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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 黃武良(Wuu-Liang Huang) | |
dc.contributor.author | Hui-Jane Mo | en |
dc.contributor.author | 莫慧偵 | zh_TW |
dc.date.accessioned | 2021-06-08T06:56:43Z | - |
dc.date.copyright | 2009-07-27 | |
dc.date.issued | 2009 | |
dc.date.submitted | 2009-07-22 | |
dc.identifier.citation | Axelson, D.E., Parkash, S., 1986. 13C solid state NMR of alberta subbituminous macerals. Fuel Science and Technology International 4, 45-85.
Bassett, W.A., Ming, L.C., 1972. Disproportionation of Fe2SiO4 to 2FeO+SiO2 at pressure up to 250 Kbar and temperatures up to 3000 ℃. Physics of the Earth and Planetary Interiors 6, 154-160. Bassett, W.A., Shen, A.H., Bucknum, M., Chou, I.M., 1993. A new diamond anvil cell for Hydrothermal studies to 2.5 GPa and from -190 to 1200℃. Review of Scientific Instruments 64, 2340-2345. Baskin, D.K., 1997. Atomic H/C ratio of kerogen as estimate of thermal maturity and organic matter conversion. American Association of Petroleum Geologist Bulletin 81, 1400 (abstract). Bertrand, P.E., 1989. Microfacies and petroleum properties of coals as revealed by a study of North Sea Jurassic coals. International Journal of Coal Geology 13, 575-595. Carr, A.D., Williamson, J.E., 1990. The relationship between aromaticity, vitrinite reflectance and maceral composition of coals: Implications for the use of vitrinite reflectance as a maturity parameter. Organic Geochemistry 16, 313-323. Chang, Y.J., Huang, S.Y., Huang, W.L., 2007. Fluorescence response of oil-prone kerogens during pyrolysis with implication to liquid petroleum generation. manuscript. Choi, C., Muntean, J.V., Thompson, A.R., Botto, R.E., 1989. Characterization of coal macerals using combined chemical and NMR spectroscopic methods. Energy and Feuls 3, 528-533. Clayton, J.L., Rice, D.D., Michael, G.E., 1991. Oil-generating coals of the San Juan Basin, New Mexico and Colorado, U.S.A. Organic Geochemistry 17, 735-742. Cody, G.D., Alexander, C.M.O., Tera, F., 2002. Solid-state (1H and 13C) nuclear magnetic resonance spectroscopy of insoluble organic residue in the Murchison meteorite: a self-consistent quantitative analysis. Geochimica et Cosmochimica Acta 66, 1851-1865. Collinson, M.E., van Bergen, P.F., Scott, A.C., de Leeuw, J.W., 1994. The oil generating potential of plants from coal and coal-bearing strata through time: a review with new evidence from Carboniferous plants. In: Scott, A.C., Fleet, A.J. (Eds.), Coal and Coal-Bearing Strata as Oil-Prone Source Rocks? Geological Society Special Publication 77, 31-70. Crelling, J.C., 1983. Current uses of fluorescence microscopy in coal petrology. Journal of Microscopy 132, 251–266. Crelling, J.C., 1989. Separation and characterization of coal macerals: accomplishments and future possibilities: preprints of papers-division of fuel chemistry. American Chemical Society 34 (no. 1), 249–253. Crelling, J.C., Bensley, D.F., 1984. Characterization of coal macerals by fluorescence microscopy. In: Winans, R.E., Crelling, J.C. (Eds.), Chemistry and characterization of coal macerals American Chemical Society, Symposium Series 252, 33-45. Davis, M.R., Abbott, J.M., Gaines, A.F., 1985. Chemical structures of telocollonites and sporinites. Differentiation between telocollinites and sporinites by the aromatic structrues present in their pyridine extracts. Fuel 64, 1362-1369. Dereppe, J.M., Boudou, J.P., Moreaux, C., Durand, B., 1983. Stractural evolution of a sedimentologically homogeneous coal series as a function of carbon content by solid state N.M.R. Fuel 62, 575-579. Durand, B., Paratte, M., 1983. Oil potential of coals: a geochemical approach. In Brooks, J. (Ed.), Petroleum Geochemistry and Exploration of Europe. Blackwell, Oxford, 255-265. Dyrkacz, G.R., Bloomquist, C.A.A., Ruscic, L., 1984. Chemical variations in coal macerals separated by density gradient centrifugation. Fuel 63, 1166-1173. Fleet, A.J., Scott, A.C., 1994. Coal and coal-bearing strata as oil-prone source rocks: an overview. In: Scott, A.C., Fleet, A.J. (Eds.), Coal and Coal-Bearing Strata as Oil-Prone Source Rocks? Geological Society Special Publication 77, 1-8. Furimsky, E. and Ripmeester, J., 1983. Characterization of Canadian coals by nuclear magnetic resonance rpectroscopy. Fuel Processing Technology 7, 191-202. George, S.C., Smith, J.W., 2004. Variability of molecular source and thermal maturity indicators in a marine-influenced coal seam: the Greta Seam, Sydney basin. Abstracts of the 21th Annual Meeting of Society for Organic Geochemistry 21, 77. Guo, Y., Bustin, P.M., 1998. Micro-FTIR spectroscopy of liptinite macerals in coal. International Journal of Coal Geology 36, 259–275. Gerstein, B.C., Murphy, P.D., Ryan, L.M., 1982. Aromaticity in coal. In: Merers, RA., (Ed.), Coal Structure. Academic Press, New York, 87-129. Huang, D., 1999. Advances in hydrocarbon generation theory II. Oil from coal and their primary migration model. Journal of Petroleum Science and Engineering 22, 131-139. Huang, D., Qin, K., Wang, T., Zhou, X., 1997. Formation and mechanism of oil from coal. Petroleum Industry Press, Beijing, 443. Huang, W.L., 1996. A new pyrolysis technique using a diamond anvil cell: In-situ visualization of kerogen transformation. Organic Geochemistry 24, 95-107. Huang, W.L., Bassett, W.A., Wu, T.C., 1994. Dehydration and hydration of montmorillonite at elevated temperatures and pressures monitored using synchrotron radiation. American Mineralogists 79, 683-691. Huang, W.L., Otten, G.A., 1998. Oil generation kinetics determined by DAC-FS/IR pyrolysis: technique development and preliminary results. Organic Geochemistry 29, 1119-1137. Huang, W.L., Otten, G.A., 2001. Cracking kinetics of crude oil and alkanes determined by diamond anvil cell-fluorescence spectroscopy pyrolysis: technique development and preliminary results. Organic Geochemistry 32, 817–830. Hunt, J.H., 1991. Generation of gas and oil from coal and other terrestrial organic matter. Organic Geochemistry 17, 673-680. Hunt, J.M., 1996. Petroleum Geochemistry and Geology, 2nd edtion. Freeman, New York, 743. Hutton, A., Daulay, B., Herudiyanto Nas, C., Pujobroto, A., Sutarwan, H., 1994. Liptinite in Indonesian Tertiary coals. Energy and Fuels 8, 1469–1477. Horsefield, B., Yordy, K.L., Crelling, J.C., 1988. Determining the petroleum-generating potential of coal using geochemistry and organic petrology. Organic Geochemistry 13, 121-129. Jarvie, D.M., Hill, R. J., Ruble, T.E., Pollastro, R.M., 2007. Unconventional shale-gas systems: The Mississippian Barnett Shale of north-central Texas as one model for thermogenic shale-gas assessment. American Association of Petroleum Geologists Bulletin 91, 475-499. Jasienko, S., Kidawa, H., Swietlik, U., Bratek, K., 1986. Changes in properties and structure of coals during coking and pyrolysis (in Polish), Rapport No 424, Wroclaw University of Technology, Wroclaw. Jurkiewicz, A., Maciel, J.M., 1995. 13C NMR spin-lattice relaxation properties and quantitative analytical methodology of 13C NMR spectroscopy for coals. Application Chemistry 67, 2188-2194. Kalkreuth, W., Steller, M., WieschenKämper, I., Ganz, S., 1991. Petrographic and chemical characterization of Canadian and German coals in relation to utilization potential. Fuel 70, 683-694. Khavari Khorasani, G., Murchison, D.G., 1988. Order of generation of petroleum hydrocarbons from liptinite macerals with increasing thermal maturity. Fuel 67, 1160-1162. Killops, S.D., Funnell, R.H., Suggate, R.P., Sykes, R., Peters, K.E., Walters, C., Woolhouse, A.D., Weston, R.J., Boudou, J.P., 1998. Predicting generation and expulsion of paraffinic oil from vitrinite-rich coals. Organic Geochemistry 29, 1-21. Killops, S.D.,Woolhouse, A.D., Weston, R.J., Cook, R.A., 1994. A geochemical appraisal of oil generation in Taranaki Basin, New Zealand. American Association Petroleum Geologists Bulletin 78, 1560-1585. Kruszewska, K.J., 2003. Fluorescing macerals in South African coals. International Journal of Coal Geology 54, 79–94. Kuehn, D.W., Davies, A., Snyder, R.W., Starsinic, M., Painter, P.C., Havens, J., Koenig, J.L., 1982. The application of FT-IR and solid state 13C NMR to the characterization of a set of vitrinite concentrates. Preprints of Papers- American Chemical Society, Division of Fuel Chemistry 27, 55-63. Land, D.H., Jones, C.M., 1987. Coal geology and exploration of part of the Tertiary Kutei Basin in East Kalimantan, Indonesia. In: Scott, A.C. (Ed.), Coal and Coal-Bearing Strata: Recent Advance. Geological Society Special Publication, 32, 235-255. Lewan, M.D., 1997. Experiments on the role of water in petroleum formation. Geochimica et Cosmochimica Acta 61, 3691-3723. Lin, R., Davis, A., 1988. A fluorogeochemical model for coal macerals. Organic Geochemistry 12, 363-374. Liu, S.L., Taylor, G.H., 1991. TEM observation on Type III kerogen, with special reference to coal as a source rock. Journal of Southeast Asian Earth Sciences 5, 43-52. Lu, L., Sahajwalla, V., Kong, C., Harris, D., 2001. Quantitative X-ray diffraction analysis and its application to various coals. Carbon 39, 1821-1833. Machnikowska, H., Krzton, A., Machnikowski, J., 2002. The characterization of coal macerals by diffuse reflectance infrared spectroscopy. Fuel 81, 245-252. Maciel, G.E., Bartuska, V.J., Miknis, F.P., 1978. Correlation between oil yields of oil shales and 13C nuclear magnetic resonance spectra. Fuel 57, 505-506. Maroto-Valer, M.M., Taulbee, D.N., Andresen, J.M., Hower, J.C., Snape, C.E., 1998. Quantitative 13C NMR study of structural variations within the vitrinite and inertinite maceral groups for a semifusinite-rich bituminous coal. Fuel 77, 805-813. McMurry, J., 2008. Organic chemistry. Thomson learning, New York, 1244. Miknis, F.P. and Netzel, D.A., 1996. NMR determination of carbon aromatization during hydrous pyrolysis of coals from the Mesaverde Group, Greater Green River Basin. Energy and Fuels 10, 3-9. Miknis, F.P., Smith, J.W., 1984. An NMR survey of United States oil shales. Organic Geochemistry 4, 193-201. Miknis, F.P., Sullivan, M., Bartuska, V.J., Maciel, G.E., 1981. Cross-polarization magic-angle spinning 13C NMR spectra of coals of varying rank. Organic Geochemistry 3, 19-28. Miknis, F.P., Netzel, D.A., Surdam, R.C., 1996. NMR determination of carbon aromatization during hydrous pyrolysis of coals from the Mesaverde Group, Greater Green River Basin. Energy and Fuels 10, 3-9. Mo, H.J., Huang, W.L., Machnikowska, H., 2007. Generation and expulsion of petroleum from coal macerals visualized in-situ during DAC pyrolysis. International Journal of Coal Geology 73, 167-184. Monthious, M., 1988. Expected mechanisms in nature and in confined system pyrolysis. Fuel 67, 843-847. Moore, P.S., Burns, B.J., Emmett, J.K., Guthrie, D.A., 1992. Integrated source, maturation and migration analysis, Gippsland Basin, Australia. Australian Petroleum Exploration Association Journal 32, 313-324. Mukhopadhyay, P.K., Hatcher, P.G., 1993. Composition of coal. In: Law, B.E., Rice, D.D. (Eds.), Hydrocarbons in coal. American Association of Petroleum Geologists, Studies in Geology 38, 79-118. Mukhopadhyay, P.K., Hatcher, P.G., Calder, J.H., 1991. Hydrocarbon generation from deltaic and intermontane fluviodeltaic coal and coaly shale from the Tertiary of Texas and Carboniferous of Nova Scotia. Organic Geochemistry 17, 765-783. Newman, J., Price, L.C., Johnston, J.H., 1997. Hydrocarbon source potential and maturation in Eocene New Zealand vitrinite-rich coals. Journal of Petroleum Geology 20, 137-163. Norgate, C.M., Boreham, C.J., Kamp, P.J.J., Newman, J., 1997. Relationship between hydrocarbon generation, coal type and rank for Middle Eocene coals, Buller Coalfield, New Zealand. Journal of Petroleum Geology 20, 427-458. Pepper, A.S., Corvi, P.J., 1995. Simple kinetic models of petroleum formation. III. Modeling an open system. Marine and Petroleum Geology 12, 417-452. Powell, T.G., and Boreham, C.J., 1991. Petroleum generation and source rock assessment in terrigenous sequences: an update. Australian Petroleum Exploration Association Journal 29, 114-129. Powell, T.G., Boreham, C.J., 1994. Terrestrially sourced oils: where do they exist and what are our limits of knowledge? A geochemical perspective. In: Scott, A.C., Fleet, A.J. (Eds.), Coal and Coal-bearing Strata as Oil-prone Source Rocks? Geological Society Special Publication 77, 11–29. Pugmire, R.J., Zilm, K.W., Wolfenden, W.R., Grant, D.M., Dyrkacy G.R., Bloomouist, C.A.A., Horwitz, E.P., 1982. Carbon-13 NMR spectra of macerals separated from individual coals. Organic Geochemistry 4, 79-84. Qin, K.Z., Chen, D.Y., Li, Z.G., 1991. A new method to estimate the oil and gas potentials of coals and kerogens by solid state 13C NMR spectroscopy. Organic Geochemistry 17, 865-872. Qin, K.Z., Huang, D.F., Li, L.Y., Guo, S.H., 1993. Oil and gas potential of macerals as viewd by 13C NMR spectroscopy. In Organic Geochemistry, Poster Sessions from the 16th International Meeting on Organic Geochemistry, Falch Hurtigtrykk, Oslo, 758-762.. Rahman, M., Kinghorn, R.R.F., 1995. A practical classification of kerogens related to hydrocarbon generation. Journal of Petroleum Geology 18, 91-102. Ritter, U., Grøver, A., 2005. Adsorption of petroleum compounds in vitrinite: implications for petroleum expulsion from coal. International Journal of Coal Geology 62, 183–191. Ruble, T.E., Lewan, M.D., Philp, R.P., 2001. New insights on the Green River petroleum system in the Uinta basin from hydrous pyrolysis experiments. American Association of Petroleum Geologists Bulletin 85, 1333–1371. Ruble, T.E., Lewan, M.D., Philp, R.P., 2003. Reply to Curry Discussion on “New insights on the Green River petroleum system in the Uinta basin from hydrous pyrolysis experiments'. American Association of Petroleum Geologists Bulletin 87, 1535–1541. Russell, N.J., Wilson, M.A., Pugmire, R.J., Grant, D.M., 1983. Preliminary studies on the aromaticity of Australian coals. Fuel 62, 601-605. Sandvik, E.I., Young, W.A., Curry, D.J., 1992. Expulsion from hydrocarbon sources: The role of organic absorption. Organic Geochemistry 19, 77–87. Scott, A.C., Fleet, A.J., 1994. Coal and coal-bearing strata as oil-prone source rocks: Current problems and future directions. In: Scott, A.C., Fleet, A.J. (Eds.), Coal and Coal-bearing Strata as Oil-prone Source Rocks? Geological Society Special Publication 77, 289-299. Seewald, J.S., 2003. Organic–inorganic interactions in petroleum-producing sedimentary basins, Nature 426, 327-333. Singh, B.D., Singh, A., 2004. Observations on Indian Permian Gondwana coals under fluorescence microscopy: an overview. Gondwana Research 7, 143–151. Smernik, R.J., Schwark, L., Schmidt, M.W.I., 2006. Assessing the quantitative reliability of solid-state 13C NMR spectra of kerogen across a gradient of thermal maturity. Solid State Nuclear Magnetic Resonance 29, 312-321. Smith, G.C., Cook, A.C., 1984. Petroleum occurrence in the Gippsland Basin and its relationship to rank and organic matter type. Australian Petroleum Exploration Association Journal 24, 196-216. Snowdon, L.R., 1991. Oil from type III organic matter: resinite revisited. Organic Geochemistry 17, 734-747. Stach, E., Mackowsky, M.T., Teichmüller, M., Taylor, G.H., Chandra, D., Tei chmüller, R., 1982. Stach’s textbook of coal petrology, Berlin Stuttgar, Gebruder Borntraeger, 535. Stankiewicz, B.A., Kruge, M.A., Mastalerz, M., 1996. A geochemical study from a Miocene lignite and an Eocene bituminous coal, Indonesia. Organic Geochemistry 24, 531-545. Stout, S.A., 1994. Chemical heterogeneity among adjacent coal microlithotypes-implications for oil generation and primary migration from humic coal. In: Scott, A.C., Fleet, A.J. (Eds.), Coal and Coal-bearing Strata as Oil-prone source rocks? Geological Society Special Publication 77, 93-106. Suggate, R.P., Dickinson, W.W., 2004. Carbon NMR of coals: the effects of coal type and rank. International Journal of Coal Geology 57, 1–22. Sung, C.M., 1976. New modification of the diamond anvil press: A versatile apparatus for research at high pressure and high temperature. Review of Scientific Instruments 47, 1343-1346. Sweeney, J.J. and Burnham, A.K., 1990. Evaluation of a simple model of vitrinite reflectance based on chemical kinetics. American Association of Petroleum Geologists bulletin 74, 1559-1570. Takeda, N., Asakawa, T., 1988. Study of petroleum by pyrolysis-I. Pyrolysis experiments by Rock-Eval and assumption of molecular structural change of kerogen using 13C-NMR. Applied Geochmistry 3, 441-453. Tissot, B.P., Welte, D.H., 1984. Petroleum formation and occurrence, 2nd ed., Springer, New York, 743. Van Krevelen, D.W., 1961, Coal, Elsevier Co., Amsterdam-London-New York-Princeton, 514. Weng, R.F., Huang, W.L., Kuo, C.L., Inan S., 2003. Characterization of oil generation and expulsion from coals and source rocks using diamond anvil cell pyrolysis. Organic Geochemistry 34, 771-787. Wertz, D.L., Quin, J.L., 1998. X-ray analysis of liquid-treated coals. 1. Effects of pyridine on the short-range structuring in Beulah Zap lignite. Energy and Fuels 12, 697–703. Wilkins, R.W.T., George, S.C., 2002. Coal as a source rock for oil. International Journal of Coal Geology 50, 317-361. Weng, R.F., Huang, W.L., Kuo, C.L., Inan, S., 2003. Characterization of oil generation and expulsion from coals and source rocks using diamond anvil cell pyrolysis. Organic Geochemistry 34, 771-787. Werner-Zwanziger, U., Lis, G., Mastalerz, M., Schimmelmann, A., 2005. Thermal maturity of type II kerogen from the New Albany Shale assessed by 13C CP/MAS NMR. Solid Sate Nuclear Magnetic Resonance 27, 140-148. Wilkins, R.W.T., George, S.C., 2002. Coal as a source rock for oil: a review. International Journal of Coal Geology 50, 317-361. Witte, E.G., Schenk, H.J., Muller, P.J., Schwochau, K., 1988. Structural modifications of kerogen during natural evolution as derived from 13C CP/MAS NMR, IR spectroscopy and Rock-Eval pyrolysis of Toarcian shales. In: Mattavelli, L., Novelli, L., (Eds.), 1987. Advances in organic Geochemistry. Organic Geochemistry 13, 1039-1044. Pergamon Press, Qxford. Yen, T. F., Chilingar, G.V., 1976. Oil shale. Elsevier, Amsterdam, 292. Zilm, K.W., Pugmire, R.J., Larter, S.R., Allan, J., Grant, D.M., 1981. Carbon-13 CP/MAS spectroscopy of coal macerals. Fuel 60, 717-722. 莫慧偵,2004,有機物之生油潛能評估:鑽石砧熱裂解及紅外線光譜分析,國立台灣大學地質科學系研究所碩士論文。 呂國榮,2007,利用固態核磁共振定量研究氨基酸的水合特徵,國立中山大學化學系研究所碩士論文。 黃麗純,2002,利用NMR研究一種新蛇毒蛋白分子CTXn之結構與動力學,國立中山大學化學系研究所碩士論文。 黃玄昇,2002,利用氫、矽、鋁之一維和二維固態核磁共振法研究沸石ZSM-5中之鋁原子位點及酸性位點之分佈,國立中山大學化學系研究所碩士論文。 孫立中,2000,抑制鏡煤素反射率之量測成因-以分離台灣裕峰煤為例,國立中央大學地球物理研究所博士論文。 王蕙君,2002,以核磁共振光譜學研究氨基酸水合,國立中山大學化學系研究所碩士論文 翁瑞富,2001,鑽石砧應用於石油生成模擬之研究:源岩熱裂解即時影像分析,國立台灣大學地質科學系研究所碩士論文。 | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/25893 | - |
dc.description.abstract | 油母質種類的不同以及成熟度的高低皆會在化學成分以及分子結構中顯示出差異。本研究使用波蘭地區石炭紀的煤素質樣品,利用鑽石砧熱裂解(DAC pyrolysis)直接觀察樣品受熱而裂解的過程、生油型態、與油氣潛能,再以固態核磁共振(Solid-state 13C CP/MAS NMR)去鑑定樣品在分子結構上的特性,同時也搭配其他非破壞性之光譜分析儀器電子顯微鏡(SEM)、紅外線(IR)、X光(XRD)、以及螢光(DAC-FS)等分析方法加以輔佐對比。在熱裂解實驗觀察出膜煤素產出大量顏色透明、流動性強的油,偶爾也伴隨一些氣泡的出現,熱裂解過程中產油速率最大那一刻的溫度Tpeak範圍是453~475℃;本研究使用含氫量一般的鏡煤素,這之中也有部分樣品能產出相當可觀的油量,這些油的顏色較深、質地較濃,Tpeak範圍是465~540℃,這結果顯示著並不是只有高氫量的鏡煤素(perhydrous vitrinite)才有產油潛能;惰煤素樣品在整個熱裂解過程中都沒有任何油或氣體的生成被觀察到;NMR的芳香環化指數(fa)是以惰煤素最高、膜煤素最低,芳香環指數之對數參數(logArNMR)與樣品自身成熟度(%Ro)顯示高度線性相關性,其餘光譜學分析結果也與以上這些煤素質的生油特性相當一致。另外,在探討成熟度對油母質生油潛力之影響上,研究樣品還包括三個不同沉積環境(湖相、海相、陸相)低成熟度的源岩,經由人工加熱至四個不同成熟度(Ro=0.79 /0.95 /1.10 /1.34%),經由光譜所呈現的化學分子結構探討個別煤素質及油母質的生油潛能。NMR結果顯示源岩樣品的脂肪烴結構明顯地隨著成熟度增加而大幅減少,fa隨成熟度增加而增加,其增加速率在低成熟度比較快,當Ro>1.1%之後的fa值則變化不大,對其作log(ArNMR)vs. %Ro圖,分別可得出三條線性趨勢線,然而相關性不如煤素質樣品那樣高。鑽石砧熱裂解的觀察中海相樣品在低成熟度下沒有生油的反應,推測其一原因可能是海相樣品會產生類似瀝青的中間產物,而在萃取固體粉末的過程中就被酸溶掉;另一可能原因是我們的這個海相樣品的組成有機物包含大量鏡煤素,因此熱裂解過程中沒有生油反應。 | zh_TW |
dc.description.abstract | A variety of maceral samples were characterized by the solid-state 13C CP/MAS NMR spectroscopy and their oil and gas generative potentials were evaluated by in-situ visual observations in a diamond anvil cell. The results show that exinite generated large amounts of visible oil-like liquid along with some gas, while fusinites generated no visible liquid and gas. The liquid (oil) from exinite appears light in color and less viscous. Some non-perhydrous vitrinite unexpectedly generated large amounts of visible liquid, although the liquid is darker and thicker than that from exinite, indicating that the oil potential of vitrinites is not limited to its perhydrous nature. The visual peak temperatures (Tpeak) of maximum rate of liquid petroleum generation for vitrinite (465-540°C) are generally higher than those for exinites (453-475°C). The results from NMR show that the aromaticities(fa) of macerals, which are the lowest in exinite and highest in fusinite, are inversely related to their oil generative capacities, which exhibits the highest oil generation potential for exinite. The observed linear relationship between the logarithms of fa values vs. %Ro suggests a potential maturity indicator. The dependence of NMR spectroscopy on organic maturity was further studied by artificially maturing two immatured keorgens from Green-River and Barnett shales and terrestrial coal. Isolated kerogen samples were pyrolyzed at 320°C in durations, equivalent to four levels of maturities(Ro = 0.79 , 0.95 , 1.10 , 1.34%) using confined-pressure (gold-tube) pyrolysis. Similar to those observed from macerals, the results show that the aliphatic groups in the matured kerogens decrease while aromatic groups increase significantly with increasing maturities. The fa values are positively correlated with the maturities among which the Green-River kerogen exhibited the highest effect. However, the fa values increase only subtle beyond a maturity equivalent to 1.1 %Ro for all three kerogens. The DAC pyrolysis of the matured samples reveals significant decrease in oil generation potential with maturity, particularly for the Barnett kerogen. | en |
dc.description.provenance | Made available in DSpace on 2021-06-08T06:56:43Z (GMT). No. of bitstreams: 1 ntu-98-D93224005-1.pdf: 7630007 bytes, checksum: 937d59acf96b963755e5904f915f9a41 (MD5) Previous issue date: 2009 | en |
dc.description.tableofcontents | 口試委員會審定書…………………………………………………………I
致謝………………………………………………………………………..II 中文摘要………………………………………………………………….III 英文摘要…………………………………………………………………IV 目錄………………………………………………………………………V 圖目錄……………………………………………………………………VII 表目錄……………………………………………………………………IX PART I GENERATION AND EXPULSION OF PETROLEUM FROM COAL MACERALS VISUALIZED IN-SITU DURING DAC PYROLYSIS 1 ABSTRACT 2 1. INTRODUCTION 4 2. EXPERIMENTAL METHODS 7 2.1 STARTING MATERIALS 7 2.2 TECHNIQUES OF MACERAL CHARACTERIZATION 12 2.3 DIAMOND ANVIL CELL PYROLYSIS TECHNIQUE 12 3. EXPERIMENTAL RESULTS 19 3.1 CHARACTERISTICS OF MACERALS 19 3.2 SEMI-OPEN SYSTEM PYROLYSIS 25 3.3 CLOSED SYSTEM PYROLYSIS 31 4. DISCUSSIONS 35 5. CONCLUSIONS 42 REFERENCES 44 PART II 固態碳13核磁共振在油母質生油潛能分析中之應用 52 摘要 53 1.緒論 55 2.研究背景 57 2.1. 石油的來源 57 2.2. 油母質 62 2.3. 煤 70 3.實驗儀器 72 3.1. 圍壓熱裂解 72 3.2. 鑽石砧 73 3.3. 固態碳13核磁共振儀 76 4.實驗方法 83 4.1. 實驗樣品 83 4.2. 圍壓熱裂解實驗 85 4.3. 鑽石砧熱裂解實驗 90 4.4. 固態碳13核磁共振實驗 92 5.結果與討論 94 5.1. 不同油母質之NMR光譜及其產油潛能 94 5.2. 不同成熟度之油母質NMR及其產油潛能之影響 100 6.結論 111 參考文獻 112 | |
dc.language.iso | zh-TW | |
dc.title | 核磁共振與鑽石砧熱裂在油母質生油潛能之評估 | zh_TW |
dc.title | Application of 13C NMR Spectroscopy and DAC Pyrolysis to the Study of Oil Potential of Kerogens | en |
dc.type | Thesis | |
dc.date.schoolyear | 97-2 | |
dc.description.degree | 博士 | |
dc.contributor.oralexamcommittee | 劉聰桂,紀文榮,郭政隆,沈俊卿 | |
dc.subject.keyword | 核磁共振,鑽石砧,油母質,成熟度, | zh_TW |
dc.subject.keyword | 13C NMR,diamond anvil cell,kerogen,maturity, | en |
dc.relation.page | 119 | |
dc.rights.note | 未授權 | |
dc.date.accepted | 2009-07-22 | |
dc.contributor.author-college | 理學院 | zh_TW |
dc.contributor.author-dept | 地質科學研究所 | zh_TW |
顯示於系所單位: | 地質科學系 |
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