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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 黃慶怡 | |
dc.contributor.author | Yao-Chih Hsu | en |
dc.contributor.author | 許堯直 | zh_TW |
dc.date.accessioned | 2021-06-13T01:20:31Z | - |
dc.date.available | 2007-07-20 | |
dc.date.copyright | 2007-07-20 | |
dc.date.issued | 2007 | |
dc.date.submitted | 2007-07-16 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/29827 | - |
dc.description.abstract | 我們利用耗散粒子動力學來探討A1-block-(A2-graft-B)兩成份線性梳狀共聚合物的相行為,藉由改變線性部份A1的聚合度m來觀察系統結構的大小尺寸衍變,我們建構出χABN對m的相圖並跟理論計算所得到的相圖來作比較。當線性部份很短時,系統會以梳狀部份內主鏈A2與接枝B分離的小尺寸結構為主,線性部份A1則與A2混雜在一起;當線性部份很長時,系統則轉變為由線性部份A1與梳狀部份A2/B之間的不相容性所形成的大尺寸結構,此結果基本上與Nap等人理論計算的結果是一致的[Macromolecules 2002, 35, 952];然而我們發現當系統開始衍變成大尺寸的結構時,成份的分布會受到作用力的影響,梳狀主鏈A2在作用力大時會因為B的排斥力而被推向界面,此界面現象導致在大小尺寸中間有個很大的過渡區塊,系統會產生層狀互穿等特殊的結構,這在理論計算中並沒有被觀察到。接下來我們發現隨著整體聚合度的增加,線性梳狀共聚合物的相行為會越來越類似於線性雙塊狀共聚合物,分離的機制主要是由於線性部份與梳狀部份兩塊狀之間的不相容性,因此系統是由fcoil來決定其結構,梳狀部份並不會因為聚合度的增加而產生小尺寸的結構,A2仍在A1與B中間形成界面。最後當系統變為三個互不相容的成份時,若線性部份A1與梳狀主鏈A2之間的不相容性夠大,系統便有可能出現大小尺寸共存的階級性結構(hierachical structure)。 | zh_TW |
dc.description.provenance | Made available in DSpace on 2021-06-13T01:20:31Z (GMT). No. of bitstreams: 1 ntu-96-R93549025-1.pdf: 1983194 bytes, checksum: 5c3fe347a4eb05d9c84edd5b93e55f5e (MD5) Previous issue date: 2007 | en |
dc.description.tableofcontents | 目 錄
誌謝 I 中文摘要 II 英文摘要 III 簡介 1 耗散粒子動力學模擬方法 5 結果與討論 7 結論 14 參考文獻 15 Figure Captions 19 | |
dc.language.iso | zh-TW | |
dc.title | 利用耗散粒子動力學探討A-graft-B梳狀以及A-block-(A-graft-B)線性梳狀共聚合物的相行為 | zh_TW |
dc.title | Phase Behavior of A-graft-B Comb and A-block-(A-graft-B) Coil-Comb Copolymers by Dissipative Particle Dynamics | en |
dc.type | Thesis | |
dc.date.schoolyear | 95-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 陳信龍,林祥泰 | |
dc.subject.keyword | 耗散粒子動力學,線性梳狀共聚合物,大小尺寸結構,層狀互穿,階級性結構, | zh_TW |
dc.subject.keyword | dissipative particle dynamics(DPD),A-graft-B comb copolymers,A-block- (A-graft-B) coil-comb copolymers,large-length scale,short-length scale., | en |
dc.relation.page | 30 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2007-07-19 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
顯示於系所單位: | 高分子科學與工程學研究所 |
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