請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/37827
標題: | 萘啶胺衍生物配基及其直線型四核鎳金屬錯合物之
合成、構造與物理性質研究 Synthesis, Crystal Structures and Physical Properties of a Series of Linear Tetranickle Complexes with the Naphthyridine-Functionalized Amine Ligands |
作者: | Che-Wei Yeh 葉哲維 |
指導教授: | 彭旭明(Shie-Ming Peng) |
關鍵字: | 萘,啶胺衍生物配基,直線型四核鎳金屬錯合物, Naphthyridine-Functionalized Amine Ligands,Linear Tetranickle Complexes, |
出版年 : | 2008 |
學位: | 碩士 |
摘要: | 本論文是探討以萘啶胺 (H2any) 衍生物配基,吡啶萘啶胺(Hpyany),萘啶甲基醯胺 (Hnyma) 與金屬形成錯合物之合成、構造與物理性質研究。本研究合成出三種不同形式之金屬錯合物,將分別於不同章節做介紹與探討。
首先利用四氮配基吡啶萘啶胺和磺醯甲苯基二吡啶二胺 (H2Tsdpda) 合成出ㄧ系列之混配基四核鎳 (Ni) 金屬串錯合物,錯合物[Ni4( Three types of metal complexes with naphthyridine-functionalized amine ligands, 2-α-pyridylamino-1,8-naphthyridine (Hpyany) and N-1,8-naphthyridyl methylamide (Hnyma) have been prepared. First, a series of linear tetranickel complexes coordinated by two kinds of ligands, Hpyany and p-toluenesulfonyl di-pyridyl-di-amine (H2Tsdpda), have been synthesized. Their structures were determined by single-crystal X-ray diffraction analysis. The ligands, Hpyany and H2Tsdpda, have been deprotonated to act as tetradentate ligands and helically wrapped the nickel metal ions to form a tetranuclear metal string, which is structurally similar to the previous report. The molecular structure of the one-electron reduction species [Ni4( |
URI: | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/37827 |
全文授權: | 有償授權 |
顯示於系所單位: | 化學系 |
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