30,117-122 (1999). [16] Lee, H. Y.; Yen, L. T.; Chien, I. L.; Huang H. P., Reactive Distillation for Esterification of an Alcohol Mixture Containing n-Butanol and n-Amyl Alcohol. Ind. Eng. Chem. Res. 2009, 48, 7186–7204 [17] Lin, L. C.; Cheng, J. K.; Yu, C. C., Use of Excess Reactant for the Design of Reactive Distillation. AIChE J. 2008 (submitted) [18] Ling, H.; Luyben, W. L., New Control Structure for Divided-Wall Columns. Ind. Eng. Chem. Res. 2009, 48, 6034–6049 [19] Ling, H.; Luyben, W. L., Temperature Control of the BTX Divided-Wall Column. Ind. Eng. Chem. Res. 2009, 48, 6034–6049 [20] Malone, M. F.; Doherty, M. F., Reactive distillation. Ind. Eng. Chem. Res. 2000, 39, (11), 3953-3957. [21] Mueller, I.; Kenig, E. Y., Reactive distillation in a dividing wall column: Rate-based modeling and simulation. Ind. Eng. Chem. Res. 2007, 46, (11), 3709-3719. [22] Mueller, I.; Pech, C.; Bhatia, D.; Kenig, E. Y., Rate-based analysis of reactive distillation sequences with different degrees of integration. Chem. Eng. Sci. 2007, 62, (24), 7327-7335. [23] Mutalib, M. I. A.; Zeglam, A. O.; Smith, R., Operation and control of dividing wall distillation columns - Part 2: Simulation and pilot plant studies using temperature control. Chem. Eng. Res. . Des. 1998, 76, (A3), 319-334. [24] Nijhuis, S. A.; Kerkhof, F. P. J. M.; Mak, A. N. S., Multiple Steady-States during Reactive Distillation of Methyl Tert-Butyl Ether. Ind. Eng. Chem. Res. 1993, 32, (11), 2767-2774. [25] Okasinski, M. J.; Doherty, M. F., Thermodynamic behavior of reactive azeotropes. AIChE J. 1997, 43, (9), 2227-2238. [26] Petlyuk, F. B.; Platonov, V. M.; Slavinsk.Dm, Thermodynamically Optimal Method for Separating Multicomponent Mixtures. Int. Chem. Eng. 1965, 5, (3), 555-&. [27] Sander, S.; Flisch, C.; Geissier, E.; SchoenmakerS, H.; Ryll, O.; Hasse, H., Methyl acetate hydrolysis in a reactive divided wall column. Chem. Eng. Res. Des. 2007, 85, (A1), 149-154. [28] Schmitt, M.; Hasse, H., Phase Equlibria for Hexyl Acetate Reactive Distillation. J. Chem. Eng. Data. 2005, 50, 1677-1683 [29] Schmitt, M.; Hasse, H., Chemical Equilibrium and Reaction Kinetics of Heterogeneously Catalyzed n-Hexyl Acetate Esterification. Ind. Eng. Chem. Res. 2006, 45, 4123-4132 [30] Sotudeh, N.; Shahraki, B. H., A method for the design of divided wall columns. Chem. Eng. Technol. 2007, 30, (9), 1284-1291. [31] Sotudeh, N.; Shahraki, B. H., Extension of a method for the design of divided wall columns. Chem. Eng. Technol. 2008, 31, (1), 83-86. [32] Triantafyllou, C.; Smith, R., The Design and Optimization of Fully Thermally Coupled Distillation-Columns. Chem. Eng. Res. Des. 1992, 70, (2), 118-132. [33] Tung, S. T.; Yu, C. C., Effects of relative volatility ranking to the design of reactive distillation. AIChE J. 2007, 53, (5), 1278-1297. [34] Wang, S. J.; Wong, D. S. H., Controllability and energy efficiency of a high-purity divided wall column. Chem. Eng. Sci. 2007, 62, (4), 1010-1025. [35] Wang, S. J.; Wong, D. S. H.; Yu, S. W., Design and control of transesterification reactive distillation with thermal coupling. Comput. Chem. Eng. 2008, 32, (12), 3030-3037. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/10013 | - |
dc.description.abstract | 反應性分隔內壁蒸餾塔(RDWC)之研究文獻到目前為止所見不多,
但以現有已發表的文獻來看, 在設計反應性分隔內壁蒸餾塔前, 須先針對原有的反應蒸餾系統(RD system)架構設計去做研究後, 再進一步去進行熱整合, 才能有效地利用反應性分隔內壁蒸餾塔之設計來達到節能之目的。 本研究主要參考Lee 等人[16]針對混合丁、戊醇酯化反應製程以 「先酯化反應, 後分離產物」之概念做設計所提出之兩種架構直接序列設計和間接序列設計- 「水相回流」,作反應性分隔內壁蒸餾塔之設計,藉由程序最小年總成本(TAC)的計算以獲得最適設計的架構,並比較此兩種架構對於混合正丁、戊醇酯化系統及混合戊、己醇酯化系統之優劣, 其結果顯示在混合正丁、戊醇酯化系統中, 直接序列設計由於乙酸與乙酸丁酯難以分離之緣故, 因此為了顧及塔底乙酸之規格而耗費大量之精餾板數,使得間接序列設計-「水相回流」之架構較具競爭性;但在混合戊、己醇酯化系統中, 排除了乙酸與乙酸丁酯難以分離之限制, 所以塔底不需耗費大量之精餾板數使乙酸達至規格, 雖然直接序列設計於反應蒸餾塔塔底因產生兩個酯類而有再混合效應產生, 但可藉由反應性分隔內壁蒸餾塔之設計, 而更具競爭性。 接著在動態模擬方面, 針對混合正戊、己醇酯化系統直接序列設計整合後之架構作動態模擬之分析, 由於在選取控制點上, 受到了開環路靈敏度之限制, 使得擾動結果在產品規格上有些許偏差。另外,在增加進料流量之擾動下, 有轉化率不足之現象, 導致產品規格受到影響, 但在最後擾動測試之結果, 僅有少部分擾動產品規格偏差較大外, 其餘擾動測試結果皆僅有0.1mol%左右的偏差。 | zh_TW |
dc.description.abstract | There are little amounts of literatures related to reactive dividing wall column(RDWC) to date. But from the already published literatures, before designing a reactive
dividing wall column, a configuration with reactive distillation system(RD system) needs to be studied, then thermally integrating the system. It will help in efficiently using the reactive dividing wall column to bring about a saving in energy.This research is based on the work of Lee et al.[16] which focuses on the esterification of alcohol mixtures of butanol and pentanol, using the concept of reaction first then separation. There are two types of configurations in which are direct sequence and indirect sequence–aqueous reflux in their work. We not only use the above as the foundation of the reactive dividing wall column design, but also minimize the total annual cost (TAC) to find the optimum design. Comparison of the pros and cons between the two configuration of esterification of butanol and pentanol system and esterification of pentanol and hexanol system has been conducted. The results show that in the esterification of pentanol and hexanol system that the separation of acetic acid and butyl acetate is hard to separate in the direct system, in order to maintain the product specification of acetic acid in the bottoms requires a lot of trays. Therefore the indirect sequence-aqua phase reflux is more competitive. But in the esterification of pentanol and hexanol system, ignoring the problem relating to the limit in separation of acetic acid and butyl acetate, so the column doesn’t need that much amount of trays to maintain the product specifications. Even though the direct sequence has a remixing effect of the two esters in the bottom of the reactive distillation column, using a reactive dividing wall column design is more competitive. In the dynamic simulation, the pentanol and hexanol system in the direct sequence 6 after integration is studied, due to the limit of the open loop sensitivity analysis, the choice of control points are affected, causing the product specification to have small deviations under disturbances. Also, under throughput disturbances, the conversion also dropped, affecting the product specifications. But in the end of the disturbances test, only some of the disturbances causes a large deviation to the product specification, the rest of the disturbances shows only a 0.1mol% deviation. | en |
dc.description.provenance | Made available in DSpace on 2021-05-20T20:55:45Z (GMT). No. of bitstreams: 1 ntu-100-R98524049-1.pdf: 1752435 bytes, checksum: 5ae49d2a3e9b98c2f7968f28543106af (MD5) Previous issue date: 2011 | en |
dc.description.tableofcontents | 目錄
誌謝 1 摘要 3 Abstract 5 目錄 7 圖索引 10 表索引 14 1 緒論 15 1.1 前言 15 1.2 文獻回顧 21 1.3 研究動機與目的 24 1.4 組織章節 25 2 混合醇酯化系統熱力學與動力學模式 27 2.1 前言 27 2.2 熱力學模式 28 2.2.1 氣相熱力學模式 28 2.2.2 液相熱力學模式 29 2.3 蒸餘曲線圖(Residual Curve Maps) 34 2.4 動力學模式 36 3 穩態設計 41 3.1 前言 41 3.2 架構設計概念 41 3.2.1 直接序列設計 41 3.2.2 間接序列設計-「水相回流」 44 3.3 混合正丁、戊醇酯化系統熱整合穩態設計 50 3.3.1 設計概念 50 3.3.2 最適化設計之結果 51 3.3.3 熱整合前後之結果及討論 54 3.4 混合正戊、己醇酯化系統之穩態設計 56 3.4.1 直接序列設計 57 3.4.1.1 設計概念 57 3.4.1.2 最適化步驟 57 3.4.1.3 最適化結果 59 3.4.2 間接序列設計-「水相回流」 67 3.4.2.1 設計概念 67 3.4.2.2 最適化步驟 67 3.4.2.3 最適化結果 69 3.4.3 混合正戊、己醇酯化系統熱整合穩態設計 76 3.4.3.1 設計概念 76 3.4.3.2 最適化設計之結果 77 3.4.4 熱整合前後之結果及討論 80 3.5 架構比較及分析 82 3.6 總結 84 4 動態模擬與控制 85 4.1 前言 85 4.2 控制環路設計 85 4.3 控制架構探討 86 4.3.1 控制點及操作變數之決定 86 4.3.2 開環路靈敏度分析 87 4.3.3 非方形相對增益(NRG) 89 4.3.4 RGA配對分析 91 4.3.5 閉環路靈敏度分析 92 4.3.6 NRGA配對分析 95 4.3.7 控制器參數調諧方法 99 4.4 動態模擬結果 101 4.5 進料組成擾動測試 103 4.6 蒸餾塔側流氣體和塔內上升氣體流率比例擾動測試 108 4.7 進料流率擾動測試 113 5 結論 118 參考文獻 120 附錄A TAC計算公式 125 作者簡介 127 | |
dc.language.iso | zh-TW | |
dc.title | 混合正丁戊醇及正戊己醇之酯化
反應性分隔內壁蒸餾塔之程序設計與控制 | zh_TW |
dc.title | Design and Control of Reactive Divided Wall Column for
Esterification with Mixed Butanol and Pentanol or Mixed Pentanol and Hexanol Feed | en |
dc.type | Thesis | |
dc.date.schoolyear | 99-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 鄭西顯,汪上曉,王國彬,陳誠亮 | |
dc.subject.keyword | 酯化反應,混合醇,反應性分隔內壁蒸餾塔, | zh_TW |
dc.subject.keyword | esterification,alcohol,reactive divided wall column, | en |
dc.relation.page | 125 | |
dc.rights.note | 同意授權(全球公開) | |
dc.date.accepted | 2011-07-29 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-100-1.pdf | 1.71 MB | Adobe PDF | 檢視/開啟 |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。