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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 楊申語(SEN-YEU YANG) | |
dc.contributor.author | Po-Lin Chen | en |
dc.contributor.author | 陳柏霖 | zh_TW |
dc.date.accessioned | 2021-06-16T13:22:19Z | - |
dc.date.available | 2015-08-06 | |
dc.date.copyright | 2013-08-06 | |
dc.date.issued | 2013 | |
dc.date.submitted | 2013-07-25 | |
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Advanced Materials 20(21): 4049-4054. 林政緯 (2012). '滾輪壓印微奈米結構於光學玻璃表面製程開發研究.' 國立台灣大學碩士論文 | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/61995 | - |
dc.description.abstract | 玻璃材料具有優異的光學性質,且對於物理性與化學性的侵蝕有較佳的抵抗能力,能用於製作出高品質之光學元件。許多奈米結構具有抗反射與高疏水的特性,若能將其用於製作於玻璃材質或玻璃光學微結構表面,不僅能保有玻璃優異的特性,同時能減少其表面反射且具有抗污自潔的效果。
傳統玻璃微結構直接加工製程如電子束微影及雷射加工等,製程昂貴且耗時,而複製成型技術如微熱壓成型又有製程時間長且為批次無法連續生產的缺點。為了克服上述缺點,本研究利用熱滾壓方式達到連續生產、快速量產的目的,降低生產成本。本研究並利用創新性的壓印技術配合陽極氧化鋁製程製作微奈米複合透鏡陣列模具,結合熱滾壓方式進行一次滾壓即成功的製作出微奈米複合透鏡陣列結構於玻璃表面。本研究又進一步使用創新氣體輔助熱壓,配合電鑄技術,製作鎳質微奈米複合模具,解決模具沾黏於基材的問題,並增進熱壓效能。運用以上製程於玻璃上所製作之微奈米複合微透鏡結構具有良好的光學性質,具有良好且均勻的聚光效果,且表面奈米柱陣列結構可於550 nm波長時將反射率由7.60%降低至0.54%。在接觸角方面由67.15∘大幅的增加至120.70∘成為疏水且具抗污自潔效果之表面並達到具低成本、快速且可連續生產之特性。 本研究開發之熱滾壓技術,配合陽極氧化鋁模具,製作奈米柱陣列於強化玻璃表面。經實際量測,本結構可於各波長減少90%左右之反射光;在疏水性方面,接觸角由39.20∘大幅提升至88.75∘。運用此結構,本研究提出並製作雙面微奈米結構奈米柱陣列菲聶爾透鏡複合玻璃,其特點為減低表面反射,抗污漬結與聚光之效果,經實際量測可運用於太陽能模組聚光並增加光強度。 | zh_TW |
dc.description.abstract | Glass is the preferred material for quality optical devices due to its high refractive index and low color aberration. Glass also possesses high mechanical strength and chemical resistance. Surface sub-wavelength nanostructures are known as antireflective and water repellent structures. By fabricating these sub-wavelength nanostructures on surface of micro optical components made of glass, premium optical device with low surface reflection and self-cleaning properties can be realized.
As the demand of fabricating micro/nano structures on glass, the need for low-cost, simple and fast fabrication method has increased. Currently, most micro or nano structures on glass are manufactured by direct-machining such as e-beam lithography and laser machining techniques which are expensive and time-consuming. Mold replicating process such as micro/nano hot embossing has disadvantages of discontinuous process and long cycle time. In this research, for continuous and fast production, hot rolling method is developed. There are three major parts in this research. In the first part, a novel method was invented by combining embossing and anodic aluminum oxide method to create AAO mold with hybrid micro/nano structures to fabricate quality microlens arrays on optical glass with low surface reflection by hot rolling. Nano pillar arrays on the surface of microlens can reduce surface reflection from 7.60% to 0.54% at 550 nm wavelength. The overall nano/micro hybrid microlens can increase contact angle from 67.15∘ to 120.70∘. In the second part, eletro-formed nickel mold was used to prevent mold sticking and enhance rolling performance. The AAO mold was replicated by gas-assisted hot embossing followed by electroforming to reduce cycle time. In the last part, nano pillars array was hot rolled on Gorilla tempered glass by using anodic aluminum oxide mold to reduce surface reflection of glass and to increase self-cleaning ability. Nano pillars array on Gorilla glass can reduce up to 90% of broadband surface reflection. Meanwhile, the contact angle increased from 39.20∘ to 88.75∘. By combining the glass with Fresnel lens microstructure, this composite optical component can increase up to three time of energy efficiency on solar panels. | en |
dc.description.provenance | Made available in DSpace on 2021-06-16T13:22:19Z (GMT). No. of bitstreams: 1 ntu-102-R00522701-1.pdf: 11248995 bytes, checksum: c75ac74a01e3a58dcbbbaa466b56b1f0 (MD5) Previous issue date: 2013 | en |
dc.description.tableofcontents | 謝誌 III
摘要 IV ABSTRACT V 目次 VI 表目錄 IX 圖目錄 X 第1章 導論 1 1.1 前言 1 1.2 光學玻璃之介紹與應用 1 1.3 玻璃表面之微奈米結構 3 1.4 微熱壓成型技術 6 1.5 微滾壓成型技術 6 1.6 於玻璃表面製作微奈米結構之方法 7 1.7 陽極氧化鋁製作奈米孔洞 8 1.8 研究動機與目標 8 1.9 論文架構 9 第2章 文獻回顧 17 2.1 紫外光固化樹脂微奈米壓印 17 2.2 玻璃微熱壓成型技術 18 2.3 用於加工玻璃基材之微奈米模具製作 20 2.4 微結構滾壓成型技術 23 2.5 陽極氧化鋁之應用 24 2.6 文獻總結 26 第3章 實驗設備 40 3.1 實驗目的與整體流程規劃 40 3.2 本實驗使用之玻璃種類 40 3.2.1低色散光學玻璃 40 3.2.2離子交換強化玻璃 40 3.3 玻璃滾輪壓印機台設備 41 3.3.1玻璃滾壓機台架構 41 3.3.2加熱元件 42 3.3.3滾輪、加壓裝置與移動平台 42 3.3.4陶瓷墊片 42 3.4 陽極氧化鋁與熱壓設備 43 3.4.1陽極氧化鋁製程之原料 43 3.4.2電解槽與低溫循環系統 43 3.4.3熱壓機 43 3.5 紫外光固化樹脂與固化設備 44 3.5.1紫外光固化樹脂 44 3.5.1紫外光固化設備 44 3.6 量測設備 44 3.6.1電子顯微鏡 44 3.6.2光譜儀 45 3.6.3雷射共焦顯微鏡 45 3.6.4接觸角量測儀 45 3.6.5光強度計 45 3.6.6表面輪廓儀 46 第4章 滾壓微奈米複合結構於光學玻璃 55 4.1 滾壓微奈米複合玻璃之製程 56 4.2 微奈米複合微透鏡模具製作 57 4.2.1複製微透鏡陣列至高純度鋁片 57 4.2.2利用陽極氧化鋁製備奈米孔洞陣列 59 4.2.3微奈米複合微透鏡模具製作結果 60 4.3 滾壓微奈米複合透鏡陣列結構於光學玻璃表面製作 61 4.3.1滾壓微奈米複合透鏡陣列於光學玻璃表面操作窗 62 4.3.2滾壓微奈米複合透鏡陣列結構均勻性探討 63 4.4 微奈米複合微透鏡陣列光學性質量測與探討 63 4.5 滾壓微奈米複合透鏡陣列其他性質量測與探討 66 4.5.1奈米柱陣列之表面反射率 66 4.5.2微奈米複合微透鏡之疏水性量測與探討 67 4.6 本章結論 67 第5章 電鑄鎳模滾壓微奈米複合結構於玻璃 89 5.1 電鑄鎳模滾壓微奈米複合結構於光學玻璃製程 90 5.2 電鑄鎳質微奈米複合微透鏡模具製作 91 5.2.1氣體輔助熱壓微奈米複合微透陣列 91 5.2.2電鑄鎳金屬微奈米複合透鏡陣列模具製作 92 5.2.3電鑄鎳金屬微奈米複合微透鏡模具製作結果 94 5.3 電鑄鎳模具滾壓微奈米複合透鏡陣列於光學玻璃 94 5.4 微奈米複合透鏡陣列光學性質與其他性質探討 96 5.4.1電鑄鎳金屬微奈米複合微透鏡光學特性 96 5.4.2電鑄鎳金屬微奈米複合微透鏡接觸角量測 97 5.5 本章結論 97 第6章 滾壓微奈米柱陣列於強化玻璃 112 6.1 滾壓微奈米柱陣列於強化玻璃製程 113 6.2 陽極氧化鋁奈米孔洞陣列模具製作 113 6.3 滾壓奈米柱陣列於強化玻璃 114 6.4 奈米柱陣列光學與其他性質量測 115 6.4.1奈米柱陣列於強化玻璃抗反射量測 115 6.4.2奈米柱陣列於強化玻璃接觸角量測 115 6.5 應用奈米柱陣列強化玻璃於太陽能板表面 116 6.5.1奈米柱陣列菲聶爾透鏡複合玻璃製程 116 6.5.2奈米柱陣列菲聶爾透鏡複合玻璃測試與討論 117 6.6 本章結論 118 第7章 結論與未來研究方向 126 7.1 研究成果總結 126 7.1.1製作微奈米複合微透鏡陣列模具 126 7.1.2滾壓微奈米複合透鏡於光學玻璃 126 7.1.3電鑄鎳質微奈米複合微透鏡模具製作 127 7.1.4電鑄鎳質模具滾壓微奈米複合透鏡陣列於光學玻璃 127 7.1.5滾壓奈米柱陣列於強化玻璃表面 127 7.2 未來研究方向 128 參考文獻 129 | |
dc.language.iso | zh-TW | |
dc.title | 滾輪壓印微奈米複合結構於光學玻璃製程開發研究 | zh_TW |
dc.title | Development of Micro/Nano Hybrid Structures on Optical Glass by Roller Hot Embossing | en |
dc.type | Thesis | |
dc.date.schoolyear | 101-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 吳煌榮(HUANG-RONG WU),吳政憲(ZHENG-XIAN WU),王?玟(MIN-WEN WANG),張復瑜(FOU-YU ZHANG) | |
dc.subject.keyword | 玻璃,熱滾壓,微奈米複合,抗反射,疏水性, | zh_TW |
dc.subject.keyword | Glass,Hot Rolling,Micro/Nano hybrid,Antireflection,Hydrophobicity, | en |
dc.relation.page | 133 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2013-07-25 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 機械工程學研究所 | zh_TW |
顯示於系所單位: | 機械工程學系 |
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