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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 張惠婷(Hui-Ting Chang) | |
dc.contributor.author | Tzu-Hsuan Sung | en |
dc.contributor.author | 宋子萱 | zh_TW |
dc.date.accessioned | 2021-06-15T06:05:31Z | - |
dc.date.available | 2011-07-06 | |
dc.date.copyright | 2011-07-06 | |
dc.date.issued | 2010 | |
dc.date.submitted | 2010-08-16 | |
dc.identifier.citation | 邱俊雄、謝煥儒 (1983) 紙張防黴之研究。科學發展11(12):1237-1242。
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/47551 | - |
dc.description.abstract | 本研究目的為評估三種沒食子酸烷基酯化合物,沒食子酸丙酯、沒食子酸辛酯、沒食子酸月桂酯,以及丁基化羥基甲苯等抗氧化劑對於紙張防黴性的改善效果以及紙張性質的保護效果,其中以沒食子酸辛酯之改善效果最佳,當濃度為200 μg/cm2時,對Aspergillus terreus 和A. niger 生長面積的抑制率為85~90%,對於Chaetomiun globosum、Myrothecium verrucaria 和 Penicillium citrinum之抑制效果最為顯著,當濃度降低至25 μg/cm2時,仍可完全抑制黴菌之生長,且以沒食子酸辛酯處理紙張不會改變紙張原有性質。當沒食子酸辛酯處理濃度為100 μg/cm2時,即可有效改善黴菌對纖維素之降解,維持紙張之結晶度與熱穩定性等性質,避免紙張纖維素聚合度下降導致紙張物理性質降低,仍可維持原有的引張強度、撕裂強度與耐折度;且可預防黴菌於紙張表面留下難以修復的黴斑,對於紙張表面顏色、化學性質與物理性質皆具良好的保護效果。結合沒食子酸辛酯與百里香酚處理可使紙張的防黴活性大幅提升,當沒食子酸辛酯與百里香酚加乘處理濃度各為50 μg/cm2時,即可完全抑制C. globosum,對於A.niger與A.terreus亦有95%以上的抑制效果,比起單一藥劑處理濃度為100 μg/cm2時之抑制效果更佳。經過加速老化試驗後發現,沒食子酸辛酯處理濾紙仍保有優異的抗黴菌效果,百里香酚處理濾紙則普遍失去活性,顯示沒食子酸辛酯處理濾紙之耐久性較為良好。綜合上述結果可知,沒食子酸辛酯處理濾紙擁有優良的耐久性,在不影響紙張性質之前提下,能有效改善紙張之防黴性,抑制紙張黴害後的性質變化,以預防之觀點來說,相當符合理想防黴藥劑應具備有的條件,是非常值得後續研究與開發應用的防黴劑。 | zh_TW |
dc.description.abstract | In this study, the inhibitory effects of three alkyl gallates, including propyl gallate, octyl galate, dodecyl gallate and butylated hydroxytoluene against mildew and the protective effects of paper properties were evaluated. In aspect of inhibitory effect against mildew, octyl gallate possessed the best anti-mildew activity and butylated hydroxytoluene couldn’t inhibit any mildew. At a concentration of 200 μg/cm2, the inhibition percentage of octyl gallate against Aspergillus terreus and A. niger were 85~90%, and octyl gallate could completely inhibit Chaetomiun globosum, Myrothecium verrucaria and Penicillium citrinum at a concentration of 25 μg/cm2. At a concentration of 100 μg/cm2, octyl gallate could maintain original crystallinity, thermal stability, degree of polymerization, tensile strength, tearing strength and folding endurance of paper materials. In addition, octyl gallate effectively prevents surface color, chemical and mechanical properties of paper from changing by mildew. Furthermore, the synergistic effect of octyl gallate and thymol against mildew was outstandingly enhanced. C. globosum was completely inhibited when combined octyl gallate and thymol at each concentration of 50 μg/cm2. And the inhibition percentage of treatment combined octyl gallate and thymol against A. niger and A. terreus were above 95%, which is much better than those of treating alone at a concentration of 100 μg/cm2. After accelerating aging, octyl gallate still owned excellent anti-mildew activity, but thymol lost the activity completely. The durability of octyl gallate is much better than thymol. Overall, octyl gallate could inhibit the growth of mildew and protect the paper properties from changing by mildew without affecting the original paper properties. Therefore, octyl gallate is an ideal environmentally benign anti-mildew reagent that is worthy of further research and application. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T06:05:31Z (GMT). No. of bitstreams: 1 ntu-99-R97625010-1.pdf: 3469310 bytes, checksum: 1cac439239467ed05760e837cedb9958 (MD5) Previous issue date: 2010 | en |
dc.description.tableofcontents | 目錄……………………………………………………………………… I
圖目錄………………………………………………………………...IV 表目錄………………………………………………………………...IX 摘要..………………………………………………………....XIV Abstract………………………………………………………......XV 一、前言………………………………………………………………….1 二、文獻回顧........................................3 (一)、紙質製品之黴害......................................3 1. 常見黴害紙質製品之菌類.................................3 2. 黴菌對紙質製品保存之影響...............................7 (二)、紙質製品滅菌與除黴方法........................8 1. 物理法................................................8 2. 化學法.............................................9 (三)、沒食子酸烷基酯化合物之生物活性..................11 1. 沒食子酸烷基酯化合物之抗氧化活性......................11 2. 沒食子酸烷基酯化合物之抗真菌活性......................13 3. 沒食子酸烷基酯化合物之抗病毒活性......................15 (四)、紙張各項性質分析方法...............................17 1. 傅立葉轉換式紅外線光譜分析法...........................17 2. 物理性質試驗法.................................19 3. 熱重分析.............................................20 4. X光繞射分析....................................23 5. 加速老化試驗..........................................26 三、材料與方法...........................................28 (一)、試驗材料....................................28 1. 紙樣................................................28 2. 化合物..............................................28 3. 試驗菌種..........................................28 (二)、藥劑處理方式......................................28 (三)、紙張防黴菌試驗......................................29 (四)、紙張表面顏色分析..............................29 (五)、紙張化學性質分析................................29 1. 傅立葉轉換紅外光光譜分析.............................29 2. 高解析X光薄膜繞射分析..................................30 3. 熱重分析........................................30 (六)、紙張物理性質分析............................30 1. 紙張之抗張強度試驗.....................................30 2. 紙張之撕裂強度試驗.................................30 3. 紙張之耐折強度試驗..............................31 4. 紙張之厚度測量試驗..............................31 (七)、紙張加速老化試驗...............................31 1. 紙及紙板加速老化試驗法 — 105℃乾熱處理..............31 2. 紙及紙板加速老化試驗法— 80℃及65% R.H.溼熱處理法.....31 (八)、統計分析....................................31 四、結果與討論....................................32 (一)、沒食子酸烷基酯化合物的抗黴菌活性評估...............32 1. 沒食子酸烷基酯化合物對紙張防黴性之影響.............32 2. 沒食子酸辛酯對紙張防黴性之改善效果....................36 3. 沒食子酸辛酯與百里香酚對紙張防黴性質之加乘效果.........37 (二)、沒食子酸辛酯對紙張黴害後之性質改善效果...........39 1. 沒食子酸辛酯對紙張黴害之表面顏色改善效果.........39 2. 沒食子酸辛酯對紙張黴害之化學性質改善效果..........44 3. 沒食子酸辛酯對紙張黴害之物理性質改善效果...............70 (三)、沒食子酸辛酯處理紙張經老化試驗後之性質評估..........79 1. 老化試驗後紙張表面顏色變化............................79 2. 老化試驗後紙張防黴性之變化............................87 五、結論...............................................93 六、參考文獻............................................95 | |
dc.language.iso | zh-TW | |
dc.title | 沒食子酸烷基酯化合物對紙張防黴性之改善效果 | zh_TW |
dc.title | Improvements of Alkyl Gallates on the Anti-mildew Property of Paper | en |
dc.type | Thesis | |
dc.date.schoolyear | 98-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 張上鎮(Shang-Tzen Chang),蘇裕昌(Yu-Chang Su),王益真(I-Chan Wang),藍浩繁(Haw-Farn Lan) | |
dc.subject.keyword | 沒食子酸烷基酯化合物,防黴性,沒食子酸辛酯,紙,百里香酚, | zh_TW |
dc.subject.keyword | Alkyl gallates,anti-mildew activity,octyl gallate,paper,thymol, | en |
dc.relation.page | 105 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2010-08-16 | |
dc.contributor.author-college | 生物資源暨農學院 | zh_TW |
dc.contributor.author-dept | 森林環境暨資源學研究所 | zh_TW |
顯示於系所單位: | 森林環境暨資源學系 |
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