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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 邱勝賢 | |
dc.contributor.author | Jia-Ling Ko | en |
dc.contributor.author | 柯嘉玲 | zh_TW |
dc.date.accessioned | 2021-06-15T04:56:57Z | - |
dc.date.available | 2012-07-30 | |
dc.date.copyright | 2010-07-30 | |
dc.date.issued | 2010 | |
dc.date.submitted | 2010-07-28 | |
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Chem. 2006, 71, 2373–2383; (c) K.-W. Cheng, C.-C. Lai, P.-T. Chiang, S.-H. Chiu, Chem. Commun. 2006, 2854–2856. [15] For a discussion of the self-assembly of DB24C8 and DBA+, see: M. C. T. Fyfe, J. F. Stoddart, Adv. Supramol. Chem. 1999, 5, 1–53. [16] Crystal data for 14-H•PF6: [C50H59O4N2][PF6]; Mr = 896.96; monoclinic; space group C 2/c; a = 35.8810(15); b = 23.1966(13); c = 12.4934(4) Å; V = 9966.3 (8) Å3; ρcalcd = 1.196 g cm–3; μ(CuKα) = 1.041 mm–1; T = 100(2) K; colorless columns; 5345 independent measured reflections; F2 refinement; R1 = 0.1500; wR2 = 0.3903. [17] CCDC-760743 (14-H•PF6) and 760744 (29-H•PF6) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif. [18] (a) S.-H. Chiu, S.-J. Rowan, S. J. Cantrill, J. F. Stoddart, A. J. P. White, D. J. Williams, Chem. Eur. J. 2002, 22, 5170–5183; (b) Y. Tachibana, N. Kihara, Y. Furusho, T. Takata, Org. Lett. 2004, 6, 4507–4509. [19] A similar method has been used to generate pseudorotaxanes as solids for the efficient syntheses of [4]rotaxanes and the smallest [2]rotaxane prepared to date; see: (a) C.-C. Hsu, N.-C. Chen, C.-C. Lai, Y.-H. Liu, S.-M. Peng, S.-H. Chiu, Angew. Chem. 2008, 120, 7585–7588; Angew. Chem. Int. Ed. 2008, 47, 7475–7478; (b) S.-Y. Hsueh, K.-W. Cheng, C.-C. Lai, S.-H. Chiu, Angew. Chem. 2008, 120, 4508–4511; Angew. Chem. Int. Ed. 2008, 47, 4436–4439. [20] D. Grandjean, P. Pale, J. Chuche, Tetrahedron 1991, 47, 1215–1230. [21] Crystal data for 29-H•PF6: [C48H80O8N][PF6]; Mr = 944.10; monoclinic; space group C2/c; a = 21.7841(11); b = 13.0799(6); c = 17.6482(7) Å; V = 5024.3(4) Å3; ρcalcd = 1.248 g cm–3; μ(CuKα) = 1.102 mm–1; T = 100(2) K; colorless columns; 3888 independent measured reflections; F2 refinement; R1 = 0.1425; wR2 = 0.4319. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/46181 | - |
dc.description.abstract | We have developed a “threading-followed-by-swelling” protocol to synthesize [2]rotaxanes efficiently and atom-economically. Our protocol employs cis-1-[(Z)-alk-1′-enyl]-2-vinylcyclopropane units as the termini of the threadlike component; these end groups are converted into more-sizable cycloheptadiene motifs, which function as stopper units, through Cope rearrangements at elevated temperature. We used this approach to synthesize [2]rotaxanes in good yield from [2]pseudorotaxanes featuring either one or two swellable termini to interlock three different types of macrocycle. The chiral centers created by the swelling process were “erased” by hydrogenating the cycloheptadiene termini into the corresponding cycloheptane units, affording achiral molecular [2]rotaxanes as the only final products. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T04:56:57Z (GMT). No. of bitstreams: 1 ntu-99-D95223010-1.pdf: 1286863 bytes, checksum: ce211269be7c85eb4514dcd49205a22f (MD5) Previous issue date: 2010 | en |
dc.description.tableofcontents | 中文摘要…………………………………………………………………I
英文摘要…………………………………………………………………II 論文發表………………………………………………………………III 目錄………………………………………………………………………IV 圖表目錄…………………………………………………………………V 流程目錄…………………………………………………………………VI 第一章 導論………………………………………………………………1 第二章 結果與討論 ……………………………………………………4 第三章 結論 …………………………………………………………15 第四章 實驗部份………………………………………………………16 第五章 參考文獻………………………………………………………32 第六章 附錄……………………………………………………………36 | |
dc.language.iso | en | |
dc.title | 利用穿透後末端膨脹法合成車輪烷 | zh_TW |
dc.title | Using a Threading-Followed-by-Swelling Approach to Synthesize [2]Rotaxanes | en |
dc.type | Thesis | |
dc.date.schoolyear | 98-2 | |
dc.description.degree | 博士 | |
dc.contributor.oralexamcommittee | 陳平,徐秀福,黃暄益,賴建成,翁紹華 | |
dc.subject.keyword | 車輪烷, | zh_TW |
dc.subject.keyword | rotaxane, | en |
dc.relation.page | 36 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2010-07-29 | |
dc.contributor.author-college | 理學院 | zh_TW |
dc.contributor.author-dept | 化學研究所 | zh_TW |
顯示於系所單位: | 化學系 |
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